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Safety Data Sheet EN

Sodium bisulphite

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Sodium bisulphite
Product Form
Pure product in solution .
Chemical Name
Sodium bisulphite
Synonyms
Sodium hydrogen sulphite

Regulatory Identifiers

CAS Number
N/A
REACH No.
01-2119524563-42

Identified Uses

See table on the front page of the annex.

Uses advised against

This product is not recommended for any industrial, professional or consumer use other than identified in table on the front page of the annex. Not for use in ornamental articles, in tricks and jokes and in games (in accordance with Annex XVII to Regulation (EC) No 1907/2006) (3. Liquid substances or mixtures, which are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: (a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F, (b) hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10, (c) hazard class 4.1, (d) hazard class 5.1).

Manufacturers & Suppliers

BRENNTAG N.V. logo

BRENNTAG N.V.

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Nijverheidslaan 38 - BE-8540 DEERLIJK

+32(0)56/77.69.44

www.brenntag.be

BRENNTAG Nederland B.V. logo

BRENNTAG Nederland B.V.

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Donker Duyvisweg 44 - NL-3316 BM DORDRECHT

+31(0)78/65.44.944

www.brenntag.nl

Emergency Contacts

Antipoison Center - Brussels

+32(0)70/245.245

National Poisoning Information Center - Bilthoven

+31(0)30/274.88.88

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox.

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H302 Harmful if swallowed.

Precautionary Statements

P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor/ if you feel unwell.
P330 Rinse mouth.
P501 Dispose of contents and/or container in accordance with local/regional/ national/international regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Sodium bisulphite ...% EC: 231-548-0 7631-90-5 19 - 43% Yes

Notes

The full text of the (EU)H-statements is in section 16. Note B (Regulation (EC) No 1272/2008) applies to the product or one or more of its components.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim into fresh air. Allow the affected person to rest in semi-sitting position. If not breathing, give artificial respiration. Consult a doctor.

Skin contact

Remove contaminated clothing. Rinse skin abundantly with water and soap. (shower if necessary).

Eye contact

Rinse immediately thoroughly and long (at least 15 min.) with plenty of water. Remove contact lenses.

Ingestion

Rinse mouth with water. Call a POISON CENTER or doctor/physician if you feel unwell.

Immediate Medical Attention

For specialist advice doctors should contact the NVIC or the Belgian Poison center.

Medical Treatment

For specialist advice doctors should contact the NVIC or the Belgian Poison center.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Extinguishing powder , Foam , Carbon dioxide (CO2) , Water spray .

Unsuitable media

None .

Specific hazards

Fire may liberate toxic and stinging vapours. ( E.g. Sulfur dioxide )

Instructions

Apply water spray or fog to cool nearby equipment. Avoid fire-fighting water to enter environment.

Firefighter Protection

Use self-contained breathing apparatus and wear protective clothes when in close proximity to fire.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate all personnel immediately and ventilate area. Avoid breathing vapour and contact with skin, eyes and clothing.

Environmental

Shut off leaks if without risks. Dike in the spilled product as much as possible with inert material. Prevent entry of product in public water, sewers or soil.

Cleanup methods

Collect the spilled liquid in closable, suitable disposal containers. Clean up any spills as soon as possible, using an inert absorbent material. Residue is to be washed down with plenty of water.

Materials: inert absorbent material

Related Substances

Similar chemicals with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

AVOID FOG TRANSFORMATION ! Avoid breathing vapour and contact with skin, eyes and clothing. Wear recommended personal protective equipment. (See section 8) Wash hands before and after working with the product. When using, do not eat, drink or smoke. Emergency eye wash fountains and showers should be available in the immediate vicinity of any potential exposure.

Storage

Keep only in the original, safely locked container in a dry, cool, dark, well ventilated place. All dangerous products should be placed on a drip tray or should be barreled. Keep away from : Acids , Oxidizing agents . Storage temperature: 20 - 27 °C

Hygiene

Wash hands before and after working with the product. When using, do not eat, drink or smoke.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ventilation ( If possible through the floor ), Local exhaust .

Hands

Suitable material for safety gloves (EN 374): The suitability of the gloves and the breakthrough time for a specific workplace should be discussed with the producers of the protective gloves. - material : Nitril rubber - thickness : 0,35 mm - breakthrough time : > 480'

Eyes

Closed safety glasses or face shield.

Respiratory

CE-approved mask for inorganic gases/vapours (type B, grey).

Skin/Body

Suitable protective clothing .

Environmental

See sections 6, 7, 12 and 13.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colourless to light yellow
Colour
Colourless to light yellow
Colour Intensity
---
Form
Colourless to light yellow.
Odor
Sulphur-like odour
Odor Threshold
Not applicable.
Ph
3,5 - 5
Melting Point
< 2 °C
Boiling Point
app. 98 °C
Flash Point
Not applicable.
Freezing Point
< 2 °C
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable.
Vapor Pressure
No data available.
Vapor Density
---
Relative Density
---
Bulk Density
---
Density
1,36 kg/l
Flammability
---
Upper Explosive Limit
Not applicable.
Lower Explosive Limit
Not applicable.
Explosive Limits
---
Auto Ignition Temperature
Not applicable.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
Not applicable.
Solubility In Water
72,4 g/100 ml
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
No data available.
Kinematic Viscosity
No data available.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable at normal circumstances .

Reactivity

Reacts violently with oxidizing agents and strong acids.

Hazardous reactions

The substance decomposes, by evaporation, by heating above 150 °C, in formation of toxic and corrosive vapours. Reacts violently with: Acids , Strong oxidizing agents => Creation of: Toxic vapours , Stinging vapours .

Avoid

High temperatures , Direct sunlight .

Incompatible

Oxidizing agents , Strong acids .

Decomposition

Sulfur oxides .

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products.

Disposal

The product has to be destroyed according to national or local legislation, by a company specialised in handling hazardous waste products.

Waste Codes

XXXXXX European waste product code. This code is assigned on the basis of the most current applications and can not be representative for pollutions which are arisen at the effective use of the product. The producer of the waste has to evaluate its process himself and has to grant the appropriate waste coding. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Sodium bisulphite known by?

Sodium bisulphite is also known as: Sodium hydrogen sulphite

What is the hazard signal word for Sodium bisulphite?

The signal word is warning.

What is the physical form of Sodium bisulphite?

Sodium bisulphite is a liquid appearing as colourless to light yellow with colourless to light yellow color. It has sulphur-like odour odor.

What is Sodium bisulphite used for?

See table on the front page of the annex.

What are the hazard statements for Sodium bisulphite?

This substance has 1 hazard statement:

  • H302: Harmful if swallowed.

What is the melting point of Sodium bisulphite?

The melting point is < 2 °C and the boiling point is app. 98 °C.

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