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Safety Data Sheet EN

SIGMADUR 1800 HARDENER

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SIGMADUR 1800 HARDENER
Product Form
Liquid
Product Code
00311112

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Coating. Professional applications, Used by spraying.

Manufacturers & Suppliers

P

PPG Industries (Singapore) Pte. Ltd.

national supplier

No. 1 Tuas Basin Close, Singapore 638803

+65 68653737

Emergency Contacts

CHEMTREC

+(65)-31581349

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 4
Resp. Sens. Cat. 1
Skin Sens. Cat. 1
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H226 Flammable liquid and vapor.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P261 Avoid breathing vapor.
P280 Wear protective gloves.
P284 Wear respiratory protection.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER or doctor if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice or attention.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor.
P352 IF ON SKIN: Wash with plenty of water.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P403 Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Hexamethylene diisocyanate, oligomers (isocyanurate type) 28182-81-2 50 - 100% Yes
n-butyl acetate 123-86-4 3 - 5% Yes
Solvent naphtha (petroleum), light aromatic 64742-95-6 1 - 3% Yes
1,2,4-trimethylbenzene 95-63-6 1 - 3% Yes
hexamethylene-di-isocyanate 822-06-0 0.1 - 0.3% Yes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Notes

SUB codes represent substances without registered CAS Numbers.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Adverse symptoms may include the following: respiratory tract irritation, coughing, wheezing and breathing difficulties, asthma.

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

Symptoms: Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: irritation, redness, dryness, cracking.

Eye contact

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Symptoms: No known significant effects or critical hazards.

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: No known significant effects or critical hazards.

Immediate Medical Attention

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

The contaminated area should be cleaned immediately with a suitable decontaminant. Add the same decontaminant to the remnants and let stand for several days until no further reaction in an unsealed container.

Materials: non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth; decontaminant: water (45 parts), ethanol or isopropyl alcohol (50 parts) and concentrated (d: 0,880) ammonia solution (5 parts) OR sodium carbonate (5 parts) and water (95 parts).

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Precautions should be taken to minimize exposure to atmospheric humidity or water. CO₂ will be formed, which, in closed containers, could result in pressurization.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Language Code
---
Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Colorless.
Colour Intensity
---
Form
---
Odor
Amine-like.
Odor Threshold
---
Ph
insoluble in water.
Melting Point
---
Boiling Point
>37.78°C (>100°F)
Flash Point
Closed cup: 31°C (87.8°F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
Not available.
Vapor Density
---
Relative Density
1.13
Bulk Density
---
Density
---
Flammability
liquid
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Not soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Dynamic (room temperature): Not available.
Kinematic Viscosity
Kinematic (40°C (104°F)): >21 mm²/s (>21 cSt)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

In a fire, hazardous decomposition products may be produced.

Incompatible

Keep away from: oxidizing agents, strong alkalis, strong acids, amines, alcohols, water. Uncontrolled exothermic reactions occur with amines and alcohols.

Decomposition

Depending on conditions, decomposition products may include the following materials: Cyanate and isocyanate. carbon oxides nitrogen oxides hydrogen cyanide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Product/ingredient name: Hexamethylene diisocyanate, oligomers (isocyanurate type) Result: Acute EC50 >1000 mg/l, Species: Algae - scenedesmus subspicatus, Exposure: 72 hours Result: Acute EC50 >100 mg/l, Species: Daphnia - daphnia magna, Exposure: 48 hours Result: Acute LC50 >100 mg/l, Species: Fish - Danio rerio (zebra fish), Exposure: 96 hours

Toxicity

Product/ingredient name: n-butyl acetate Result: Acute LC50 18 mg/l Species: Fish Exposure: 96 hours

Toxicity

Product/ingredient name: Solvent naphtha (petroleum), light aromatic | Result: Acute LC50 8.2 mg/l | Species: Fish | Exposure: 96 hours

Persistence/degradability

Product/ingredient name | Test | Result | Dose | Inoculum | n-butyl acetate | TEPA and OECD 301D | 83 % - Readily - 28 days | - | -

Persistence/degradability

Product/ingredient name: Hexamethylene diisocyanate, oligomers (isocyanurate type); Aquatic half-life: -; Photolysis: -; Biodegradability: Not readily

Persistence/degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | n-butyl acetate | - | - | Readily |

Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | Hexamethylene diisocyanate, oligomers (isocyanurate type) | 5.54 | 3.2 | Low |

Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | n-butyl acetate | 2.3 | - | Low |

Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | 1,2,4-trimethylbenzene | 3.63 | 120.23 | Low |

Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | hexamethylene-di-isocyanate | 0.02 | - | Low |

Mobility in soil

Soil/Water partition coefficient : Not available.

Other adverse effects

No known significant effects or critical hazards.
13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
PAINT
Transport Class
3
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for SIGMADUR 1800 HARDENER?

The signal word is danger.

What is the physical form of SIGMADUR 1800 HARDENER?

SIGMADUR 1800 HARDENER is a liquid. with colorless. color. It has amine-like. odor.

What is SIGMADUR 1800 HARDENER used for?

Coating. Professional applications, Used by spraying.

What are the hazard statements for SIGMADUR 1800 HARDENER?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapor.
  • H317: May cause an allergic skin reaction.
  • H332: Harmful if inhaled.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H335: May cause respiratory irritation.