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Safety Data Sheet EN

Vanadium ICP standard traceable to SRM from NIST NH₄VO₃ in HNO₃ 15% 10000 mg/l V CertiPUR®

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Vanadium ICP standard traceable to SRM from NIST NH₄VO₃ in HNO₃ 15% 10000 mg/l V CertiPUR®
Product Code
170388

Regulatory Identifiers

CAS Number
N/A
REACH No.
This product is a mixture. REACH Registration Number see section 3.

Identified Uses

Reagent for analysis For additional information on uses please refer to the Merck Chemicals portal (www.merck-chemicals.com).

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Met. Corr. Cat. 1 H290
Skin Corr. Cat. 1B H314

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.

Precautionary Statements

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Aqueous solution

Chemical Name CAS Number Concentration Hazardous
nitric acid 7697-37-2 10 - 20% Yes
Ammonium monovanadate 7803-55-6 1 - 3% Yes

The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16. For the full text of the R-phrases mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Call in physician.

Symptoms: Cough, Shortness of breath

Skin contact

After skin contact: wash off with plenty of water. Immediately remove contaminated clothing. If available swab with polyethylene glycol 400. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist.

Ingestion

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Symptoms: Bloody vomiting

Immediate Medical Attention

Call in physician. Call a physician immediately. Immediately call in ophthalmologist.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Not combustible. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: nitrogen oxides

Instructions

Suppress (knock down) gases/vapours/mists with a water spray jet.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid substance contact. Do not breathe vapours, aerosols. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not empty into drains.

Cleanup methods

Collect, bind, and pump off spills. Take up with liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595). Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions.

Storage

Tightly closed. Store at +15°C to +25°C.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. See section 7.1.

Hands

full contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min. splash contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: > 480 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact), KCL 741 Dermatril® L (splash contact).

Eyes

Tightly fitting safety goggles

Respiratory

required when vapours/aerosols are generated. Recommended Filter type: filter E-(P2). The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Skin/Body

Acid-resistant protective clothing

Environmental

Do not empty into drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solidification Point
---
Vapor Pressure
No information available.
Molecular Weight
---
Kinematic Viscosity
---
Appearance
---
Physical State Data
liquid
Properties Status
---
Evaporation Rate
No information available.
Auto Ignition Temperature
No information available.
Crystallisation Point
---
Freezing Point
---
Solubility In Fat
---
Density
---
Odor
odourless
Odor Threshold
No information available.
Upper Explosive Limit
No information available.
Flammability
No information available.
Partition Coefficient
No information available.
Ph
< 1 at 20 °C
Decomposition Temperature
No information available.
Colour Intensity
---
Metal Corrosion
May be corrosive to metals.
Colour
yellow
Boiling Point
No information available.
State Under Standard Conditions
---
Cloud Point
---
Vapor Density
---
Flash Point
No information available.
Bulk Density
---
Form
liquid
Softening Point
---
Explosive Limits
---
Melting Point
No information available.
Dynamic Viscosity
No information available.
Relative Evaporation Rate
---
Solubility In Water
No information available.
Lower Explosive Limit
No information available.
Voc Content
---
Physical State
liquid
Relative Density
ca.1,093 g/cm³ at 20 °C
Solubility
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

See section 10.3

Hazardous reactions

Risk of explosion with: Risk of ignition or formation of inflammable gases or vapours with: Alkali metals, Alkaline earth metals, Ammonia, alkalines, hydrides, halogens, halogen compounds, nonmetallic oxides, nonmetallic halides, nonmetallic hydrogen compounds, nonmetals, phosphides, nitrides, lithium silicide, hydrogen peroxide, organic combustible substances, oxidisable substances, organic solvent, Alcohols, Ketones, Aldehydes, anhydrides, Amines, anilines, Nitriles, organic nitro compounds, hydrazine and derivatives, acetylcholine, Metals, metal alloys, metallic oxides, acids

Avoid

no information available

Incompatible

Metals, metal alloys (generation of hydrogen)

Decomposition

in the event of fire: See section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 2031
Shipping Name
NITRIC ACID
Transport Class
8
Packing Group
II
ADR

yes

IMDG

yes

IATA

yes

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Vanadium ICP standard traceable to SRM from NIST NH₄VO₃ in HNO₃ 15% 10000 mg/l V CertiPUR®?

The signal word is danger.

What is the physical form of Vanadium ICP standard traceable to SRM from NIST NH₄VO₃ in HNO₃ 15% 10000 mg/l V CertiPUR®?

Vanadium ICP standard traceable to SRM from NIST NH₄VO₃ in HNO₃ 15% 10000 mg/l V CertiPUR® is a liquid with yellow color. It has odourless odor.

What is Vanadium ICP standard traceable to SRM from NIST NH₄VO₃ in HNO₃ 15% 10000 mg/l V CertiPUR® used for?

Reagent for analysis For additional information on uses please refer to the Merck Chemicals portal (www.merck-chemicals.com).

What are the hazard statements for Vanadium ICP standard traceable to SRM from NIST NH₄VO₃ in HNO₃ 15% 10000 mg/l V CertiPUR®?

This substance has 2 hazard statements:

  • H290: May be corrosive to metals.
  • H314: Causes severe skin burns and eye damage.

What is the melting point of Vanadium ICP standard traceable to SRM from NIST NH₄VO₃ in HNO₃ 15% 10000 mg/l V CertiPUR®?

The melting point is No information available. and the boiling point is No information available..