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Safety Data Sheet EN

VERSENEX* 80 Chelating Agent

CAS 140-01-2
EC 205-391-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
VERSENEX* 80 Chelating Agent
Chemical Name
Pentasodium diethylenetriaminepentaacetate

Regulatory Identifiers

CAS Number
140-01-2 Check regulations →
EC Number
205-391-3 Check regulations →
REACH No.
01-2119474445-33-0000, 01-2119474445-33-0001

Identified Uses

Industrial uses: Manufacture of substances Formulation and (re)packing of substances and mixtures. Use in paper, textile and leather production, industrial. Use as a curing agent in foam production, industrial. Use as process chemical, industrial. Intermediate Use in Oil and Gas field drilling and production operations, industrial. Professional uses: Use in Cleaning Agents, professional. Consumer uses: Use in Cleaning Agents, consumer. Uses in Coatings, consumer.

Manufacturers & Suppliers

R

ROHM AND HAAS LATINOAMERICA S DE RL DE CV

manufacturer

AV PASEO DE LA REFORMA NO. 243 PISO 8 06500 DELEGACION CUAUHTEMOC MEXICO

Emergency Contacts

Local Emergency Contact

00 31 115 69 4982

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Met. Corr. Cat. 1 H290
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Repr. Cat. 2 H361d
STOT RE Cat. 2 H373

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H290 May be corrosive to metals.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.

Precautionary Statements

P201 Obtain special instructions before use.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P312 Call a POISON CENTER/doctor if you feel unwell.
P337 + P313 If eye irritation persists: Get medical advice/ attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Pentasodium diethylenetriaminepentaacetate EC: 205-391-3 140-01-2 38 - 40% Yes
Water EC: 231-791-2 7732-18-5 52% No
sodium hydroxide EC: 215-185-5 1310-73-2 1.5% Yes

Notes

If present in this product, any not classified components disclosed above for which no country specific OEL value(s) is(are) indicated under Section 8, are being disclosed as voluntarily disclosed components. For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air; if effects occur, consult a physician.

Symptoms: May cause asthma-like (reactive airways) symptoms.

Skin contact

Wash off with plenty of water.

Eye contact

Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available.

Symptoms: Chemical eye burns.

Ingestion

Do not induce vomiting. Give one cup (8 ounces or 240 ml) of water or milk if available and transport to a medical facility. Do not give anything by mouth unless the person is fully conscious.

Symptoms: Swallowing may result in burns/ulceration of mouth, stomach and lower gastrointestinal tract with subsequent stricture.

Immediate Medical Attention

Obtain medical attention without delay, preferably from an ophthalmologist. Transport to a medical facility.

Medical Treatment

Bronchodilators, expectorants, antitussives and corticosteroids may be of help. Chemical eye burns may require extended irrigation. Suggest endotracheal/esophageal control if lavage is done. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam.

Unsuitable media

No data available

Specific hazards

This material will not burn until the water has evaporated. Residue can burn.

Instructions

Keep people away. Isolate fire and deny unnecessary entry. To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam.

Firefighter Protection

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate area. Keep upwind of spill. Ventilate area of leak or spill. Only trained and properly protected personnel must be involved in clean-up operations. Use appropriate safety equipment.

Small spill

Absorb with materials such as: Non-combustible material. Collect in suitable and properly labeled containers.

Large spill

Dike area to contain spill. Wash the spill site with water.

Environmental

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.

Cleanup methods

Absorb with materials such as: Non-combustible material. Collect in suitable and properly labeled containers. Wash the spill site with water.

Materials: Non-combustible material.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not swallow. Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Use with adequate ventilation. Keep container closed. Avoid breathing mist.

Storage

Do not store in: Opened or unlabeled containers. Zinc. Aluminum. Aluminum and its alloys. Copper. Copper alloys. Galvanized containers. Nickel. Store in accordance with good manufacturing practices. Store in original unopened container.

Hygiene

Wash thoroughly after handling.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations.

Hands

Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. If hands are cut or scratched, use gloves chemically resistant to this material even for brief exposures. Examples of preferred glove barrier materials include: Butyl rubber. Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl chloride ("PVC" or "vinyl"). Avoid gloves made of: Polyvinyl alcohol ("PVA"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended. Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical substance as this level of protection is also highly dependent on the specific composition of the material that the glove is fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35mm to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35mm. Other glove materials with a thickness of less than 0.35mm may offer sufficient protection when only brief contact is expected. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use chemical goggles. Chemical goggles should be consistent with EN 166 or equivalent.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. In misty atmospheres, use an approved particulate respirator. Use the following CE approved air-purifying respirator: Particulate filter, type P2.

Skin/Body

Wear clean, body-covering clothing.

Environmental

See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Colorless to yellow
Colour Intensity
---
Form
---
Odor
Mild
Odor Threshold
No test data available
Ph
11.0 - 11.8 1% Literature
Melting Point
Not applicable to liquids
Boiling Point
106 °C
Flash Point
No measurable flash point
Freezing Point
-28 °C
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
< 0.8
Vapor Pressure
Same as water
Vapor Density
---
Relative Density
1.30 at 25 °C / 25 °C
Bulk Density
---
Density
---
Flammability
Not applicable to liquids
Upper Explosive Limit
Not applicable
Lower Explosive Limit
Not applicable
Explosive Limits
---
Auto Ignition Temperature
Not applicable
Decomposition Temperature
No test data available
Solubility
---
Partition Coefficient
No data available
Solubility In Water
completely miscible with water
Solubility In Fat
---
Molecular Weight
503.1 g/mol
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
33 cSt at 20 °C
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions. See Storage, Section 7.

Reactivity

No data available

Hazardous reactions

Polymerization will not occur.

Avoid

Some components of this product can decompose at elevated temperatures.

Incompatible

Avoid contact with metals such as: Aluminum alloys. Copper. Copper alloys. Nickel. Flammable hydrogen may be generated from contact with metals such as: Zinc. Aluminum.

Decomposition

Decomposition products depend upon temperature, air supply and the presence of other materials.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code will depend on the use that is made of this material. Contact the authorized waste disposal services.

Disposal

Contact the authorized waste disposal services.

Waste Codes

The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code will depend on the use that is made of this material. EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3267
Shipping Name
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.(Sodium hydroxide, Pentasodium Diethylenetriaminepentaacetate)
Transport Class
8
Packing Group
III
ADR

Hazard Identification Number: 80

IMDG

EmS: F-A, S-B

IATA

No data available.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for VERSENEX* 80 Chelating Agent?

The signal word is warning.

What is the physical form of VERSENEX* 80 Chelating Agent?

VERSENEX* 80 Chelating Agent is a liquid. with colorless to yellow color. It has mild odor.

What is VERSENEX* 80 Chelating Agent used for?

Industrial uses: Manufacture of substances Formulation and (re)packing of substances and mixtures. Use in paper, textile and leather production, industrial. Use as a curing agent in foam production, industrial. Use as process chemical, industrial. Intermediate Use in Oil and Gas field drilling and production operations, industrial. Professional uses: Use in Cleaning Agents, professional. Consumer uses: Use in Cleaning Agents, consumer. Uses in Coatings, consumer.

What are the hazard statements for VERSENEX* 80 Chelating Agent?

This substance has 6 hazard statements:

  • H290: May be corrosive to metals.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H332: Harmful if inhaled.
  • H361d: Suspected of damaging the unborn child.
  • H373: May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.

What is the melting point of VERSENEX* 80 Chelating Agent?

The melting point is Not applicable to liquids and the boiling point is 106 °C.