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Safety Data Sheet EN

LOCTITE HHD 3652 20KG

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
LOCTITE HHD 3652 20KG
Product Code
2931958

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Polyurethane Hot Melt

Uses advised against

None identified

Manufacturers & Suppliers

Henkel Corporation logo

Henkel Corporation

manufacturer

One Henkel Way, Rocky Hill, Connecticut 06067

+1 (860) 571-5100

www.henkelna.com

Emergency Contacts

Poison Control Center

1-877-671-4608

Poison Control Center

1-303-592-1711

CHEMTREC

1-800-424-9300

CHEMTREC

1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2A
Resp. Sens. Cat. 1
Skin Sens. Cat. 1
STOT SE Cat. 3
STOT RE Cat. 1

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H242 STATIC CHARGES GENERATED BY EMPTYING PACKAGE IN OR NEAR FLAMMABLE VAPORS MAY CAUSE IGNITION.
H315 CAUSES SKIN IRRITATION.
H317 MAY CAUSE AN ALLERGIC SKIN REACTION.
H319 CAUSES SERIOUS EYE IRRITATION.
H332 HARMFUL IF INHALED.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H335 VAPORS ABOVE MOLTEN ADHESIVE MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
H335 MAY CAUSE RESPIRATORY IRRITATION.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
MOLTEN ADHESIVE MAY CAUSE SEVERE BURNS.

Precautionary Statements

P233 Keep container tightly closed.
P264 Wash affected area thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves, eye protection, and face protection.
P285 In case of inadequate ventilation wear respiratory protection.
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a POISON CENTER or physician if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P337 + P313 If eye irritation persists: Get medical attention.
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P342 + P311 If experiencing respiratory symptoms: Call a poison center or physician.
P351 IF IN EYES: Rinse cautiously with water for several minutes.
P352 IF ON SKIN: Wash with plenty of water.
P362 Take off contaminated clothing.
P403 Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.
Do not breathe dust or fumes.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Polyurethane --- 80 - 100% Yes
Methylenebis(phenylisocyanate) 101-68-8 1 - 5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If not breathing, give artificial respiration. If breathing is difficult, oxygen should be administered by qualified personnel. Move to fresh air. If symptoms persist, seek medical advice.

Symptoms: Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours.

Skin contact

Cool skin rapidly with cold water after contact with molten material. Cover affected areas with clean sheeting or gauze and seek immediate medical attention. No attempt should be made to remove material from skin or to remove contaminated clothing as damaged skin can be easily torn.

Symptoms: Molten adhesive may cause severe burns.

Eye contact

If eye contact occurs with molten material immediately cool with water. Do not remove adhesive. Seek medical attention.

Ingestion

Seek immediate medical attention. Do not induce vomiting. Never give anything by mouth to an unconscious person.

Immediate Medical Attention

Seek immediate medical attention.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water spray (fog), foam, dry chemical or carbon dioxide. Use extinguishing measures appropriate to local circumstances and the surrounding environment.

Specific hazards

Sealed containers at elevated temperatures or contaminated with water may rupture explosively.

Instructions

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Keep unnecessary personnel away. In case of fire, keep containers cool with water spray.

Firefighter Protection

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Environmental

Do not allow product to enter sewer or waterways.

Cleanup methods

If product is spilled in the solid state, pick up and place in an appropriate waste disposal container. If product is spilled in the molten state, allow product to solidify before scraping up and disposing of in an appropriate waste disposal container.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Always be careful around molten material. Avoid skin contact with molten resins. See Section 8 of the SDS for Personal Protective Equipment. Precaution - this product should only be heated to recommended temperatures. Hazards of pyrolysis products emitted are unknown and may be hazardous to health. If recommended temperature is exceeded, there is an increased possibility that MDI may be released. Follow suggested application temperature. Use caution if using container unloading equipment that inverts product, in order to avoid dislodging product prematurely. Do not place wet or damp solid into melt tank.

Storage

Store between 5 °C (41°F) and 35 °C (95°F). Do not let moisture contaminate this material. Product reacts with water to release carbon dioxide, which could build up pressure in closed containers and lead to bursting. Do not reseal if moisture contamination is suspected. Store in original container until ready to use.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Molecular Weight
---
Density
---
Auto Ignition Temperature
Not available.
Properties Status
---
Metal Corrosion
---
Ph
Not applicable
Voc Content
Not available.
Physical State Data
solid
Solubility
---
State Under Standard Conditions
---
Cloud Point
---
Odor
Resinous
Softening Point
---
Colour
amber
Partition Coefficient
Not available.
Decomposition Temperature
Not available.
Form
---
Boiling Point
Not available.
Melting Point
Not available.
Physical State
solid
Flammability
Not applicable
Flash Point
200 - 300 °C (392°F - 572°F) Internal Henkel specification
Solubility In Fat
---
Bulk Density
---
Dynamic Viscosity
4,500 - 6,000 cp
Appearance
---
Upper Explosive Limit
Not available.
Freezing Point
---
Relative Density
---
Vapor Density
Not available.
Explosive Limits
---
Solubility In Water
Not available.
Solidification Point
---
Odor Threshold
Not available.
Relative Evaporation Rate
---
Colour Intensity
---
Vapor Pressure
Not available.
Crystallisation Point
---
Evaporation Rate
Not available.
Lower Explosive Limit
Not available.
Kinematic Viscosity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of storage and use.

Reactivity

MDI reacts slowly with water to form carbon dioxide gas.

Hazardous reactions

Exothermic. Polymerization may occur at elevated temperature or in the presence of incompatible materials.

Avoid

Avoid moisture. Container can be pressurised by carbon dioxide due to reaction with humid air and/or water. Extremes of temperature and direct sunlight. Contamination with water.

Incompatible

Water. Alcohols. Amines. Moisture. Strong acids and strong bases. Strong oxidizing agents.

Decomposition

Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Hydrogen cyanide. Isocyanate vapors

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for LOCTITE HHD 3652 20KG?

The signal word is danger.

What is the physical form of LOCTITE HHD 3652 20KG?

LOCTITE HHD 3652 20KG is a solid with amber color. It has resinous odor.

What is LOCTITE HHD 3652 20KG used for?

Polyurethane Hot Melt

What are the hazard statements for LOCTITE HHD 3652 20KG?

This substance has 10 hazard statements:

  • H242: STATIC CHARGES GENERATED BY EMPTYING PACKAGE IN OR NEAR FLAMMABLE VAPORS MAY CAUSE IGNITION.
  • H315: CAUSES SKIN IRRITATION.
  • H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
  • H319: CAUSES SERIOUS EYE IRRITATION.
  • H332: HARMFUL IF INHALED.
  • H334: MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
  • H335: VAPORS ABOVE MOLTEN ADHESIVE MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
  • H335: MAY CAUSE RESPIRATORY IRRITATION.
  • H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
  • MOLTEN ADHESIVE MAY CAUSE SEVERE BURNS.

What is the melting point of LOCTITE HHD 3652 20KG?

The melting point is Not available. and the boiling point is Not available..