Identification
Product identifiers, regulatory numbers, and supplier information
Product Information
- Product Name
- SIGMADUR 188/520/550 HARDENER
- Product Form
- Liquid
- Product Code
- 00238759
Regulatory Identifiers
- CAS Number
- N/A
Identified Uses
Professional applications, Used by spraying. Coating.
Uses advised against
Not applicable.
Manufacturers & Suppliers
PPG Canada Inc.
national supplier
5676 Timberlea Blvd Mississauga ON L4W 4M6 Canada
+1 905-629-7999
PPG Industries, Inc.
manufacturer
One PPG Place Pittsburgh, PA 15272
888-977-4762
Emergency Contacts
Emergency Contact
(412) 434-4515
Emergency Contact
(514) 645-1320
Emergency Contact
01-800-00-21-400
Emergency Contact
+ 52 55 5559 1588
Hazard Identification
GHS classification, signal word, pictograms, and hazard statements
Hazard Classifications
GHS Pictograms
GHS02
GHS07
GHS08
Hazard Statements
Precautionary Statements
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Composition / Information on Ingredients
Chemical components, concentration ranges, and hazardous substance identification
| Chemical Name | CAS Number | Concentration | Hazardous |
|---|---|---|---|
| Hexamethylene diisocyanate, oligomers (Biuret type) | 28182-81-2 | 60 - 80% | No |
| 2-methoxy-1-methylethyl acetate | 108-65-6 | 7 - 13% | No |
| xylene | 1330-20-7 | 3 - 7% | No |
| ethylbenzene | 100-41-4 | 3 - 7% | No |
| hexamethylene-di-isocyanate | 822-06-0 | 0.1 - 1% | No |
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Notes
Ranges if listed above for hazardous ingredient(s) are prescribed ranges.
First Aid Measures
Emergency procedures for chemical exposure incidents
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Symptoms: Harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Adverse symptoms may include the following: respiratory tract irritation coughing wheezing and breathing difficulties asthma
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.
Symptoms: Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: irritation redness dryness cracking
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.
Symptoms: No known significant effects or critical hazards.
If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.
Symptoms: No known significant effects or critical hazards.
Immediate Medical Attention
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. seek immediate medical advice. If swallowed, seek medical advice immediately and show this container or label.
Medical Treatment
In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. No specific treatment.
Firefighting Measures
Extinguishing media, specific hazards, and firefighter protection
Use dry chemical, CO₂, water spray (fog) or foam.
Do not use water jet.
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Firefighter Protection
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Accidental Release Measures
Spill cleanup procedures, containment, and environmental protection
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Avoid breathing vapor or mist. Provide adequate ventilation.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Contain and collect spillage with non-combustible, absorbent material. The contaminated area should be cleaned immediately with a suitable decontaminant.
Materials: sand, earth, vermiculite or diatomaceous earth
Related Products
Similar products with comparable safety profiles
Handling and Storage
Safe handling precautions, storage conditions, and workplace requirements
Put on appropriate personal protective equipment. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
Store between 0 to 35°C (32 to 95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.
Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.
Exposure Controls / PPE
Occupational exposure limits, engineering controls, and protective equipment
Physical and Chemical Properties
Appearance, physical state, melting point, boiling point, and material characteristics
Stability and Reactivity
Chemical stability, hazardous reactions, and incompatible materials
The product is stable.
No specific test data related to reactivity available for this product or its ingredients.
Under normal conditions of storage and use, hazardous reactions will not occur.
In a fire, hazardous decomposition products may be produced. Refer to protective measures listed in sections 7 and 8.
Keep away from: oxidizing agents, strong alkalis, strong acids, amines, alcohols, water. Uncontrolled exothermic reactions occur with amines and alcohols.
Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen, hydrogen cyanide, monomeric isocyanates.
Ecological Information
Environmental toxicity, biodegradation, and bioaccumulation data
12.5 Results of PBT and vPvB assessment
12.6 Endocrine disrupting properties
12.7 Other adverse effects
12.4 Mobility in soil
Toxicity
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Endocrine disrupting properties
12.7 Other adverse effects
12.2 Persistence and degradability
12.2 Persistence and degradability
Persistence and degradability
Bioaccumulative potential
12.3 Bioaccumulative potential
12.3 Bioaccumulative potential
12.3 Bioaccumulative potential
12.3 Bioaccumulative potential
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulative potential
Disposal Considerations
Waste treatment methods, disposal recommendations, and waste codes
Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Transport Information
UN numbers, shipping names, transport classes, and regulatory requirements
- UN Number
- UN1263
- Shipping Name
- PAINT
- Transport Class
- 3
- Packing Group
- III
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Regulatory Information
Chemical regulations, safety assessments, and compliance status
Frequently Asked Questions
Common questions about safety, handling, and properties
What is the hazard signal word for SIGMADUR 188/520/550 HARDENER?
The signal word is danger.
What is the physical form of SIGMADUR 188/520/550 HARDENER?
SIGMADUR 188/520/550 HARDENER is a liquid. .
What is the solubility of SIGMADUR 188/520/550 HARDENER?
Insoluble in the following materials: cold water.
What is SIGMADUR 188/520/550 HARDENER used for?
Professional applications, Used by spraying. Coating.
What are the hazard statements for SIGMADUR 188/520/550 HARDENER?
This substance has 8 hazard statements:
- H226: Flammable liquid and vapor.
- H316: Prolonged or repeated contact may dry skin and cause irritation.
- H317: May cause an allergic skin reaction.
- H332: Harmful if inhaled.
- H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
- H335: May cause respiratory irritation.
- H351: Suspected of causing cancer.
- H372: May cause damage to organs through prolonged or repeated exposure. (hearing organs)