Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- SIGMADUR 550H HARDENER
- Product Form
- Liquid
- Product Code
- 000001202113
- Synonyms
- 00477199
Regulatory Identifiers
- CAS Number
- N/A
Identified Uses
Hardener. Coating. Professional applications, Used by spraying.
Manufacturers & Suppliers
PPG Industries (Singapore) Pte. Ltd.
manufacturer
No. 1 Tuas Basin Close, Singapore 638803
+65 68653737
Emergency Contacts
CHEMTREC
+(65)-31581349
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS07
GHS08
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Hexamethylene diisocyanate, oligomers (isocyanurate type) | 28182-81-2 | 50 - 100% | Yes |
| n-butyl acetate | 123-86-4 | 3 - 5% | Yes |
| Solvent naphtha (petroleum), light aromatic | 64742-95-6 | 1 - 3% | Yes |
| 1,2,4-trimethylbenzene | 95-63-6 | 1 - 3% | Yes |
| hexamethylene-di-isocyanate | 822-06-0 | 0.1 - 0.3% | Yes |
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Notes
SUB codes represent substances without registered CAS Numbers.
First Aid Measures
Emergency procedures for chemical exposure incidents
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Symptoms: Harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Adverse symptoms may include the following: respiratory tract irritation, coughing, wheezing and breathing difficulties, asthma.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners.
Symptoms: Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: irritation, redness, dryness, cracking.
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.
Symptoms: No known significant effects or critical hazards.
If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting.
Symptoms: No known significant effects or critical hazards.
Immediate Medical Attention
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice. If swallowed, seek medical advice immediately and show the container or label.
Medical Treatment
In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. No specific treatment.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Use dry chemical, CO₂, water spray (fog) or foam.
Do not use water jet.
Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Firefighter Protection
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
The contaminated area should be cleaned immediately with a suitable decontaminant. Add the same decontaminant to the remnants and let stand for several days until no further reaction in an unsealed container. Once this stage is reached, close container and dispose of according to local regulations.
Materials: non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitisation problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.
Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The product is stable.
No specific test data related to reactivity available for this product or its ingredients.
Under normal conditions of storage and use, hazardous reactions will not occur.
In a fire, hazardous decomposition products may be produced.
Keep away from: oxidising agents, strong alkalis, strong acids, amines, alcohols, water. Uncontrolled exothermic reactions occur with amines and alcohols.
Depending on conditions, decomposition products may include the following materials: Cyanate and isocyanate. carbon oxides nitrogen oxides hydrogen cyanide
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
Toxicity
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Endocrine disrupting properties
12.7 Other adverse effects
Persistence/degradability
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Endocrine disrupting properties
12.7 Other adverse effects
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Endocrine disrupting properties
12.7 Other adverse effects
Persistence and degradability
Bioaccumulative potential
12.3 Bioaccumulative potential
12.3 Bioaccumulative potential
12.3 Bioaccumulative potential
Bioaccumulative potential
Mobility in soil
Other adverse effects
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- UN1263
- Shipping Name
- PAINT
- Transport Class
- 3
- Packing Group
- III
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Frequently Asked Questions
Common questions about safety, handling, and properties
What other names is SIGMADUR 550H HARDENER known by?
SIGMADUR 550H HARDENER is also known as: 00477199
What is the hazard signal word for SIGMADUR 550H HARDENER?
The signal word is danger.
What is the physical form of SIGMADUR 550H HARDENER?
SIGMADUR 550H HARDENER is a liquid with colourless. color. It has aromatic. [slight] odor.
What is SIGMADUR 550H HARDENER used for?
Hardener. Coating. Professional applications, Used by spraying.
What are the hazard statements for SIGMADUR 550H HARDENER?
This substance has 5 hazard statements:
- H226: Flammable liquid and vapour.
- H317: May cause an allergic skin reaction.
- H332: Harmful if inhaled.
- H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
- H335: May cause respiratory irritation.