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Safety Data Sheet EN

SIGMASHIELD 420/460/880/880 GF HARDENER

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SIGMASHIELD 420/460/880/880 GF HARDENER
Product Form
Liquid.
Product Code
50880-TBHRD/5L

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Professional applications, Used by spraying. Coating.

Uses advised against

Not applicable.

Manufacturers & Suppliers

P

PPG Coatings (Kunshan) Co., Ltd

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53 Jinyang Road, Lujia Town, 215331 Kunshan City, Jiangsu Province, P.R. China

86 512 57678859

Emergency Contacts

Emergency Contact

00 86 532 83889090

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 4
Acute Tox. Cat. 4
Acute Tox. Cat. 4
Skin Corr. Cat. 1C
Eye Dam. Cat. 1
Skin Sens. Cat. 1
Carc. Cat. 2
Repr. Cat. 1B
Aquatic Acute Cat. 2
Aquatic Chronic Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapor.
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H351 Suspected of causing cancer.
H401 Toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
May damage fertility or the unborn child.

Precautionary Statements

Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves, protective clothing and eye or face protection.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools.
Take action to prevent static discharges.
Keep container tightly closed.
Use only outdoors or in a well-ventilated area.
Avoid release to the environment.
Avoid breathing vapor.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace.
Collect spillage.
IF exposed or concerned: Get medical advice or attention.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Immediately call a POISON CENTER or doctor.
IF SWALLOWED: Immediately call a POISON CENTER or doctor.
Rinse mouth.
Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
Immediately call a POISON CENTER or doctor.
Wash contaminated clothing before reuse.
IF ON SKIN: Call a POISON CENTER or doctor if you feel unwell.
Wash with plenty of water.
If skin irritation or rash occurs: Get medical advice or attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Store locked up.
Store in a well-ventilated place.
Keep cool.
Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Mixture

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
Epoxy Amine Resin --- 25 - 40% No
xylene isomers mixture EC: 905-215-1 1330-20-7 10 - 25% No
Propylidynetrimethanol, gepropoxyleerd, reactieproducten met ammoniak EC: 500-105-6 39423-51-3 10 - 25% No
ALCOOL BENZYLIQUE EC: 202-859-9 100-51-6 10 - 25% No
2-methylpropan-1-ol 78-83-1 1 - 10% No
bisphenol A EC: 201-245-8 80-05-7 1 - 10% No
M-phenylenebis(methylamine) EC: 216-032-5 1477-55-0 1 - 10% No
ethylbenzene 100-41-4 1 - 10% No
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL 90-72-2 1 - 10% No

Notes

SUB codes represent substances without registered CAS Numbers.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Symptoms: Harmful if inhaled. Adverse symptoms may include reduced fetal weight, increase in fetal deaths, and skeletal malformations.

Skin contact

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

Symptoms: Causes severe burns. Harmful in contact with skin. Defatting to the skin. May cause an allergic skin reaction. Adverse symptoms may include pain or irritation, redness, dryness, cracking, blistering, reduced fetal weight, increase in fetal deaths, and skeletal malformations.

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.

Symptoms: Causes serious eye damage. Adverse symptoms may include pain, watering, and redness.

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

Symptoms: Harmful if swallowed. Adverse symptoms may include stomach pains, reduced fetal weight, increase in fetal deaths, and skeletal malformations.

Immediate Medical Attention

Seek immediate medical attention for eye contact or if swallowed. In case of inhalation of decomposition products in a fire, symptoms may be delayed, and the exposed person may need to be kept under medical surveillance for 48 hours.

Medical Treatment

No specific treatment.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Gloves: nitrile neoprene

Eyes

Chemical splash goggles and face shield.

Respiratory

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Yellowish.
Colour Intensity
---
Form
---
Odor
Characteristic.
Odor Threshold
---
Ph
---
Melting Point
---
Boiling Point
>37.78C (>100F)
Flash Point
Closed cup: 41C (105.8F)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
1.02
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
Upper: 13%
Lower Explosive Limit
Lower: 1.3%
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Not soluble
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (40C): >21 mm2/s
Properties Status
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3469
Shipping Name
PAINT, FLAMMABLE, CORROSIVE
Transport Class
3 (8)
Packing Group
III
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for SIGMASHIELD 420/460/880/880 GF HARDENER?

The signal word is danger.

What is the physical form of SIGMASHIELD 420/460/880/880 GF HARDENER?

SIGMASHIELD 420/460/880/880 GF HARDENER is a liquid. with yellowish. color. It has characteristic. odor.

What is SIGMASHIELD 420/460/880/880 GF HARDENER used for?

Professional applications, Used by spraying. Coating.

What are the hazard statements for SIGMASHIELD 420/460/880/880 GF HARDENER?

This substance has 9 hazard statements:

  • H226: Flammable liquid and vapor.
  • H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled.
  • H314: Causes severe skin burns and eye damage.
  • H317: May cause an allergic skin reaction.
  • H318: Causes serious eye damage.
  • H351: Suspected of causing cancer.
  • H401: Toxic to aquatic life.
  • H410: Very toxic to aquatic life with long lasting effects.
  • May damage fertility or the unborn child.

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