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Safety Data Sheet EN

CONTROX 778

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
CONTROX 778
Product Code
304007780000

Regulatory Identifiers

CAS Number
N/A
UFI Code
2C40-40VR-G005-TP0T

Manufacturers & Suppliers

Kluthe Benelux B.V. logo

Kluthe Benelux B.V.

national supplier

Produktieweg 8, NL-2404 Alphen aan den Rijn

+31 172/ 516 000

http://www.kluthe.com

Emergency Contacts

CHEMTREC

+44 20 3885 0382

24h/7/365

CHEMTREC local

0800 1817059

CHEMTREC local

+43 1 3649237

CHEMTREC local

+31 85 888 0596

CHEMTREC local

+32 2 808 32 37

CHEMTREC local

+34 931768511

CHEMTREC local

+351 308 801 773

CHEMTREC local

+45 69 91 85 73

CHEMTREC local

+46 8 525 034 03

CHEMTREC local

+48 22 398 80 29

CHEMTREC local

+420 228 880 039

CHEMTREC local

+386 1 888 80 16

CHEMTREC local

+36 1 808 8425

CHEMTREC local

+44 20 3807 3798

Pirogov

+359 2 9154 213

Centro Antiveleni di Milano

02.66101029

Centro Antiveleni di Roma

06.3054343

Centro Antiveleni di Roma

06.49978000

Centro Antiveleni di Roma

06.68593726

Centro Antiveleni di Pavia

0382.24444

Centro Antiveleni di Firenze

055.7947819

Centro Antiveleni di Bergamo

800.883300

Centro Antiveleni di Foggia

0881.732326

Centro Antiveleni di Napoli

081.7472870

Centro Antiveleni di Verona

800.011.858

CIAV

+351 800 250 250

NTIC

+421 2 5477 4166

INTCF

+34 91 562 04 20

ETTSZ

+36 80 201 199

ETTSZ

+36 1 476 6464

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Skin Corr. Cat. 1 H314
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335
STOT RE Cat. 2 H373

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray
P280 Wear protective gloves/protective clothing and eye/face protection
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor
P331 Do NOT induce vomiting

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Benzyl alcohol EC: 202-859-9 100-51-6 75 - 100% Yes
Ethylene glycol EC: 203-473-3 107-21-1 10 - 25% Yes
Ethanolamine EC: 205-483-3 141-43-5 5 - 10% Yes
Potassium hydroxide EC: 215-181-3 1310-58-3 3 - 5% Yes

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No. 1907/2006 (REACH), Article 59)

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If breathing is difficult, (trained personnel should) give oxygen.

Symptoms: Delayed pulmonary edema may occur.

Skin contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get immediate medical attention.

Symptoms: May cause an allergic skin reaction.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical attention.

Ingestion

Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Get immediate medical attention.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

Do not scatter spilled material with high pressure water streams.

Specific hazards

The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases and vapors. Product is or contains a sensitizer. May cause sensitization by skin contact.

Instructions

CAUTION: Use of water spray when fighting fire may be inefficient.

Firefighter Protection

Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Environmental

Prevent further leakage or spillage if safe to do so. Should not be released into the environment.

Cleanup methods

Take up mechanically, placing in appropriate containers for disposal.

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Handle product only in closed system or provide appropriate exhaust ventilation. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Avoid breathing vapors or mists.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Protect from moisture. Store locked up. Store away from other materials.

Hygiene

Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

None under normal use conditions.

Hands

Wear suitable gloves. Impervious gloves. Butyl caoutchouc (butyl rubber), 0.5 mm, >=480 min.

Eyes

Tight sealing safety goggles. Face protection shield.

Respiratory

No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Recommended Filter Type: Filtering device (full mask or mouthpiece) with filter: AP-2

Skin/Body

Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.

Environmental

No information available.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid
Colour
light yellow
Colour Intensity
---
Form
---
Odor
characteristic
Odor Threshold
Not established
Ph
14
Melting Point
Not established
Boiling Point
170 - 206 °C
Flash Point
~ 96 °C
Freezing Point
---
Softening Point
No information available
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not established
Vapor Pressure
---
Vapor Density
---
Relative Density
Not established
Bulk Density
no data available
Density
1.058 - 1.078 g/cm³
Flammability
Not established
Upper Explosive Limit
not relevant
Lower Explosive Limit
not relevant
Explosive Limits
---
Auto Ignition Temperature
385 °C
Decomposition Temperature
None known
Solubility
---
Partition Coefficient
---
Solubility In Water
partially miscible
Solubility In Fat
---
Molecular Weight
No information available
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Not applicable
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

No information available.

Hazardous reactions

None under normal processing.

Avoid

None known based on information supplied.

Incompatible

Strong acids. Strong oxidizing agents.

Decomposition

None known based on information supplied.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1. Toxicity

| Chemical name | Parameter | Species | Effective dose | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Benzyl alcohol 100-51-6 | LC50 | Pimephales promelas | 460 mg/L | 96 h | |

12.1. Toxicity

Chemical name | Parameter | Species | Effective dose | Exposure time | Method --- Ethanolamine | LC50 | Pimephales | 2070 mg/L | 96 h 141-43-5 | | promelas | | | |

12.1. Toxicity

| Chemical name | Parameter | Species | Effective dose | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Potassium hydroxide 1310-58-3 | LC50 | Gambusia affinis | 80 mg/L | 96 h | |

12.1. Toxicity

| Chemical name | Parameter | Species | Effective dose | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Benzyl alcohol 100-51-6 | EC50 | water flea | 23 mg/L | 48 h | OECD 202 |

12.1. Toxicity

| Chemical name | Parameter | Species | Effective dose | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Ethanolamine 141-43-5 | EC50 | Daphnia magna | 65 mg/L | 48 h | |

12.1. Toxicity

| Chemical name | Parameter | Species | Effective dose | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Benzyl alcohol 100-51-6 | EC50 | Pseudokirchneriella subcapitata | 770 mg/L | 72 h | OECD 201 |

12.1. Toxicity

| Chemical name | Parameter | Species | Effective dose | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Ethanolamine 141-43-5 | EC50 | Desmodesmus subspicatus | 15 mg/L | 72 h | |

12.1. Toxicity

| Chemical name | Parameters | Species | Effective dose | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Benzyl alcohol 100-51-6 | EC10 | pseudomonas putida | 658 mg/L | 16 h | DIN 38412 |

12.1. Toxicity

| Chemical name | Parameters | Species | Effective dose | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Ethanolamine 141-43-5 | EC50 | pseudomonas putida | 110 mg/L | 16 h | DIN 38412 |

12.1. Toxicity

| Chemical name | Parameters | Species | Effective dose | Exposure time | Method | | --- | --- | --- | --- | --- | --- | | Potassium hydroxide 1310-58-3 | EC50 | Photobacterium phosphoreum | 22 mg/L | 15 min. | |

12.2. Persistence and degradability

Persistence and degradability | Chemical name | degradation rate | test duration | Readily biodegradable | Remarks | Method | | --- | --- | --- | --- | --- | --- |

12.2. Persistence and degradability

| Chemical name | degradation rate | test duration | Readily biodegradable | Remarks | Method | | --- | --- | --- | --- | --- | --- | | Benzyl alcohol 100-51-6 | >90 % | 14 d | Yes | Aerobic biological treatment | OECD 301 C |

12.2. Persistence and degradability

| Chemical name | degradation rate | test duration | Readily biodegradable | Remarks | Method | | --- | --- | --- | --- | --- | --- | | Ethylene glycol 107-21-1 | 90 - 100 % | 10 d | Yes | | OECD 301 A |

12.2. Persistence and degradability

| Chemical name | degradation rate | test duration | Readily biodegradable | Remarks | Method | | --- | --- | --- | --- | --- | --- | | Ethanolamine 141-43-5 | >90 % | 21 d | Yes | Aerobic biological treatment | |

12.3. Bioaccumulative potential

| Chemical name | Partition coefficient | Bioconcentration factor (BCF) | | --- | --- | --- | | Benzyl alcohol | 1.1 | < 100 | | 100-51-6 | | |

12.3. Bioaccumulative potential

| Chemical name | Partition coefficient | Bioconcentration factor (BCF) | | --- | --- | --- | | Ethylene glycol 107-21-1 | -1.93 | |

12.3. Bioaccumulative potential

| Chemical name | Partition coefficient | Bioconcentration factor (BCF) | | --- | --- | --- | | Ethanolamine 141-43-5 | -2.3 | > 4 |

12.3. Bioaccumulative potential

| Chemical name | Partition coefficient | Bioconcentration factor (BCF) | | --- | --- | --- | | Potassium hydroxide 1310-58-3 | 0.83 | < 500 |

12.4. Mobility in soil

Mobility in soil: No information available. Mobility: No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment: No information available | Chemical name | PBT and vPvB assessment | | --- | --- | | Benzyl alcohol 100-51-6 | The substance is not PBT / vPvB | | Ethylene glycol 107-21-1 | The substance is not PBT / vPvB | | Ethanolamine 141-43-5 | The substance is not PBT / vPvB | | Potassium hydroxide 1310-58-3 | The substance is not PBT / vPvB |
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3267
Shipping Name
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
Transport Class
8
Packing Group
III
IMDG

223, 274

IATA

ERG Code: 8L

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This safety data sheet was created pursuant to the requirements of: Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for CONTROX 778?

The signal word is danger.

What is the physical form of CONTROX 778?

CONTROX 778 is a liquid appearing as liquid with light yellow color. It has characteristic odor.

What are the hazard statements for CONTROX 778?

This substance has 5 hazard statements:

  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H335: May cause respiratory irritation.
  • H373: May cause damage to organs through prolonged or repeated exposure.

What is the melting point of CONTROX 778?

The melting point is Not established and the boiling point is 170 - 206 °C.