R14994A

Consult a physician after significant exposure. If unconscious, place in recovery position and seek medical advice. If breathing has stopped, assist ventilation with a mechanical device. Do not use mouth-to-mouth resuscitation if exposure to hydrogen sulphide is suspected.

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. In case of burns apply cold water until pain subsides then seek medical advice.

Symptoms: Dermatitis

Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists: Get medical advice/ attention.

Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Obtain medical attention.

Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames

High volume water jet

Not classified as flammable or combustible, but will combust if ignited.

Fire-fighters should exercise extreme caution in enclosed spaces due to the possible presence of toxic decomposition and combustion products. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Advice for emergency responders: Ensure adequate ventilation. Use personal protective equipment. Material can create slippery conditions. Advice for non-emergency personnel: Avoid contact with spilled material. Do not touch or walk through spilled material.

Dyke far ahead of liquid spill for later recovery and disposal.

See attached ES. Prevent entry into waterways, sewers, basements or confined areas. Prevent further leakage or spillage if safe to do so.

Recover by pumping or with suitable absorbent. Seek the advice of a specialist before using dispersants.

Materials: sand, silica gel, acid binder, universal binder, sawdust

Do not breathe vapors or spray mist. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. May cause sensitization of susceptible persons by skin contact. Smoking, eating and drinking should be prohibited in the application area.

Product should be stored below the recommended maximum loading / unloading temperature to avoid degradation of product quality and eventually decomposition.

Smoking, eating and drinking should be prohibited in the application area.

Normal measures for preventive fire protection.

See attached ES. No special requirements under ordinary conditions of use and with adequate ventilation. If decomposition is suspected, or if the product has been overheated, do not open the container, discontinue heating and secure the unit. Initiate emergency procedures, taking all necessary precautions to avoid exposure to noxious or flammable gases (e.g. hydrogen sulphide), such as evacuation of contaminated areas, and use of suitable respiratory protection.

Polyvinyl alcohol or nitrile- butyl-rubber gloves Before removing gloves clean them with soap and water. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. When handling hot material, use heat resistant gloves. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

The applicable European standard can be found in EN 166. Eye wash bottle with pure water. Tightly fitting safety goggles. Ensure that eyewash stations and safety showers are close to the workstation location.

In the case of vapor formation use a respirator with an approved filter. The applicable European standard can be found in EN 140, EN 137, EN 143, EN 14387.

Impervious clothing. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Long sleeved clothing. The applicable European standard can be found in EN 14605.

See attached ES. Prevent entry into waterways, sewers, basements or confined areas. Local authorities should be advised if significant spillages cannot be contained. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Try to prevent the material from entering drains or water courses. If the product contaminates rivers and lakes or drains inform respective authorities.

Stable under recommended storage conditions.

No dangerous reaction known under conditions of normal use.

No hazards to be specially mentioned.

Excessive heat.

Strong oxidizing agents, water

Hydrogen Sulfide

The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/ container to an approved waste disposal plant.

Dispose of contents/ container to an approved waste disposal plant. Disposal recommendations based on material as supplied, Disposal must be in accordance with applicable laws and regulations, and material characteristics at time of disposal.