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Safety Data Sheet EN

Ethylene oxide

CAS 75-21-8
EC 200-849-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ethylene oxide
Product Code
387614
Chemical Name
ethyleenoxide
Synonyms
1,2-Epoxyethane, Oxirane, EO

Regulatory Identifiers

CAS Number
75-21-8 Check regulations →
EC Number
200-849-9 Check regulations →

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street SAINT LOUIS MO 63103 USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Gas Cat. 1 H220
Press. Gas (Liq.) H280
Acute Tox. Cat. 3 H331
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2A H319
Muta. Cat. 1B H340
Carc. Cat. 1B H350
STOT SE Cat. 3 H335
Aquatic Acute Cat. 3 H402
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS02 - Flammable

GHS02

GHS04 - Compressed gas

GHS04

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H340 May cause genetic defects.
H350 May cause cancer.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 Eliminate all ignition sources if safe to do so.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410 + P403 Protect from sunlight. Store in a well-ventilated place.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
ethyleenoxide EC: 200-849-9 75-21-8 90 - 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Splash contact Material: butyl-rubber Minimum layer thickness: 0.3 mm Break through time: 10 min Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Molecular Weight
---
Density
---
Flammability
No data available
Relative Density
0.882 g/cm3 at 25 ℃ (77 ºF)
Physical State Data
liquid
Properties Status
---
Odor
No data available
Colour
---
Solubility
slightly soluble
Boiling Point
10.7 °℃ (51.3 ºF) - lit.
Decomposition Temperature
No data available
Solubility In Water
slightly soluble
Cloud Point
---
Solidification Point
---
Melting Point
- 111 °℃ (-168 ºF) - lit.
Vapor Pressure
1,440 hPa (1,080 mmHg) at 20 °℃ (68 °F) 2,080 hPa (1,560 mmHg) at 30 ℃ (86 °F) 3,950 hPa (2,963 mmHg) at 50 ℃ (122 ºF)
Odor Threshold
No data available
Crystallisation Point
---
Solubility In Fat
---
Voc Content
---
Freezing Point
---
Form
---
Dynamic Viscosity
---
Partition Coefficient
log Pow: 0.3
Upper Explosive Limit
99.9 %(V)
Auto Ignition Temperature
429.0 °C (804.2 ºF)
Flash Point
-20.0 °℃ (-4.0 °F) - closed cup
Appearance
Form: Liquefied gas
Bulk Density
---
Metal Corrosion
---
Physical State
Liquefied gas
Evaporation Rate
No data available
Ph
7.0 at 20 °℃ (68 ºF)
Vapor Density
No data available
Softening Point
---
Kinematic Viscosity
---
Relative Evaporation Rate
---
Lower Explosive Limit
3 %(V)
Colour Intensity
---
Explosive Limits
---
State Under Standard Conditions
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1040
Shipping Name
Ethylene oxide
Transport Class
2.3 (2.1)
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Ethylene oxide known by?

Ethylene oxide is also known as: 1,2-Epoxyethane, Oxirane, EO

What is the hazard signal word for Ethylene oxide?

The signal word is danger.

What is the physical form of Ethylene oxide?

Ethylene oxide is a liquefied gas appearing as form: liquefied gas . It has no data available odor.

What is the solubility of Ethylene oxide?

slightly soluble

What is Ethylene oxide used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Ethylene oxide?

This substance has 9 hazard statements:

  • H220: Extremely flammable gas.
  • H280: Contains gas under pressure; may explode if heated.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H331: Toxic if inhaled.
  • H335: May cause respiratory irritation.
  • H340: May cause genetic defects.
  • H350: May cause cancer.
  • H412: Harmful to aquatic life with long lasting effects.

What is the melting point of Ethylene oxide?

The melting point is - 111 °℃ (-168 ºF) - lit. and the boiling point is 10.7 °℃ (51.3 ºF) - lit..

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