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Safety Data Sheet EN

RESENE ARMOURBOND HARDENER

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
RESENE ARMOURBOND HARDENER

Regulatory Identifiers

CAS Number
N/A

Identified Uses

9342

Manufacturers & Suppliers

Resene Paints Ltd logo

Resene Paints Ltd

manufacturer

32-50 Vogel Street Naense 5011 Wellington New Zealand

+64 4 577 0500

www.resene.co.nz

Emergency Contacts

NZ POISONS (24hr 7 days)

0600 764 766

24hr 7 days

CHEMWATCH EMERGENCY RESPONSE

+800 2436 2286

CHEMWATCH EMERGENCY RESPONSE

+612 9186 1132

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Acute Tox. Cat. 3
Acute Tox. Cat. 4
Skin Sens. Cat. 1
Eye Dam. Cat. 1
Resp. Sens. Cat. 1
Repr. Cat. 2
STOT SE Cat. 2
Aquatic Acute Cat. 3
Aquatic Chronic Cat. 3
Met. Corr. Cat. 1
Skin Corrosion/Inhalation Cat. 1C
STOT SE Cat. 3

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H290 May be corrosive to metals
H311 Toxic in contact with skin
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H332 Harmful if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H361 Suspected of damaging fertility or the unborn child
H371 May cause damage to organs
H412 Harmful to aquatic life with long lasting effects
Harmful if swallowed
Harmful to aquatic life

Precautionary Statements

P201 Obtain special instructions before use.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P405 Store locked up.
P501 Dispose of contents/container to authorized chemical landfill or if organic to high temperature incineration

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
diethylenetriamine 111-40-0 1 - 5% No
diethylenetriamine / MEK ketimine adduct with PGE 68541-07-1 20 - 40% No
hydrocarbons, C6-unsaturated, polymerised 71302-83-5 15 - 30% No
tetranthylenepentamine 112-57-2 10 - 15% No

Notes

See section below for composition of Mixtures

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient clean. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.

Symptoms: Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.

Skin contact

Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. Transport to hospital, or doctor. Injury should be irrigated for 20-30 minutes.

Eye contact

Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. Injury should be irrigated for 20-30 minutes. Eye injuries require saline.

Ingestion

For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay. Milk and water are the preferred diluents. No more than 2 glasses of water should be given to an adult.

Immediate Medical Attention

Transport to hospital or doctor without delay.

Medical Treatment

Respiratory stress is uncommon but present occasionally because of soft tissue edema. Unless exoblaschial intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary. Oxygen is given as indicated. The presence of shock suggests perforation and mandates an intravenous line and fluid administration. Withhold oral feedings initially. If endoscopy confirms transmucosal injury start steroids only within the first 48 hours. Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention. Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing (dysphagia). Management is essentially supportive.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam.

Specific hazards

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result. WARNING: In use may form flammable/ explosive vapour-air mixtures.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Clear area of personnel and move upwind.

Small spill

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material.

Large spill

Clear area of personnel and move upwind.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

DO NOT allow clothing wet with material to stay in contact with skin. The substance accumulates peroxides which may become hazardous only if it evaporates or is distilled or otherwise treated to concentrate the peroxides.

Storage

If slight coloration of the ethyleneamine is acceptable, storage tanks may be made of carbon steel or black iron, provided they are free of rust and mill scale.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Melting Point
Not Available
Freezing Point
---
Dynamic Viscosity
---
Auto Ignition Temperature
---
Physical State
Liquid
Form
---
Relative Evaporation Rate
---
Solubility In Water
Immissible
Flash Point
>100 °C
Voc Content
---
Odor
Not Available
Odor Threshold
Not Available
Ph
Not Available
Softening Point
---
Molecular Weight
---
Appearance
Colourless clear liquid with mild odour
Partition Coefficient
---
Explosive Limits
---
Bulk Density
---
Vapor Density
---
Boiling Point
>115 °C
State Under Standard Conditions
---
Solubility In Fat
---
Physical State Data
liquid
Colour
---
Cloud Point
---
Colour Intensity
---
Solubility
---
Density
---
Vapor Pressure
Not Available
Kinematic Viscosity
300 cSt
Crystallisation Point
---
Metal Corrosion
---
Evaporation Rate
Not Available
Upper Explosive Limit
Not Available
Flammability
Not Applicable
Relative Density
0.998
Solidification Point
---
Decomposition Temperature
---
Properties Status
---
Lower Explosive Limit
Not Available
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Unstable in the presence of incompatible materials.

Reactivity

See section 7

Hazardous reactions

See section 7

Avoid

See section 7

Incompatible

See section 7

Decomposition

See section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2922
Shipping Name
CORROSIVE LIQUID, TOXIC, N.O.S.
Transport Class
Class 8 Subrisk 6.1
Packing Group
III
ADR

Special provisions 220;274 Limited quantity 5 L

IMDG

Special provisions 223.274 Limited Quantities 5 L

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for RESENE ARMOURBOND HARDENER?

The signal word is danger.

What is the physical form of RESENE ARMOURBOND HARDENER?

RESENE ARMOURBOND HARDENER is a liquid appearing as colourless clear liquid with mild odour . It has not available odor.

What is RESENE ARMOURBOND HARDENER used for?

9342

What are the hazard statements for RESENE ARMOURBOND HARDENER?

This substance has 13 hazard statements:

  • H290: May be corrosive to metals
  • H311: Toxic in contact with skin
  • H314: Causes severe skin burns and eye damage
  • H317: May cause an allergic skin reaction
  • H318: Causes serious eye damage
  • H332: Harmful if inhaled
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
  • H335: May cause respiratory irritation
  • H361: Suspected of damaging fertility or the unborn child
  • H371: May cause damage to organs
  • H412: Harmful to aquatic life with long lasting effects
  • Harmful if swallowed
  • Harmful to aquatic life

What is the melting point of RESENE ARMOURBOND HARDENER?

The melting point is Not Available and the boiling point is >115 °C.