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Safety Data Sheet EN

MANGAMIX 70

CAS 1317-35-7 / 7439-96-5
EC 215-266-5 / 231-105-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
MANGAMIX 70
Chemical Name
Manganese Oxide in slurry
Synonyms
Manganese Oxide

Regulatory Identifiers

CAS Number
1317-35-7 / 7439-96-5 Check regulations →
EC Number
215-266-5 / 231-105-1 Check regulations →

Identified Uses

Industrial use of Manganese Oxide for coloration of ceramic, mainly in clay industry (body and surface pigment).

Uses advised against

There are no uses advised against

Manufacturers & Suppliers

K

KIMPE SAS

manufacturer

35, Rue Lambic – 31200 TOULOUSE – FRANCE

+33 (0)5 61 42 70 90

Emergency Contacts

Emergency Contact

+33 (0)5 61 42 70 90

Monday – Friday 8.30am – 6.00pm

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Repr. Cat. 2 H361

GHS Pictograms

GHS08 - Serious health hazard

GHS08

Hazard Statements

H361 Suspected of damaging fertility or the unborn child

Precautionary Statements

P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P280 Wear protective gloves/protective clothing/eye protection/face protection
P405 Store locked up

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Water EC: 231-791-2 7732-18-5 25 - 35% No
Mn --- 55 - 65% No
Fe₂O₃ EC: 215-168-2 1309-37-1 4 - 6% No
CaO EC: 215-138-9 1305-78-8 1 - 5% No
SiO₂ EC: 231-545-4 7631-86-9 1 - 4% No

Solution of sodium polyacrylate as well as acrylate polymer are used in low quantity to make the suspension

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

In exceptional conditions of dust formation/inhalation, move the patient to fresh air and keep him/her warm and still.

Skin contact

Remove contaminated clothing. Wash with neutral soap and water. Do not use solvents or thinners

Eye contact

Irrigate with clean water for 15 minutes holding eyelids open. Seek medical advice if irritation occurs and persists

Ingestion

If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. If swallowed, rinse mouth with water (only if the person is conscious).

Immediate Medical Attention

Seek medical advice if irritation occurs and persists (eye contact). Seek medical advice immediately (ingestion). Always call a doctor in case of doubt or if symptoms persist.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray / extinguishing powder / foam

Specific hazards

Small quantities of fume could come out during firing.

Instructions

Do not stay in the area of the fume.

Firefighter Protection

Wear usual appropriate PPE.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

During emergency procedure, avoid direct contact

Large spill

For huge quantities, pump the product into suitable, closed containers for disposal.

Environmental

Product should not be released into the environment.

Cleanup methods

Use absorbent materials to pick up waste residues and put them into suitable, closed containers for disposal.

Materials: absorbent materials

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wash with water thoroughly after handling. Do not eat, drink or smoke when using this product.

Storage

Keep in properly labeled containers. Avoid any type of leakage and keep the product into tightly closed container. Keep away from frost and extreme warm temperatures.

Hygiene

Wash with water thoroughly after handling. Do not eat, drink or smoke when using this product.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use adequate exhaust ventilation to keep airborne concentration below the allowable exposure limit at places dust could be formed.

Hands

The following glove materials meeting CEN standards are suitable for handling this product: PVC (1.5 mm, > 480 minutes, EN 374), Natural Rubber (1.3 mm, > 480 minutes, EN 374), Nitrile (0.85 mm, > 480 minutes, EN 374)

Eyes

Safety glasses with side-shield (frame goggles) are recommended (Ex: EN 166) where splash can happen

Respiratory

Advisable in case of possible exceptional important air contamination

Skin/Body

Advisable. Good personal hygiene is particularly recommended.

Environmental

Avoid discharge to sewers, storm drains, surface waters and soil. Collect the quantities of products spilled on the ground

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid
Colour
Brown / Dark Brown
Colour Intensity
---
Form
---
Odor
Characteristic
Odor Threshold
Not Determined
Ph
> 7
Melting Point
Not Determined
Boiling Point
~100°C (1.013hPa)
Flash Point
No Flash point before boiling point.
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not Tested
Vapor Pressure
Not Determined
Vapor Density
Not Determined
Relative Density
---
Bulk Density
---
Density
~2.15 g/cm³ at 20°C
Flammability
Not Flammable
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
Not self-igniting. Product also contains high rate of water.
Decomposition Temperature
---
Solubility
---
Partition Coefficient
Not Applicable
Solubility In Water
0.79 g/L if 20°C. Additives used are miscible and dispersive
Solubility In Fat
Not Tested
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
15-60 seconds (COUP FORD N°4) (Under normal conditions of use, viscosity shall increase with time).
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of storage and use (see section 7)

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Concentrated hydrochloric acid (HCl) reacts with the product forming a very toxic gas (Chlorine Cl₂). Reacts violently with hydrogen peroxide (H₂O₂)

Avoid

Avoid high temperature and direct contact to sunlight

Incompatible

oxidizing agents and acids (mainly hydrochloric acid)

Decomposition

None known

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Fish short-term toxicity (Oncorrhynchus mykiss) LC₅₀ (96h): >100% v/v Fish long-term toxicity (Oncorrhynchus mykiss) Aquatic invertebrates short-term toxicity (Daphnia) EC₅₀ (48h): >100% v/v Aquatic invertebrates' long-term toxicity (Daphnia) NOEC (8d): 1.3 mg/L dissolved based on mortality

MOBILITY

This product is not mobile under normal environmental conditions. However, not all the data regarding the additives used to manufacture the product is available yet. Thus, it is recommended to prevent the contamination of soil.

The product is not mobile under normal environmental conditions, though data on additives is incomplete; soil contamination should be prevented.

PERSISTENCE AND DEGRADABILITY

Trimanganese Tetraoxide contains an inorganic cation (Mn²⁺), and as such the criterion "persistence" is not relevant for the metal and its inorganic compounds in a way as it is applied to organic substances. The polymeric part of additives (less than 2% of the product) is hardly biodegradable.

BIO ACCUMULATIVE POTENTIAL

A hazard assessment concluded that manganese and manganese compounds including Mn₃O₄ do not bio-accumulate or bio-magnify.

PBT AND vPvB ASSESSMENT

The product does not contain any substance which can be considered as PBT (Persistant/Biaccumulative/Toxic) or vPvB (Very Persistant/Very Bioaccumulable).

The product does not contain any substance which can be considered as PBT or vPvB.

OTHER ADVERSE EFFECTS

None known
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Dispose of in accordance with local or national legislation or regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The text of this product safety datasheet is prepared in compliance with Regulation (EC) NO 1907/2006 (REACH) and Regulation (EC) No 1272/2008 (CLP).

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is MANGAMIX 70 known by?

MANGAMIX 70 is also known as: Manganese Oxide

What is the hazard signal word for MANGAMIX 70?

The signal word is warning.

What is the physical form of MANGAMIX 70?

MANGAMIX 70 is a liquid appearing as liquid with brown / dark brown color. It has characteristic odor.

What is MANGAMIX 70 used for?

Industrial use of Manganese Oxide for coloration of ceramic, mainly in clay industry (body and surface pigment).

What are the hazard statements for MANGAMIX 70?

This substance has 1 hazard statement:

  • H361: Suspected of damaging fertility or the unborn child

What is the melting point of MANGAMIX 70?

The melting point is Not Determined and the boiling point is ~100°C (1.013hPa).