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Safety Data Sheet EN

SIGMACOVER 456 HS HARDENER

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SIGMACOVER 456 HS HARDENER
Product Form
Liquid
Product Code
000001011154
Synonyms
00189958; 00189961

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Professional applications, Used by spraying. Hardener.

Uses advised against

Not applicable.

Manufacturers & Suppliers

P

PPG PMC Japan Co., Ltd.

manufacturer

8F, Shintetsu Bldg., 1-1, Daikaidori 1-chome, Kobe 652-0803 Japan

+81-78-574-2777

Emergency Contacts

Emergency Contact

078 574 2777

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 4
Skin Corr. Cat. 1
Eye Dam. Cat. 1
Skin Sens. Cat. 1
Carc. Cat. 2
Repr. Cat. 1B
STOT SE Cat. 1
STOT SE Cat. 3
STOT RE Cat. 1
Aquatic Acute Cat. 1
Aquatic Chronic Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapor.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H360 May damage fertility or the unborn child.
H372 Causes damage to organs. (central nervous system (CNS), kidneys, liver, respiratory organs)
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Do not breathe vapor.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye or face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER or doctor.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor.
P310 Immediately call a POISON CENTER or doctor.
P333 + P313 If skin irritation or rash occurs: Get medical advice or attention.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Xylene 1330-20-7 15 - 20% No
Fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall-oil fatty acids and triethylenetetramine 68082-29-1 10 - 12.5% No
4-Nonylphenol branched 84852-15-3 7 - 10% No
Poly[oxy(methyl-1,2-ethanediyl)], α-(2-aminomethylethyl)-ω-(2-aminomethylethoxy)-isobutyl alcohol 9046-10-0 7 - 10% No
2,4,6-Tris(dimethylaminomethyl)phenol 78-83-1 7 - 10% No
2,4,6-Tris(dimethylaminomethyl)phenol (continued) 90-72-2 3 - 5% No
Ethyl Benzene 100-41-4 2 - 3% No
Triethylenetetramine 112-24-3 1 - 2% No

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

Symptoms: Causes severe burns. Causes damage to organs following a single exposure in contact with skin. Defatting to the skin. May cause an allergic skin reaction. Adverse symptoms may include the following: pain or irritation, redness, dryness, cracking, blistering may occur, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.

Symptoms: Causes serious eye damage. Adverse symptoms may include the following: pain, watering, redness.

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: Corrosive to the digestive tract. Causes burns. Causes damage to organs following a single exposure if swallowed. Can cause central nervous system (CNS) depression. Adverse symptoms may include the following: stomach pains, reduced fetal weight, increase in fetal deaths, skeletal malformations.

Immediate Medical Attention

Seek immediate medical attention (for eye contact). Seek medical advice immediately (for ingestion).

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Wash spillages into an effluent treatment plant.

Materials: water, inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Hygiene

Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid.
Colour
Colorless.
Colour Intensity
---
Form
---
Odor
Amine-like.
Odor Threshold
---
Ph
---
Melting Point
---
Boiling Point
>37.78°C (>100°F)
Flash Point
Closed cup: 31°C (87.8°F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
0.95
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
335°C (635°F)
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Not soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

When exposed to high temperatures may produce hazardous decomposition products.

Incompatible

Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids.

Decomposition

Depending on conditions, decomposition products may include the following materials: carbon oxides nitrogen oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

12.2 Persistence and degradability

Not readily

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.2 Persistence and degradability

| Product/ingredient name | Aquatic half-life | | Photolysis | | Biodegradability | | | Ethyl Benzene | - | | - | | Readily | |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | Xylene | 3.12 | 7.4 to 18.5 | Low |

12.3 Bioaccumulative potential

Product/ingredient name: 4-Nonylphenol branched, LogP_{ow}: 5.4, BCF: 251.19, Potential: Low

12.3 Bioaccumulative potential

Product/ingredient name: isobutyl alcohol, LogP_ow: 1, BCF: -, Potential: Low

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | 2,4,6-Tris (dimethylaminomethyl)phenol | 0.219 | - | Low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | Ethyl Benzene | 3.6 | 79.43 | Low |

12.3 Bioaccumulative potential

Product/ingredient name: Triethylenetetramine; LogP_ow: -1.66 to -1.4; BCF: -; Potential: Low

Mobility in soil

Soil/Water partition coefficient : Not available. Mobility : Not available.

Other adverse effects

No known significant effects or critical hazards.

12.1 Toxicity

Fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall-oil fatty acids and triethylenetetramine | EC10 1.78 mg/l | Algae | 72 hours

12.1 Toxicity

Product/ingredient name: 4-Nonylphenol branched Result: Acute EC50 0.04 mg/l, Species: Algae - Raphidocelis subcapitata, Exposure: 72 hours Result: Acute EC50 0.044 mg/l, Species: Crustaceans - Moina macrocopa, Exposure: 48 hours Result: Acute LC50 0.221 mg/l, Species: Fish, Exposure: 96 hours

12.1 Toxicity

Poly[oxy(methyl-1,2-ethanediyl)], α-(2-aminomethylethyl)-ω-(2-aminomethylethoxy)-isobutyl alcohol | EC50 15 mg/l | Algae | 72 hours

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

Product/ingredient name: 2,4,6-Tris (dimethylaminomethyl)phenol. Result: Acute EC50 1100 mg/l, Species: Daphnia, Exposure: 48 hours. Result: Acute LC50 >100 mg/l, Species: Daphnia, Exposure: 48 hours.

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.1 Toxicity

Product/ingredient name: Ethyl Benzene Result: Acute LC50 >100 mg/l, Species: Fish, Exposure: 96 hours Result: Acute EC50 1.8 mg/l Fresh water, Species: Daphnia, Exposure: 48 hours Result: Chronic NOEC 1 mg/l Fresh water, Species: Daphnia - Ceriodaphnia dubia, Exposure: -

12.1 Toxicity

12.2 Persistence and degradability

2,4,6-Tris (dimethylaminomethyl)phenol | OECD Ready Biodegradability - Closed Bottle Test | 4 % - Not readily - 28 days

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.2 Persistence and degradability

Product/ingredient name: Ethyl Benzene | Test: - | Result: 79 % - Readily - 10 days | Dose: - | Inoculum: -

12.2 Persistence and degradability

Product/ingredient name: Xylene, Biodegradability: Readily

12.2 Persistence and degradability

Not readily
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3470
Shipping Name
PAINT, CORROSIVE, FLAMMABLE
Transport Class
8 (3)
Packing Group
II
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Regulatory information for Japan regarding SIGMACOVER 456 HS HARDENER.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is SIGMACOVER 456 HS HARDENER known by?

SIGMACOVER 456 HS HARDENER is also known as: 00189958; 00189961

What is the hazard signal word for SIGMACOVER 456 HS HARDENER?

The signal word is danger.

What is the physical form of SIGMACOVER 456 HS HARDENER?

SIGMACOVER 456 HS HARDENER is a liquid appearing as liquid. with colorless. color. It has amine-like. odor.

What is SIGMACOVER 456 HS HARDENER used for?

Professional applications, Used by spraying. Hardener.

What are the hazard statements for SIGMACOVER 456 HS HARDENER?

This substance has 10 hazard statements:

  • H226: Flammable liquid and vapor.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.
  • H360: May damage fertility or the unborn child.
  • H372: Causes damage to organs. (central nervous system (CNS), kidneys, liver, respiratory organs)
  • H410: Very toxic to aquatic life with long lasting effects.