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Safety Data Sheet EN

R449A

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
R449A

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Refrigerant, For professional users only.

Manufacturers & Suppliers

A-Gas (Australia) Pty Ltd logo

A-Gas (Australia) Pty Ltd

manufacturer

9-11 Oxford Rd, Laverton North Victoria 3026 Australia

93689222

www.agas.com

Emergency Contacts

A-Gas (Australia) Pty Ltd

1800737001

CHEMWATCH EMERGENCY RESPONSE (24/7)

+61 1800 951 288 (ID#: 5185-73)

CHEMWATCH EMERGENCY RESPONSE (24/7)

+61 3 9573 3188

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Gases Under Pressure (Liquefied Gas) H280

GHS Pictograms

GHS04 - Compressed gas

GHS04

Hazard Statements

H280 Contains gas under pressure; may explode if heated.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P410+P403 Protect from sunlight. Store in a well-ventilated place.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

See section below for composition of Mixtures

Chemical Name CAS Number Concentration Hazardous
1,1,1,2-TETRAFLUOROETHANE EC: 212-377-0 811-97-2 25.7% No
2,3,3,3- Tetrafluoropropene EC: 468-710-7 754-12-1 25.3% No
Pentafluoroethane (R125) EC: 206-557-8 354-33-6 24.7% No
Difluoromethaan EC: 200-839-4 75-10-5 24.2998% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If the patient is not breathing spontaneously, administer rescue breathing. If the patient does not have a pulse, administer CPR. If medical oxygen and appropriately trained personnel are available, administer 100% oxygen. Summon an emergency ambulance. If an ambulance is not available, contact a physician, hospital, or Poison Control Centre for further instruction. Keep the patient warm, comfortable and at rest while awaiting medical care. MONITOR THE BREATHING AND PULSE, CONTINUOUSLY. Administer rescue breathing (preferably with a demand-valve resuscitator, bag-valve mask-device, or pocket mask as trained) or CPR if necessary.

Symptoms: Following exposure to gas, remove the patient from the gas source or contaminated area.

Skin contact

Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. In case of cold burns (frost-bite): Move casualty into warmth before thawing the affected part; if feet are affected carry if possible. Bathe the affected area immediately in luke-warm water (not more than 35 deg C) for 10 to 15 minutes, immersing if possible and without rubbing.

Symptoms: If skin or hair contact occurs.

Eye contact

Gently rinse the affected eye(s) with clean, cool water for at least 15 minutes. Have the patient lie or sit down and tilt the head back. Hold the eyelid(s) open and pour water slowly over the eyeball(s) at the inner corners, letting the water run out of the outer corners. The patient may be in great pain and wish to keep the eyes closed. It is important that the material is rinsed from the eyes to prevent further damage.

Symptoms: If product comes in contact with eyes.

Ingestion

For advice, contact a Poisons Information Centre or a doctor.

Symptoms: Not considered a normal route of entry.

Immediate Medical Attention

Maintain an open airway and assist ventilation if necessary. Treat coma and arrhythmias if they occur. Avoid (adrenaline) epinephrine or other sympathomimetic amines that may precipitate ventricular arrhythmias.

Medical Treatment

Administer activated charcoal, if available. DO NOT induce vomiting because of rapid absorption and the risk of abrupt onset CNS depression.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment.

Hands

When handling sealed and suitably insulated cylinders wear cloth or leather gloves. Insulated gloves: NOTE: Insulated gloves should be loose fitting so that may be removed quickly if liquid is spilled upon them. Insulated gloves are not made to permit hands to be placed in the liquid; they provide only short-term protection from accidental contact with the liquid.

Eyes

Chemical goggles. Full face shield may be required for supplementary but never for primary protection of eyes. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.

Respiratory

Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content. The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask is not functioning properly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use of cartridge respirators is considered appropriate. Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determined that the humidity is less than 75%, in which case, cartridges can be used for 4 hr. Used cartridges should be discarded daily, regardless of the length of time used. Positive pressure, full face, air-supplied breathing apparatus should be used for work in enclosed spaces if a leak is suspected or the primary containment is to be opened (e.g. for a cylinder change). Air-supplied breathing apparatus is required where release of gas from primary containment is either suspected or demonstrated.

Skin/Body

See Hand protection below

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquified Gas
Physical State Data
gas
State Under Standard Conditions
---
Appearance
Clear liquefied gas with a slight ether-like odour.
Colour
---
Colour Intensity
---
Form
---
Odor
Ether like
Odor Threshold
Not Available
Ph
Not Available
Melting Point
Not Available
Boiling Point
-46
Flash Point
Not Applicable
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
>1 (CCL4=1.0)
Vapor Pressure
1274.8 @ 25C
Vapor Density
3.07
Relative Density
1.10 @25C
Bulk Density
---
Density
---
Flammability
Not Applicable
Upper Explosive Limit
Not Applicable
Lower Explosive Limit
Not Applicable
Explosive Limits
---
Auto Ignition Temperature
Not Available
Decomposition Temperature
Not Available
Solubility
---
Partition Coefficient
Not Available
Solubility In Water
Not Available
Solubility In Fat
---
Molecular Weight
Not Applicable
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not Available
Kinematic Viscosity
---
Properties Status
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1078
Shipping Name
REFRIGERANT GAS, N.O.S. (contains 1,1,1,2-tetrafluoroethane and 2,3,3,3-tetrafluoropropene)
Transport Class
2.2
Packing Group
Not Applicable
ADR

274

IMDG

EMS Number F-C , S-V

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for R449A?

The signal word is warning.

What is the physical form of R449A?

R449A is a liquified gas appearing as clear liquefied gas with a slight ether-like odour. . It has ether like odor.

What is R449A used for?

Refrigerant, For professional users only.

What are the hazard statements for R449A?

This substance has 1 hazard statement:

  • H280: Contains gas under pressure; may explode if heated.

What is the melting point of R449A?

The melting point is Not Available and the boiling point is -46.

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