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Safety Data Sheet EN

Copper ICP standard traceable to SRM from NIST Cu(NO₃)₂ in HNO₃ 2-3% 1000 mg/l Cu CertiPUR®

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Copper ICP standard traceable to SRM from NIST Cu(NO₃)₂ in HNO₃ 2-3% 1000 mg/l Cu CertiPUR®
Product Code
170314

Regulatory Identifiers

CAS Number
N/A
REACH No.
This product is a mixture. REACH Registration Number see section 3.

Identified Uses

Reagent for analysis For additional information on uses please refer to the Merck Chemicals portal (www.merck-chemicals.com).

Manufacturers & Suppliers

M

Merck KGaA

manufacturer

64271 Darmstadt, Germany

+49 6151 72-0

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Aquatic Chronic Cat. 3 H412
Met. Corr. Cat. 1 H290

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H290 May be corrosive to metals.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Nitric acid solution.

Chemical Name CAS Number Concentration Hazardous
nitric acid 7697-37-2 1 - 5% Yes
Copper(II) nitrate 3251-23-8 0.25 - 1% Yes

The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air.

Symptoms: Cough, Shortness of breath

Skin contact

After skin contact: wash off with plenty of water. Remove contaminated clothing.

Symptoms: irritant effects

Eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist.

Symptoms: irritant effects

Ingestion

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

Symptoms: irritant effects

Immediate Medical Attention

Call in ophthalmologist (for eye contact), Consult a physician (for swallowing).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable media

For this substance/mixture no limitations of extinguishing agents are given.

Specific hazards

Ambient fire may liberate hazardous vapours.

Firefighter Protection

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental

Do not let product enter drains.

Cleanup methods

Take up with liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595). Dispose of properly. Clean up affected area.

Materials: liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Observe label precautions.

Storage

Tightly closed. Store at +15°C to +25°C.

Hygiene

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment.

Hands

full contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: >480 min; splash contact: Glove material: Nitrile rubber, Glove thickness: 0,11 mm, Break through time: >480 min. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact), KCL 741 Dermatril® L (splash contact).

Eyes

Safety glasses

Respiratory

required when vapours/aerosols are generated.

Skin/Body

protective clothing

Environmental

Do not let product enter drains.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
blue
Colour Intensity
---
Form
liquid
Odor
odourless
Odor Threshold
---
Ph
ca. 0,5 at 20 °C
Melting Point
---
Boiling Point
---
Flash Point
---
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
ca.1,014 g/cm³ at 20 °C
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
soluble at 20 °C
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is chemically stable under standard ambient conditions (room temperature).

Reactivity

See section 10.3

Hazardous reactions

increased reactivity with: oxidisable substances, organic solvent, Metals, metal alloys, Alkali metals, Alkaline earth metals, Ammonia, alkalines, acids

Avoid

no information available

Incompatible

Metals, metal alloys

Decomposition

in the event of fire: See section 5.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 3264
Shipping Name
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONT. NITRIC ACID SOLUTION)
Transport Class
8
Packing Group
III
ADR

yes

IMDG

yes

IATA

no

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

Take note of Dir 94/33/EC on the protection of young people at work.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Copper ICP standard traceable to SRM from NIST Cu(NO₃)₂ in HNO₃ 2-3% 1000 mg/l Cu CertiPUR®?

The signal word is warning.

What is the physical form of Copper ICP standard traceable to SRM from NIST Cu(NO₃)₂ in HNO₃ 2-3% 1000 mg/l Cu CertiPUR®?

Copper ICP standard traceable to SRM from NIST Cu(NO₃)₂ in HNO₃ 2-3% 1000 mg/l Cu CertiPUR® is a liquid with blue color. It has odourless odor.

What is Copper ICP standard traceable to SRM from NIST Cu(NO₃)₂ in HNO₃ 2-3% 1000 mg/l Cu CertiPUR® used for?

Reagent for analysis For additional information on uses please refer to the Merck Chemicals portal (www.merck-chemicals.com).

What are the hazard statements for Copper ICP standard traceable to SRM from NIST Cu(NO₃)₂ in HNO₃ 2-3% 1000 mg/l Cu CertiPUR®?

This substance has 4 hazard statements:

  • H290: May be corrosive to metals.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H412: Harmful to aquatic life with long lasting effects.