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Safety Data Sheet EN

LOCTITE STYCAST US 5536 PTA known as HYSOL US5536 PART A 5 GAL

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE STYCAST US 5536 PTA known as HYSOL US5536 PART A 5 GAL
Product Code
UA5536-B80

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Part A for 2-K-Polyurethane adhesive and sealant

Uses advised against

None identified

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way Rocky Hill, Connecticut 06067

+1 (860) 571-5100

http://www.henkelna.com

Emergency Contacts

Poison Control Center

1-877-671-4608

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Eye Irrit. Cat. 2A H319
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317
STOT RE Cat. 1 H372

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 CAUSES SKIN IRRITATION.
H317 MAY CAUSE AN ALLERGIC SKIN REACTION.
H319 CAUSES SERIOUS EYE IRRITATION.
H332 HARMFUL IF INHALED.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

Precautionary Statements

P260 Do not breathe vapors, mist, or spray.
P264 Wash affected area thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves, eye protection, and face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P342 + P311 If experiencing respiratory symptoms: Call a poison center or physician.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Methylene bis(phenylisocyanate) 101-68-8 30 - 60% Yes
Polymeric diphenylmethane diisocyanate 9016-87-9 30 - 60% Yes
Methylene bisphenyl isocyanate 26447-40-5 10 - 30% Yes
o-(p-Isocyanatobenzyl)phenyl isocyanate 5873-54-1 1 - 5% Yes

Notes

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Symptoms: Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Extreme asthmatic reactions can be life threatening.

Skin contact

Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. If symptoms develop and persist, get medical attention. Wash clothing before reuse.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Symptoms: Workplace vapors have produced reversible corneal epithelial edema impairing vision.

Ingestion

Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention.

Immediate Medical Attention

Get medical attention.

Medical Treatment

Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Skin: This compound is a known skin sensitizer. Treat symptomatically as for contact dermatitis or thermal burns. Ingestion: Treat symptomatically. Respiratory: This compound is a known pulmonary sensitizer.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray (fog), foam, dry chemical or carbon dioxide.

Specific hazards

Sealed containers at elevated temperatures or contaminated with water may rupture explosively. During a fire, MDI vapors and other irritating, highly toxic gases may be generated by thermal decomposition or combustion.

Instructions

In case of fire, keep containers cool with water spray.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up.

Small spill

For minor spills, absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well ventilated area (outside) and treat with neutralizing solution: mixture of 80% water and 20% non-ionic surfactant Tergitol TMN-10; or 90% water, 3-8% concentrated ammonia and 2% detergent. Add about ten parts of neutralizer per part of isocyanate, with mixing. Allow to stand uncovered for 48 hours to let carbon dioxide escape.

Large spill

Large quantities may be pumped into closed, but not sealed containers for disposal.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. If temporary control of isocyanate vapor is required, a blanket of protein foam (available at most fire departments) may be placed over spill. Large quantities may be pumped into closed, but not sealed containers for disposal. For minor spills, absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well ventilated area (outside) and treat with neutralizing solution.

Materials: sawdust or other absorbent

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Exposure to vapors of heated MDI can be extremely dangerous. Protect from moisture. Keep away from heat, spark and flame.

Storage

Store at or below 30 °C (86°F). Store in tightly closed containers to prevent moisture contamination. Do not reseal if contamination is suspected. Store in a cool, dry place under low relative humidity, away from excessive heat.

Hygiene

Wash thoroughly after handling.

Fire prevention

Keep away from heat, spark and flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Dark brown
Colour Intensity
---
Form
---
Odor
Musty
Odor Threshold
Not available.
Ph
Not available.
Melting Point
Not available.
Boiling Point
> 200 °C (> 392°F)1,013 hPa
Flash Point
225.6 °C (438.08 °F) Flash Point, Pensky-Martens
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
< 0.0001 mm hg (25 °C (77°F))
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1.24 at 25 °C (77°F)
Flammability
Not applicable
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
Reacts slowly with water to liberate carbon dioxide gas. Water
Partition Coefficient
Not available.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
0 % (value for resin and hardener together) (estimated)
Metal Corrosion
---
Dynamic Viscosity
Not available.
Kinematic Viscosity
Not available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of storage and use.

Reactivity

Not available.

Hazardous reactions

Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols.

Avoid

Keep away from heat, spark and flame. High temperatures. Contamination with water. Store away from incompatible materials.

Incompatible

Water. Amines. Strong bases. Alcohols. Copper alloys.

Decomposition

Thermal decomposition can lead to release of irritating gases and vapors. Hydrogen cyanide. MDI vapors and aerosols. Oxides of carbon. Oxides of nitrogen.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3082
Shipping Name
RQ, Environmentally hazardous substance, liquid, n.o.s.
Transport Class
9
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LOCTITE STYCAST US 5536 PTA known as HYSOL US5536 PART A 5 GAL?

The signal word is danger.

What is the physical form of LOCTITE STYCAST US 5536 PTA known as HYSOL US5536 PART A 5 GAL?

LOCTITE STYCAST US 5536 PTA known as HYSOL US5536 PART A 5 GAL is a liquid with dark brown color. It has musty odor.

What is the solubility of LOCTITE STYCAST US 5536 PTA known as HYSOL US5536 PART A 5 GAL?

Reacts slowly with water to liberate carbon dioxide gas. Water

What is LOCTITE STYCAST US 5536 PTA known as HYSOL US5536 PART A 5 GAL used for?

Part A for 2-K-Polyurethane adhesive and sealant

What are the hazard statements for LOCTITE STYCAST US 5536 PTA known as HYSOL US5536 PART A 5 GAL?

This substance has 6 hazard statements:

  • H315: CAUSES SKIN IRRITATION.
  • H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
  • H319: CAUSES SERIOUS EYE IRRITATION.
  • H332: HARMFUL IF INHALED.
  • H334: MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
  • H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.

What is the melting point of LOCTITE STYCAST US 5536 PTA known as HYSOL US5536 PART A 5 GAL?

The melting point is Not available. and the boiling point is > 200 °C (> 392°F)1,013 hPa.