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Safety Data Sheet EN

Ethanol 96 % denatured with IPA, MEK and Bitrex

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ethanol 96 % denatured with IPA, MEK and Bitrex
Product Code
147195

Regulatory Identifiers

CAS Number
N/A
UFI Code
AXN5-801H-600H-7SXP

Identified Uses

Laboratory chemicals

Manufacturers & Suppliers

A

AppliChem GmbH

manufacturer

Ottoweg 4, D-64291 Darmstadt

+49 (0)6151 93570

Emergency Contacts

Emergency Contact

+49(0)6151 93570

Mo-Th 08:00 - 17:00 h; Fr 08:00 - 14:30 h

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Eye Irrit. Cat. 2 H319

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403 + P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Mixture of substances listed below with nonhazardous additions.

Chemical Name CAS Number Concentration Hazardous
ethanol EC: 200-578-6 64-17-5 50 - 100% Yes
butanone EC: 201-159-0 78-93-3 1 - 2.5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air; consult doctor in case of complaints.

Symptoms: Dizziness

Skin contact

Wash off with plenty of water. Immediately remove any clothing soiled by the product. If skin irritation continues, consult a doctor.

Symptoms: Irritation to skin

Eye contact

Call a doctor immediately.

Symptoms: Irritation to eyes

Ingestion

make victim drink water (maximum of 2 drinking glasses). Seek medical treatment.

Symptoms: Nausea

Medical Treatment

Treat symptomatically and supportively.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Specific hazards

Combustible. Forms explosive mixtures with air at ambient temperatures. Vapours are heavier than air and may spread along floors. Beware of backfiring. Forms explosive mixtures with air on intense heating.

Firefighter Protection

Wear self-contained respiratory protective device. Wear fully protective suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away. Avoid substance contact. Do not inhale steams/aerosols.

Environmental

danger of explosion! Do not allow to enter sewers/ surface or ground water.

Cleanup methods

Clean up affected area.

Materials: liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust)

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from heat and direct sunlight. Work only in fume cupboard. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air). Keep ignition sources away - Do not smoke. Protect from heat. Protect against electrostatic charges.

Storage

Keep away from heat and direct sunlight.

Fire prevention

Keep ignition sources away - Do not smoke. Protect from heat.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No further data; see item 7.

Hands

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. For the permanent contact gloves made of the following materials are suitable: Butyl rubber, BR. Recommended thickness of the material: ≥ 0.7 mm. Value for the permeation: Level ≥ 480 min. As protection from splashes gloves made of the following materials are suitable: Nitrile rubber, NBR. Recommended thickness of the material: ≥ 0.11 mm. Value for the permeation: Level ≥ 480 min.

Eyes

Tightly sealed goggles

Respiratory

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Use suitable respiratory protective device only when aerosol or mist is formed. Recommended filter device for short term use: Filter AX

Skin/Body

Solvent resistant protective clothing. Flame retardant antistatic protective clothing

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Fluid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colourless
Colour
Colourless
Colour Intensity
---
Form
Liquid
Odor
Alcohol-like
Odor Threshold
Not determined.
Ph
5.7
Melting Point
-114.5 °C
Boiling Point
78 °C
Flash Point
10-13 °C
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined.
Vapor Pressure
57.3 hPa
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
0.79 g/cm³
Flammability
Highly flammable.
Upper Explosive Limit
13.5 Vol %
Lower Explosive Limit
2.5 Vol %
Explosive Limits
---
Auto Ignition Temperature
363-425 °C
Decomposition Temperature
Not determined.
Solubility
---
Partition Coefficient
Not determined.
Solubility In Water
Easily soluble.
Solubility In Fat
---
Molecular Weight
---
Voc Content
100.00 %
Metal Corrosion
---
Dynamic Viscosity
Not determined.
Kinematic Viscosity
Not determined.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

No decomposition if used according to specifications.

Reactivity

Forms explosive gas mixture with air.

Hazardous reactions

Reacts with strong acids. Reacts with oxidising agents. Forms explosive gas mixture with air.

Avoid

Danger of receptacles bursting because of high vapour pressure when heated. Forms explosive gas mixture with air.

Incompatible

alkali metals, alkaline earth metals

Decomposition

In the event of fire: See chapter 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

Aquatic toxicity: No further relevant information available. Type of test Effective concentration Method Assessment 64-17-5 ethanol

No further relevant information available.

12.1 Toxicity

64-17-5 ethanol | EC50/72 h | 275 mg/l (Algae) | | --- | --- | | EC50/48 h | 12,900 mg/l (Algae) | | LC50/24 h | 11,200 mg/l (fish) | | LC50/48 h | 12,340 mg/l (daphnia magna) | | LC50/96 h | 13,000 mg/l (fish) |

12.2 Persistence and degradability

The product is easily biodegradable.

12.3 Bioaccumulative potential

No further relevant information available.

12.4 Mobility in soil

No further relevant information available.

12.5 Results of PBT and vPvB assessment

PBT: Not applicable. vPvB: Not applicable.

12.6 Endocrine disrupting properties

For information on endocrine disrupting properties see section 11.

12.7 Other adverse effects

Additional ecological information: General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Do not allow product to reach ground water, water course or sewage system. Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Chemicals must be disposed of in compliance with the respective national regulations.

Disposal

Must not be disposed together with household garbage.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1170
Shipping Name
ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
Transport Class
3
Packing Group
II
ADR

Warning: Flammable liquids.

IMDG

Warning: Flammable liquids.

IATA

Warning: Flammable liquids.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Ethanol 96 % denatured with IPA, MEK and Bitrex?

The signal word is danger.

What is the physical form of Ethanol 96 % denatured with IPA, MEK and Bitrex?

Ethanol 96 % denatured with IPA, MEK and Bitrex is a fluid appearing as colourless with colourless color. It has alcohol-like odor.

What is Ethanol 96 % denatured with IPA, MEK and Bitrex used for?

Laboratory chemicals

What are the hazard statements for Ethanol 96 % denatured with IPA, MEK and Bitrex?

This substance has 2 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H319: Causes serious eye irritation.

What is the melting point of Ethanol 96 % denatured with IPA, MEK and Bitrex?

The melting point is -114.5 °C and the boiling point is 78 °C.