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Safety Data Sheet EN

605100 R11634A

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
605100 R11634A

Regulatory Identifiers

CAS Number
N/A
UFI Code
0845-701W-000W-4SAC

Identified Uses

Heavy Duty Diesel

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Eye Irrit. Cat. 2 H319
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P264 Wash thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Mineral oil --- 20 - 50% Yes
Calcium branched alkyl phenate sulphide (overbased) --- 1 - 5% Yes
zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) EC: 218-679-9 --- 1 - 3% Yes
Butanedioic acid, 2,3-dihydroxy-, mixed C12-16-alkyl and C13-rich C11-14-isoalkyl diesters, (2R,3R)-rel- EC: 482-100-8 --- 1 - 3% Yes
Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC: 253-249-4 --- 1 - 5% Yes
Phenol, dodecyl-, branched EC: 310-154-3 --- 0.01 - 0.25% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash with soap and water. Launder contaminated clothing before reuse.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Rinse mouth.

Immediate Medical Attention

If eye irritation persists: Get medical advice/attention. If skin irritation occurs, get medical attention. Get medical attention if symptoms occur (ingestion).

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

No unusual fire or explosion hazards noted.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Personal Protective Equipment must be worn, see Personal Protection Section for PPE recommendations.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with eyes. Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid environmental contamination. Keep container closed when not in use.

Storage

Keep container closed when not in use.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling.

Fire prevention

Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or grounding procedures.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No special requirements under ordinary conditions of use and with adequate ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Supplementary local exhaust ventilation, closed systems, or respiratory and eye protection may be needed in special circumstances, such as poorly ventilated spaces, heating, evaporation of liquids from large surfaces, spraying of mists, mechanical generation of dusts, drying of solids, etc.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. The correct choice of protective gloves depends upon the chemicals being handled, and the conditions of work and use. Most gloves provide protection for only a limited time before they must be discarded and replaced. Gloves should be chosen in consultation with the supplier / manufacturer and taking account of a full assessment of the working conditions. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. For tasks involving thermal hazards, the standards set out in EN 407 should be considered. Breakthrough time: For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. Glove thickness: For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. Eye protection should meet the standards set out in EN 166.

Respiratory

Use disposable dust/mist mask if the recommended exposure limit is exceeded. A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Under normal use conditions, respirator is not usually required. Use appropriate respiratory protection if exposure to dust particles, mist or vapors is likely. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Brown
Colour Intensity
---
Form
liquid
Odor
Mild
Odor Threshold
---
Ph
---
Melting Point
---
Boiling Point
---
Flash Point
165 °C (Pensky-Martens Closed Cup)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
---
Vapor Pressure
---
Vapor Density
---
Relative Density
0.932 - 0.972 (15.6 °C)
Bulk Density
---
Density
---
Flammability
---
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
---
Decomposition Temperature
---
Solubility
---
Partition Coefficient
---
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
3000 mm2/s (40 °C); 150 mm2/s (100 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Do not expose to excessive heat, ignition sources, or oxidizing materials.

Incompatible

Strong mineral acids and strong oxidizing agents. Halogens and halogenated compounds. Strong acids. Strong oxidizing agents. Strong bases. Strong oxidizing agents.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, nitrogen oxides, and other products of incomplete combustion.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Fish Mineral oil: LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Ecotoxicity

Calcium branched alkyl phenate sulphide (overbased): LC 50 (Fathead Minnow, 4 d): > 1,000 mg/l

12.1 Ecotoxicity

Fish zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate): LC 50 (Rainbow Trout, 4 Days): 4.5 mg/l NOEC (Rainbow Trout, 4 Days): 1.8 mg/l LC 50 (Sheepshead Minnow, 4 Days): 46 mg/l

12.1 Ecotoxicity

Reaction products of Benzeneamine, N-phenyl- with nonene (branched): LC 50 (Zebra Fish, 4 d): > 100 mg/l

12.1 Ecotoxicity

Fish Phenol, dodecyl-, branched: LC 50 (Fathead Minnow, 4 d): 40 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Mineral oil: EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Calcium branched alkyl phenate sulphide (overbased): EC 50 (Water flea (Daphnia magna), 48 h): > 1,000 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate): EC 50 (Water flea (Daphnia magna), 2 d): 23 mg/l NOEC (Water flea (Daphnia magna), 2 d): 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.4 mg/l

12.1 Ecotoxicity

Reaction products of Benzeneamine, N-phenyl- with nonene (branched): EC 50 (Water flea (Daphnia magna), 2 d): > 100 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Phenol, dodecyl-, branched: EC 50 (Water flea (Daphnia magna), 2 d): 0.037 mg/l EC 50 (Shrimp (Mysidopsis Bahia), 4 d): > 0.58 mg/l EC 50 (Water flea (Daphnia magna), 21 d): 0.0079 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.0037 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Mineral oil: EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Calcium branched alkyl phenate sulphide (overbased) EC 50 (Green algae (Selenastrum capricornutum), 96 h): > 1,000 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): 21 mg/l

12.1 Ecotoxicity

Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC 50 (Green algae (Selenastrum capricornutum), 3 d): 600 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Phenol, dodecyl-, branched EC 50 (Green algae (Scenedesmus quadricauda), 72 h): 0.36 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms Calcium branched alkyl phenate sulphide (overbased) EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms Reaction products of Benzeneamine, N-phenyl- with nonene (branched) EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms Phenol, dodecyl-, branched EC 50 (Sludge, 0.1 d): > 1,000 mg/l

12.2 Persistence and Degradability

Biodegradation Mineral oil OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Calcium branched alkyl phenate sulphide (overbased) OECD TG 301 B, 4.7 - 10.8 %, 28 d, Not readily degradable. Inherent Sludge, 38.8 %, 28 d

12.2 Persistence and Degradability

Biodegradation zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) OECD TG 301 B, 1.5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Reaction products of Benzeneamine, N-phenyl- with nonene (branched) OECD TG 301 B, 0 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Phenol, dodecyl-, branched Miscellaneous, 10 %, 56 d, Not readily degradable. OECD TG 301 B, 25 %, 28 d, Not readily degradable.

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF) Calcium branched alkyl phenate sulphide (overbased) Bioconcentration Factor (BCF): 2.2

12.3 Bioaccumulative potential

### Bioconcentration Factor (BCF) Phenol, dodecyl-, branched Bioconcentration Factor (BCF): 794.33 (Measured)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) Calcium branched alkyl phenate sulphide (overbased) Log Kow: 11.08 (Measured)

12.3 Bioaccumulative potential

### Partition Coefficient n-octanol / water (log Kow) zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) Log Kow: 2.21 20 °C (Measured)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) Reaction products of Benzeneamine, N-phenyl- with nonene (branched) Log Kow: > 7 Experimental result, Weight of Evidence study

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) Phenol, dodecyl-, branched Log Kow: 7.14 (Measured)

12.4 Mobility:

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine Disruption:

Product: No data available.

No data available.

12.7 Other adverse effects

This material contains one or more components that have an impurity (alkylated phenol) that is highly toxic to aquatic organisms (Aquatic Acute 1 and Aquatic Chronic 1). The component containing the impurity (calcium phenate) was tested in fish, invertebrates and algae and the results showed that it may cause long lasting harmful effects to aquatic life (Aquatic Chronic 4). Therefore the classification shown in Section 3 for the alkylphenol impurity should not be used to classify the product for aquatic toxicity.

The product contains an alkylated phenol impurity that is highly toxic to aquatic organisms; however, testing of the calcium phenate component indicates long-lasting harmful effects (Aquatic Chronic 4), suggesting the impurity classification should not be used for the product.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 605100 R11634A?

The signal word is warning.

What is the physical form of 605100 R11634A?

605100 R11634A is a liquid with brown color. It has mild odor.

What is 605100 R11634A used for?

Heavy Duty Diesel

What are the hazard statements for 605100 R11634A?

This substance has 2 hazard statements:

  • H319: Causes serious eye irritation.
  • H412: Harmful to aquatic life with long lasting effects.