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Safety Data Sheet EN

SIGMADUR 188/520/550 HARDENER

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SIGMADUR 188/520/550 HARDENER
Product Code
00293378

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Professional applications, Used by spraying. Coating.

Manufacturers & Suppliers

P

PPG Coatings SPRL/BVBA

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Tweemontstraat 104 B-2100 Deurne Belgium

+32-33606311

Emergency Contacts

PPG Coatings SPRL/BVBA

+31 20 4075210

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Skin Sens. Cat. 1 H317
STOT SE Cat. 3 H335

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.

Precautionary Statements

Wear protective gloves.
Wear eye or face protection.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Avoid breathing vapour.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If skin irritation or rash occurs: Get medical attention.
Store in a well-ventilated place.
Keep cool.
Not applicable.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Mixture

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplace exposure limit and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
hexamethylene diisocyanate, oligomers EC: 500-060-2 28182-81-2 50 - 75% Yes
2-methoxy-1-methylethyl acetate EC: 203-603-9 108-65-6 10 - 25% No
XYLNE EC: 215-535-7 1330-20-7 10 - 25% Yes
ETHYLBENZOL EC: 202-849-4 100-41-4 1 - 3% Yes
diizocyjanian heksametylenu EC: 212-485-8 822-06-0 0.3 - 0.5% Yes

Occupational exposure limits, if available, are listed in Section 8. SUB codes represent substances without registered CAS Numbers.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Harmful if inhaled. May cause respiratory irritation. Adverse symptoms may include respiratory tract irritation, coughing.

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners.

Symptoms: Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction. Adverse symptoms may include irritation, redness, dryness, cracking.

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.

Symptoms: No known significant effects or critical hazards. Adverse symptoms may include pain or irritation, watering, redness.

Ingestion

If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: No known significant effects or critical hazards. No specific data.

Immediate Medical Attention

Seek immediate medical attention (for eye contact). If swallowed, seek medical advice immediately. The exposed person may need to be kept under medical surveillance for 48 hours.

Medical Treatment

No specific treatment.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Gloves: butyl rubber

Eyes

Chemical splash goggles.

Respiratory

By spraying: air-fed respirator. By other operations than spraying, in well ventilated areas, air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Not available.
Colour
Not available.
Colour Intensity
---
Form
---
Odor
Characteristic.
Odor Threshold
Not available.
Ph
Not available.
Melting Point
Not available.
Boiling Point
Not available.
Flash Point
Closed cup: 31C
Freezing Point
Not available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Highest known value: 1.2 kPa (9.3 mm Hg) (at 20C) (ethylbenzene). Weighted average: 0.68 kPa (5.1 mm Hg) (at 20C)
Vapor Density
Highest known value: 4.6 (Air = 1) (2-methoxy-1-methylethyl acetate). Weighted average: 4.15 (Air = 1)
Relative Density
1.07
Bulk Density
---
Density
---
Flammability
Not available. Material supports combustion. Yes.
Upper Explosive Limit
1.74%
Lower Explosive Limit
0.91%
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
Insoluble in the following materials: cold water.
Partition Coefficient
Not available.
Solubility In Water
Insoluble in cold water.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
>0.21 cm2/s
Properties Status
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
PAINT
Transport Class
3
Packing Group
III
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for SIGMADUR 188/520/550 HARDENER?

The signal word is warning.

What is the physical form of SIGMADUR 188/520/550 HARDENER?

SIGMADUR 188/520/550 HARDENER is a liquid. appearing as not available. with not available. color. It has characteristic. odor.

What is the solubility of SIGMADUR 188/520/550 HARDENER?

Insoluble in the following materials: cold water.

What is SIGMADUR 188/520/550 HARDENER used for?

Professional applications, Used by spraying. Coating.

What are the hazard statements for SIGMADUR 188/520/550 HARDENER?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapour.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.

What is the melting point of SIGMADUR 188/520/550 HARDENER?

The melting point is Not available. and the boiling point is Not available..

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