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Safety Data Sheet EN

Chromium ICP standard traceable to SRM from NIST Cr(NO₃)₃ in HNO₃ 2-3% 1000 mg/l Cr CertiPUR®

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Chromium ICP standard traceable to SRM from NIST Cr(NO₃)₃ in HNO₃ 2-3% 1000 mg/l Cr CertiPUR®
Product Code
170312

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Reagent for analysis For additional information on uses please refer to the Merck Chemicals portal (www.merck-chemicals.com).

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Met. Corr. Cat. 1 H290

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H290 May be corrosive to metals.
H315 Causes skin irritation.
H319 Causes serious eye irritation.

Precautionary Statements

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Aqueous solution

Chemical Name CAS Number Concentration Hazardous
nitric acid 7697-37-2 1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

fresh air.

Symptoms: Cough, Shortness of breath

Skin contact

wash off with plenty of water. Remove contaminated clothing.

Eye contact

rinse out with plenty of water. Call in ophthalmologist.

Ingestion

immediately make victim drink water (two glasses at most).

Symptoms: methaemoglobinaemia after the uptake of large quantities

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Not combustible. Ambient fire may liberate hazardous vapours.

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up with liquid-absorbent and neutralising material. Dispose of properly. Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions.

Storage

Tightly closed. Store at +15°C to +25°C.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min; splash contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact), KCL 741 Dermatril® L (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Safety glasses

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: Filter P 2 (acc. to DIN 3181) for solid and liquid particles of harmful substances. The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Dynamic Viscosity
---
Form
liquid
Relative Density
ca.1,015 g/cm³ at 20 °C
Molecular Weight
---
Physical State Data
liquid
Auto Ignition Temperature
---
Bulk Density
---
Boiling Point
---
Ph
ca. 0,5 at 20 °C
Metal Corrosion
---
Physical State
liquid
Solubility In Fat
---
Lower Explosive Limit
---
Odor Threshold
---
Odor
odourless
Softening Point
---
Partition Coefficient
---
Decomposition Temperature
---
Relative Evaporation Rate
---
Evaporation Rate
---
Solubility In Water
at 20 °C soluble
Explosive Limits
---
State Under Standard Conditions
---
Crystallisation Point
---
Properties Status
---
Appearance
---
Vapor Density
---
Vapor Pressure
---
Upper Explosive Limit
---
Solubility
---
Colour Intensity
---
Solidification Point
---
Kinematic Viscosity
---
Density
---
Cloud Point
---
Flash Point
---
Flammability
---
Voc Content
---
Freezing Point
---
Melting Point
---
Colour
blue
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

See section 10.3

Hazardous reactions

increased reactivity with: oxidisable substances, organic solvent, Metals, metal alloys, Alkali metals, Alkaline earth metals, Ammonia, alkalines, acids

Avoid

no information available

Incompatible

Metals, metal alloys (generation of hydrogen)

Decomposition

no information available in the event of fire: See section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3264
Shipping Name
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONT. NITRIC ACID SOLUTION)
Transport Class
8
Packing Group
III
ADR

yes

IMDG

yes

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Chromium ICP standard traceable to SRM from NIST Cr(NO₃)₃ in HNO₃ 2-3% 1000 mg/l Cr CertiPUR®?

The signal word is warning.

What is the physical form of Chromium ICP standard traceable to SRM from NIST Cr(NO₃)₃ in HNO₃ 2-3% 1000 mg/l Cr CertiPUR®?

Chromium ICP standard traceable to SRM from NIST Cr(NO₃)₃ in HNO₃ 2-3% 1000 mg/l Cr CertiPUR® is a liquid with blue color. It has odourless odor.

What is Chromium ICP standard traceable to SRM from NIST Cr(NO₃)₃ in HNO₃ 2-3% 1000 mg/l Cr CertiPUR® used for?

Reagent for analysis For additional information on uses please refer to the Merck Chemicals portal (www.merck-chemicals.com).

What are the hazard statements for Chromium ICP standard traceable to SRM from NIST Cr(NO₃)₃ in HNO₃ 2-3% 1000 mg/l Cr CertiPUR®?

This substance has 3 hazard statements:

  • H290: May be corrosive to metals.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.