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Safety Data Sheet EN

Tandemol H 674 I-LV

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Tandemol H 674 I-LV

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Formulation additives, lubricants and greases - Industrial Metal Rolling Lubricant

Manufacturers & Suppliers

T

TotalEnergies Lubrifiants

manufacturer

562 Avenue du Parc de L'île, 92029 Nanterre Cedex FRANCE

+33 (0)1 41 35 40 00

T

TOTAL BELGIUM

national supplier

Handelsstraat, 93, Rue du Commerce, B-1040 BRUSSEL - BRUXELLES, België - Belgique

+32 (0)22 889 933

Emergency Contacts

Hopital Militaire Reine Astrid - Militair Hospitaal Koningin Astrid

+32 (0)2 264 48 48

Algemeen centrum Ziekenhuis

+32 (0)3 217 71 11

Centre Universitaire UZ Gand-Universitair Ziekenhuis UZ Gent

+32 (0)9 240 34 90

U.Z. Leuven

+32 (0)16 34 87 50

Hôpital Saint Joseph et Sainte Thérèse, section I.M.T. R

+32 (0)71 44 80 00

CHU Liège domaine Universitaire du Sart Tilman

+32 (0)4 366 72 94

Poison center

+32 (0)70 245 245

Emergency Contact

+44 1235 239670

Teleserv S.O.S Total Belgium

+32 (0)78 15 51 51

On duty staff in Ertvelde (Lub)

+32 (0)475 66 07 77

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Eye Dam. Cat. 1 H318

GHS Pictograms

GHS05 - Corrosive

GHS05

Hazard Statements

H318 Causes serious eye damage.

Precautionary Statements

P280 Wear eye/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Distillates (petroleum), hydrotreated light naphthenic EC: 265-156-6 64742-53-6 10 - 25% Yes
Fatty acids, C16-18 and C18-unsatd., compds. with triethanolamine EC: 270-279-3 68424-19-1 10% Yes
Alcohols, C12-15, ethoxylated, phosphates EC: 500-185-2 68071-35-2 8.3% Yes
2-amino-2-methylpropanol EC: 204-709-8 124-68-5 1.6% Yes
Alcohols, C12-15, ethoxylated EC: 500-195-7 68131-39-5 1% Yes
Alcohols, C12-13, ethoxylated EC: 500-165-3 66455-14-9 1% Yes
methyl-1H-benzotriazole EC: 249-596-6 29385-43-1 1% Yes
diphenyl ether EC: 202-981-2 101-84-8 0.1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No specific data.

Skin contact

Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: Chemical burns.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.

Symptoms: Chemical burns.

Ingestion

Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: Chemical burns.

Immediate Medical Attention

Get medical attention immediately. Call a poison center or physician.

Medical Treatment

Chemical burns must be treated promptly by a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

In a fire or if heated, a pressure increase will occur and the container may burst.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.

Small spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Materials: inert dry material, non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Hydrocarbon-proof gloves, nitrile rubber, butyl rubber, Fluorinated rubber. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. In case of prolonged contact with the product, it is recommended to wear gloves

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respirator with combination filter for vapor/particulate Type A/P1 Warning! filters have a limited use duration. The use of breathing apparatus must comply strictly with the manufacturer's instructions and the regulations governing their choices and uses. None under normal use conditions.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid. [Clear.]
Colour
Yellow.
Colour Intensity
---
Form
---
Odor
Characteristic.
Odor Threshold
Not available.
Ph
8.3 [Conc. (% w/w): 5%]
Melting Point
---
Boiling Point
---
Flash Point
Closed cup: ≥140°C [ASTM D 93]
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not available.
Vapor Pressure
---
Vapor Density
---
Relative Density
0.91
Bulk Density
---
Density
---
Flammability
Not available.
Upper Explosive Limit
Not available.
Lower Explosive Limit
Not available.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
Not available.
Solubility
Not available.
Partition Coefficient
Not applicable.
Solubility In Water
No.
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
Kinematic (40°C): 34 mm²/s
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

No specific data.

Incompatible

Strong oxidizing agents strong acids Strong bases

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

| Product/substance | Result | Species | Exposure | Test | | --- | --- | --- | --- | --- | | Distillates (petroleum), hydrotreated light naphthenic | Acute EC50 >1000 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute LC50 5001 mg/l | Fish | 96 hours | - |

12.1 Toxicity

| Product/substance | Result | Species | Exposure | Test | | --- | --- | --- | --- | --- | | 2-amino-2-methylpropanol | Acute EC50 520 mg/l | Algae - Desmodesmus subspicatus | 72 hours | - | | | Acute EC50 179 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute LC50 190 mg/l | Fish | 96 hours | - |

12.1 Toxicity

| Product/substance | Result | Species | Exposure | Test | | --- | --- | --- | --- | --- | | Alcohols, C12-15, ethoxylated | Acute EC50 0.7 mg/l Fresh water | Algae - Pseudokirchneriella subcapitata | 96 hours | - | | | Acute EC50 0.39 mg/l Fresh water | Crustaceans - Ceriodaphnia dubia - Neonate | 48 hours | - | | | Acute EC50 0.14 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute LC50 1400 μg/l Fresh water | Fish - Pimephales promelas | 96 hours | - | | | Chronic NOEC 1 mg/l Fresh water | Algae - Pseudokirchneriella subcapitata | 96 hours | - | | | Chronic NOEC 83 μg/l Fresh water | Daphnia - Daphnia magna - Neonate | 21 days | - | | | Chronic NOEC 83 μg/l Fresh water | Algae - Daphnia Magna | 48 hours | - |

12.1 Toxicity

| Product/substance | Result | Species | Exposure | Test | | --- | --- | --- | --- | --- | | Alcohols, C12-13, ethoxylated | Acute EC50 0.46 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute EC50 460 μg/l Fresh water | Fish | 96 hours | - | | | Acute LC50 0.96 mg/l | Daphnia - Daphnia Magna | 21 days | - | | | Chronic NOEC 0.77 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | OECD 201 | | | Chronic NOEC 0.77 mg/l | Crustaceans - Daphnia galatea | 48 hours | OECD 202 |

12.1 Toxicity

| Product/substance | Result | Species | Exposure | Test | | --- | --- | --- | --- | --- | | methyl-1H-benzotriazole | Acute EC50 75 mg/l | Fish - Cyprinodon variegatus | 96 hours | OECD 203 | | | Acute LC50 8.58 mg/l | Algae - Desmodesmus subspicatus | 72 hours | OECD 201 | | | Acute LC50 55 mg/l | Crustaceans - Daphnia galatea | 21 days | OECD 211 | | | Chronic EC50 2.86 mg/l | Algae - Pseudokirchneriella subcapitata | 72 hours | - | | | Chronic NOEC 0.4 mg/l | Crustaceans - Daphnia galatea | 96 hours | - |

12.1 Toxicity

| Product/substance | Result | Species | Exposure | Test | | --- | --- | --- | --- | --- | | diphenyl ether | Acute EC50 0.304 mg/l | Algae - Pseudokirchneriella subcapitata | 96 hours | - | | | Acute EC50 800 μg/l | Algae - Skeletonema costatum | 96 hours | - | | | Marine water | Daphnia - Daphnia magna | 48 hours | - | | | Acute LC50 1.96 mg/l | Daphnia - Daphnia magna | 48 hours | - | | | Acute LC50 670 μg/l Fresh water | Fish | 96 hours | - | | | Acute LC50 4.2 mg/l | Fish - Lepomis macrochirus | 96 hours | - | | | Acute LC50 1.7 mg/l Fresh water | Algae - Pseudokirchneriella subcapitata | 72 hours | - |

12.2 Persistence and degradability

| Product/substance | Test | Result | Dose | Inoculum | | --- | --- | --- | --- | --- | | methyl-1H-benzotriazole | OECD 301D | 4 % - Not readily - 28 days | - | Activated sludge |

12.2 Persistence and degradability

| Product/substance | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | Distillates (petroleum), hydrotreated light naphthenic | - | - | Not readily |

12.2 Persistence and degradability

| Product/substance | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | Fatty acids, C16-18 and C18-unsatd., compds. with triethanolamine | - | - | Readily |

12.2 Persistence and degradability

| Product/substance | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | 2-amino-2-methylpropanol | - | - | Readily |

12.2 Persistence and degradability

| Product/substance | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | Alcohols, C12-15, ethoxylated | - | - | Readily |

12.2 Persistence and degradability

| Product/substance | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | Alcohols, C12-13, ethoxylated | - | - | Readily |

12.2 Persistence and degradability

| Product/substance | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | methyl-1H-benzotriazole | - | - | Not readily |

12.1 Toxicity

12.2 Persistence and degradability

| Product/substance | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | diphenyl ether | - | - | Readily |

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Endocrine disrupting properties

12.7 Other adverse effects

12.3 Bioaccumulative potential

| Product/substance | LogK_{ow} | BCF | Potential | | --- | --- | --- | --- | | 2-amino-2-methylpropanol | -0.63 | 320 | low |

12.3 Bioaccumulative potential

| Product/substance | LogK_{ow} | BCF | Potential | | --- | --- | --- | --- | | Alcohols, C12-15, ethoxylated | 2.03 to 6.24 | - | high |

12.3 Bioaccumulative potential

| Product/substance | LogK_{ow} | BCF | Potential | | --- | --- | --- | --- | | Alcohols, C12-13, ethoxylated | 2.03 to 5.26 | - | low |

12.3 Bioaccumulative potential

| Product/substance | LogK_{ow} | BCF | Potential | | --- | --- | --- | --- | | methyl-1H-benzotriazole | 1.1 | - | low |

12.3 Bioaccumulative potential

| Product/substance | LogK_{ow} | BCF | Potential | | --- | --- | --- | --- | | diphenyl ether | 4.21 | 200 | low |

12.4 Mobility in soil

Soil/water partition coefficient (Koc) : Not available. Mobility : Not available. Mobility in soil : Given its physical and chemical characteristics, the product generally shows low soil mobility. Loss by evaporation is limited. Forms an emulsion

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

The mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects

No known significant effects or critical hazards.

No known significant effects or critical hazards.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Disposal

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Waste Codes

12 01 09* EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Tandemol H 674 I-LV?

The signal word is danger.

What is the physical form of Tandemol H 674 I-LV?

Tandemol H 674 I-LV is a liquid. appearing as liquid. [clear.] with yellow. color. It has characteristic. odor.

What is the solubility of Tandemol H 674 I-LV?

Not available.

What is Tandemol H 674 I-LV used for?

Formulation additives, lubricants and greases - Industrial Metal Rolling Lubricant

What are the hazard statements for Tandemol H 674 I-LV?

This substance has 1 hazard statement:

  • H318: Causes serious eye damage.