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Safety Data Sheet EN

PRINTPERFEKT 226 FF

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
PRINTPERFEKT 226 FF

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Textile auxiliary

Manufacturers & Suppliers

C

CHT Germany GmbH

manufacturer

Bismarckstraße 102, 72072 Tübingen, Germany

+49 7071 154 0

C

CHT Switzerland AG

manufacturer

Kriessernstrasse 20, 9462 Montlingen, Switzerland

+41 71 763 88 11

C

CHT UK Bridgwater Ltd.

manufacturer

Showground Road, Bridgwater TA6 6AJ, United Kingdom

+44 1278 411 400

Emergency Contacts

CHEMTREC

+1 703 527 3887

24 hours

CHEMTREC

+44 20 3807 3798

24 hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H317 May cause an allergic skin reaction.

Precautionary Statements

P261 Avoid breathing mist or vapours.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Acrylic polymer in aqueous dispersion

Chemical Name CAS Number Concentration Hazardous
ethanediol EC: 203-473-3 107-21-1 1 - 10% Yes
2-methyl-2H-isothiazol-3-one EC: 220-239-6 2682-20-4 0.0025 - 0.025% Yes
1,2-benzisothiazol-3(2H)-one EC: 220-120-9 2634-33-5 0.0025 - 0.025% Yes
mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) 55965-84-9 0.0002% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If symptoms persist, call a physician.

Skin contact

Wash off immediately with soap and plenty of water. If skin irritation persists, call a physician.

Symptoms: There may be reddening, swelling associated with itching on contact.

Eye contact

Immediately flush eye(s) with plenty of water. If symptoms persist, call a physician.

Ingestion

Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Call a physician immediately.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO2), Water spray, Dry powder, Foam

Unsuitable media

None known.

Specific hazards

Hazardous decomposition products formed under fire conditions.

Instructions

In case of fire do not inhale smoke, conflagration gases and steams.

Firefighter Protection

In the event of fire, wear self-contained breathing apparatus.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Contaminated surfaces will be extremely slippery.

Environmental

The product should not be allowed to enter drains, water courses or the soil. Pay attention to local or official regulations.

Cleanup methods

Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Clean contaminated surface thoroughly.

Materials: sand, silica gel, acid binder, universal binder, sawdust

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin, eyes and clothing. Do not breathe vapours, aerosols. Take off all contaminated clothing immediately. Handle in accordance with good industrial hygiene and safety practice.

Storage

Do always store in containers which correspond to the original ones. Keep container tightly closed. Protect from frost.

Hygiene

Avoid contact with skin, eyes and clothing. Do not breathe vapours, aerosols. Take off all contaminated clothing immediately. Handle in accordance with good industrial hygiene and safety practice.

Fire prevention

No special protective measures against fire required.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Solids with occupational exposure limits in liquid preparations do not cause an exposure in the workplace, because they are not present in a respirable form. Exposure can occur in the form of aerosols or after drying of the liquid the solids remain, possibly in a finely dispersed form. Provide sufficient air exchange and/or exhaust in work rooms.

Hands

Material: Nitrile rubber Break through time: > 480 min Glove thickness: >= 0.35 mm Protective index: Class 6 Material: Chloroprene Break through time: > 480 min Glove thickness: >= 0.5 mm Protective index: Class 6 Remarks: The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. The obtained break through times according to EN 374 Part III are not measured under normal operating conditions. Therefore a maximum usage time of 50% of the break through time is recommended.

Eyes

Goggles (EN 166)

Respiratory

In case the work place is not ventilated sufficiently and during spray processing, it is necessary to wear respiratory protective equipment. Recommended Filter type: Combination filter A/P (EN 141)

Skin/Body

Wear suitable protective clothing (EN 14605).

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
liquid
Colour
white
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
---
Ph
7 - 9.5 (20 °C) (undiluted)
Melting Point
No data available
Boiling Point
ca. 100 °C (1,013 hPa)
Flash Point
Not applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable
Vapor Pressure
ca. 23 hPa (20 °C) Water
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
ca. 1 g/cm3 (20 °C)
Flammability
does not ignite
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
not determined
Decomposition Temperature
The substance or mixture is not classified self-reactive.
Solubility
---
Partition Coefficient
Not applicable
Solubility In Water
miscible
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
13,300 - 19,900 mPa.s (20 °C) Brookfield RVT spindle 5 20 rpm
Kinematic Viscosity
not determined
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable.

Reactivity

No hazards to be specially mentioned.

Hazardous reactions

No dangerous reaction known under conditions of normal use.

Avoid

Not applicable

Incompatible

Not applicable

Decomposition

No decomposition if stored and applied as directed.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Product: Toxicity to fish : Remarks: No data is available on the product itself. Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Remarks: Argument by analogy Toxicity to algae/aquatic plants : Remarks: No data is available on the product itself. Toxicity to microorganisms : EC50 (activated sludge): > 1,000 mg/l Method: Retarded respiration test (OECD 209) Remarks: Argument by analogy

12.1 Toxicity

ethanediol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Test Type: static test Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia (water flea)): > 100 mg/l Exposure time: 48 h Test Type: static test Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : IC50 (Pseudokirchneriella subcapitata (algae)): > 1,000 mg/l Exposure time: 96 h Test Type: static test Toxicity to microorganisms : EC20 (activated sludge): > 1,000 mg/l Exposure time: 0.5 h Test Type: static test Method: ISO 8192

12.1 Toxicity

2-methyl-2H-isothiazol-3-one: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 4.77 mg/l Exposure time: 96 h Test Type: flow-through test Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia (water flea)): 0.934 mg/l Exposure time: 48 h Test Type: flow-through test Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : EC50 (Pseudokirchneriella subcapitata (green algae)): 0.22 mg/l Exposure time: 120 h Test Type: static test Method: OECD Test Guideline 201 NOEC (Pseudokirchneriella subcapitata (green algae)): 0.05 mg/l Exposure time: 120 h Test Type: static test Method: OECD Test Guideline 201 M-Factor (Acute aquatic toxicity) : 10 Toxicity to microorganisms : EC50 (activated sludge): 41 mg/l Exposure time: 3 h Test Type: static test Method: OECD Test Guideline 209 Toxicity to fish (Chronic toxicity) : NOEC: 4.93 mg/l Exposure time: 98 d Species: Oncorhynchus mykiss (rainbow trout) Test Type: flow-through test Method: OECD Test Guideline 210 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 0.044 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: flow-through test Method: OECD Test Guideline 211 M-Factor (Chronic aquatic toxicity) : 1

12.1 Toxicity

1,2-benzisothiazol-3(2H)-one: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2.15 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia (water flea)): 2.9 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : EC10 (Selenastrum capricornutum (green algae)): 0.043 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 EC50 (Selenastrum capricornutum (green algae)): 0.11 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 M-Factor (Acute aquatic toxicity) : 1 Toxicity to microorganisms : EC50 (activated sludge): 12.8 mg/l Exposure time: 3 h Method: OECD Test Guideline 209

12.1 Toxicity

mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1): Toxicity to fish : EC50 (Oncorhynchus mykiss (rainbow trout)): 0.22 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia (water flea)): 0.12 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae/aquatic plants : NOEC (Pseudokirchneriella subcapitata (green algae)): 0.0012 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 EC50 (Pseudokirchneriella subcapitata (green algae)): 0.048 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 M-Factor (Acute aquatic toxicity) : 100 Toxicity to microorganisms : EC20 (activated sludge): 0.97 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Toxicity to fish (Chronic toxicity) : NOEC: 0.098 mg/l Exposure time: 28 d Species: Oncorhynchus mykiss (rainbow trout) Method: OECD Test Guideline 210 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 0.004 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Method: OECD Test Guideline 211 M-Factor (Chronic aquatic toxicity) : 100

12.2 Persistence and degradability

Product: Biodegradability : Test Type: DOC measuring Biodegradation: > 70 % Exposure time: 28 d Method: OECD 302 B (elimination) Remarks: Argument by analogy The product is "inherently biodegradable" according to the criteria of the OECD. Biochemical Oxygen Demand (BOD) : 22 mg/g Incubation time: 5 d Method: DIN EN 1899-1 (H 55) Remarks: Argument by analogy Chemical Oxygen Demand (COD) : 260 mg/g Method: DIN 38409-H-41 Remarks: Argument by analogy Physico-chemical removability : Remarks: Can be eliminated from water by precipitation.

The product is inherently biodegradable according to OECD criteria and can be eliminated from water by precipitation.

12.2 Persistence and degradability

ethanediol: Biodegradability : Test Type: DOC measuring Result: Readily biodegradable. Biodegradation: 90 - 100 % Exposure time: 10 d Method: OECD 301 A (elimination)

12.2 Persistence and degradability

2-methyl-2H-isothiazol-3-one: Biodegradability : Test Type: CO2 measuring Biodegradation: 47.6 - 55.8 % Exposure time: 29 d Method: OECD 301 B (mineralisation)

12.2 Persistence and degradability

1,2-benzisothiazol-3(2H)-one: Biodegradability : Result: rapidly degradable

12.2 Persistence and degradability

mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1): Biodegradability : Test Type: O2 measuring Result: Readily biodegradable. Biodegradation: > 60 % Exposure time: 28 d Method: OECD 301 D (mineralisation) Remarks: The product is "readily biodegradable" according to the criteria of the OECD. Remarks: The 10 day time window criterion is not fulfilled.

12.3 Bioaccumulative potential

Product: Bioaccumulation : Remarks: No data is available on the product itself. Components:

No data is available on the product itself.

12.3 Bioaccumulative potential

ethanediol: Partition coefficient: n-octanol/water : log Pow: -1.36 (25 °C)

12.3 Bioaccumulative potential

2-methyl-2H-isothiazol-3-one: Bioaccumulation : Bioconcentration factor (BCF): 5.75 Partition coefficient: n-octanol/water : log Pow: 0.486 (20 °C) Method: OECD Test Guideline 117

12.3 Bioaccumulative potential

1,2-benzisothiazol-3(2H)-one: Partition coefficient: n-octanol/water : log Pow: 0.70 (20 °C)

12.3 Bioaccumulative potential

mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1): Partition coefficient: n-octanol/water : log Pow: 0.75 Remarks: Active ingredient

12.4 Mobility in soil

Product: Mobility : Remarks: No data available

12.5 Results of PBT and vPvB assessment

Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

The substance/mixture contains no components considered to be PBT or vPvB at levels of 0.1% or higher.

12.6 Other adverse effects

Product: Adsorbed organic bound halogens (AOX) : Remarks: The product does not increase the AOX-value of the waste water.

The product does not increase the AOX-value of the waste water.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Pay attention to local or official regulations.

Disposal

Pay attention to local or official regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Relevant EU provisions transposed through retained EU law

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for PRINTPERFEKT 226 FF?

The signal word is warning.

What is the physical form of PRINTPERFEKT 226 FF?

PRINTPERFEKT 226 FF is a liquid appearing as liquid with white color. It has characteristic odor.

What is PRINTPERFEKT 226 FF used for?

Textile auxiliary

What are the hazard statements for PRINTPERFEKT 226 FF?

This substance has 1 hazard statement:

  • H317: May cause an allergic skin reaction.

What is the melting point of PRINTPERFEKT 226 FF?

The melting point is No data available and the boiling point is ca. 100 °C (1,013 hPa).