Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- SIGMASHIELD 420/460/880/880 GF HARDENER
- Product Form
- Liquid.
- Product Code
- 50880-TBHRD/5L
- Synonyms
- 00445405
Regulatory Identifiers
- CAS Number
- N/A
Identified Uses
Professional applications, Used by spraying., Coating.
Uses advised against
Not applicable.
Manufacturers & Suppliers
PPG Coatings (Kunshan) Co., Ltd
manufacturer
53 Jinyang Road, Lujia Town, 215331 Kunshan City, Jiangsu Province, P.R. China
86 512 57678859
Emergency Contacts
Emergency Contact
00 86 532 83889090
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS05
GHS07
GHS08
GHS09
Hazard Statements
Precautionary Statements
Get a free compliance audit
Upload your SDS inventory and get a detailed compliance report
Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Epoxy Amine Resin | --- | 25 - 40% | No |
| xylene isomers mixture | 1330-20-7 | 10 - 25% | No |
| Propylidynetrimethanol, propoxylated, reaction products with ammonia | 39423-51-3 | 10 - 25% | No |
| benzyl alcohol | 100-51-6 | 10 - 25% | No |
| 2-methylpropan-1-ol | 78-83-1 | 1 - 10% | No |
| bisphenol A | 80-05-7 | 1 - 10% | No |
| m-phenylenebis(methylamine) | 1477-55-0 | 1 - 10% | No |
| ethylbenzene | 100-41-4 | 1 - 10% | No |
| 2,4,6-tris(dimethylaminomethyl)phenol | 90-72-2 | 1 - 10% | No |
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Notes
SUB codes represent substances without registered CAS Numbers.
First Aid Measures
Emergency procedures for chemical exposure incidents
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Symptoms: Harmful if inhaled. Adverse symptoms may include the following: reduced fetal weight, increase in fetal deaths, skeletal malformations.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.
Symptoms: Causes severe burns. Harmful in contact with skin. Defatting to the skin. May cause an allergic skin reaction. Adverse symptoms may include the following: pain or irritation, redness, dryness, cracking, blistering may occur, reduced fetal weight, increase in fetal deaths, skeletal malformations.
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Symptoms: Causes serious eye damage. Adverse symptoms may include the following: pain, watering, redness.
If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.
Symptoms: Harmful if swallowed. Adverse symptoms may include the following: stomach pains, reduced fetal weight, increase in fetal deaths, skeletal malformations.
Immediate Medical Attention
Seek immediate medical attention for eye contact. If swallowed, seek medical advice immediately.
Medical Treatment
The exposed person may need to be kept under medical surveillance for 48 hours.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Use dry chemical, CO₂, water spray (fog) or foam.
Do not use water jet.
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is very toxic to aquatic life with long lasting effects.
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Firefighter Protection
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material. Wash spillages into an effluent treatment plant.
Materials: water, inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Do not get in eyes or on skin or clothing. Do not ingest.
Store and use away from heat, sparks, open flame or any other ignition source. Eliminate all ignition sources.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Gloves: nitrile neoprene
Chemical splash goggles and face shield.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The product is stable.
No specific test data related to reactivity available for this product or its ingredients.
Under normal conditions of storage and use, hazardous reactions will not occur.
When exposed to high temperatures may produce hazardous decomposition products.
Keep away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong acids.
Depending on conditions, decomposition products may include the following materials: carbon oxides nitrogen oxides
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
The data for this section has not been processed yet.
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- UN3469
- Shipping Name
- PAINT, FLAMMABLE, CORROSIVE
- Transport Class
- 3 (8)
- Packing Group
- III
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Frequently Asked Questions
Common questions about safety, handling, and properties
What other names is SIGMASHIELD 420/460/880/880 GF HARDENER known by?
SIGMASHIELD 420/460/880/880 GF HARDENER is also known as: 00445405
What is the hazard signal word for SIGMASHIELD 420/460/880/880 GF HARDENER?
The signal word is danger.
What is the physical form of SIGMASHIELD 420/460/880/880 GF HARDENER?
SIGMASHIELD 420/460/880/880 GF HARDENER is a liquid. appearing as liquid. yellowish. with yellowish. color. It has characteristic. odor.
What is SIGMASHIELD 420/460/880/880 GF HARDENER used for?
Professional applications, Used by spraying., Coating.
What are the hazard statements for SIGMASHIELD 420/460/880/880 GF HARDENER?
This substance has 9 hazard statements:
- H226: Flammable liquid and vapor.
- H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled.
- H314: Causes severe skin burns and eye damage.
- H317: May cause an allergic skin reaction.
- H318: Causes serious eye damage.
- H351: Suspected of causing cancer.
- H360: May damage fertility or the unborn child.
- H401: Toxic to aquatic life.
- H410: Very toxic to aquatic life with long lasting effects.