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Safety Data Sheet EN

Methylene chloride

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Methylene chloride
Product Code
D143-1; D143-4; D143-4LC; D143N2-19; D143POP-28; D143RS-19; D143RS-28; D143RS-50;143RS-115; D143RS-200; D143SK-1; D143SK-4; D143SS-19; D143SS-28; D143SS-50; D143SS-115; D143SS-200;
Synonyms
Dichloromethane; DCM

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals.

Uses advised against

Not for food, drug, pesticide or biocidal product use

Manufacturers & Suppliers

F

Fisher Scientific

manufacturer

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC®

800-424-9300

CHEMTREC®

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2
Eye Irrit. Cat. 2
Carc. Cat. 1B
STOT SE Cat. 3

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 Causes skin irritation
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness
H350 May cause cancer

Precautionary Statements

P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash face, hands and any exposed skin thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear eye/face protection
P281 Use personal protective equipment as required
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P308 + P313 IF exposed or concerned: Get medical attention/advice
P332 + P313 If skin irritation occurs: Get medical advice/attention
P337 + P313 If eye irritation persists: Get medical advice/attention
P362 + P364 Take off contaminated clothing and wash before reuse
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Methylene chloride 75-09-2 99.5% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If breathing is difficult, give oxygen. Obtain medical attention.

Symptoms: Breathing difficulties. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention.

Ingestion

Do not induce vomiting. Call a physician or Poison Control Center immediately.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable media

No information available

Specific hazards

Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Keep people away from and upwind of spill/leak.

Environmental

Should not be released into the environment. See Section 12 for additional ecological information.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location.

Hands

Wear appropriate protective gloves

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate protective clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Ph
Not applicable
Relative Density
1.33
Softening Point
---
Solubility
No information available
Kinematic Viscosity
---
Voc Content
---
State Under Standard Conditions
---
Explosive Limits
---
Lower Explosive Limit
13 vol %
Bulk Density
---
Odor
sweet
Odor Threshold
No information available
Solidification Point
---
Partition Coefficient
No data available
Appearance
Colorless
Cloud Point
---
Solubility In Fat
---
Melting Point
-97 °C / -142.6 °F
Molecular Weight
84.93
Solubility In Water
---
Physical State Data
liquid
Relative Evaporation Rate
---
Boiling Point
39 °C / 102.2 °F
Metal Corrosion
---
Density
---
Physical State
Liquid
Upper Explosive Limit
23 vol %
Dynamic Viscosity
---
Properties Status
---
Auto Ignition Temperature
556 °C / 1032.8 °F
Colour Intensity
---
Vapor Pressure
350 mbar @ 20°C
Flash Point
No information available
Form
---
Evaporation Rate
No information available
Freezing Point
---
Decomposition Temperature
No information available
Flammability
Not applicable
Crystallisation Point
---
Colour
Colorless
Vapor Density
2.93 (Air = 1.0)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

None under normal processing. Hazardous polymerization does not occur.

Avoid

Incompatible products. Excess heat.

Incompatible

Strong oxidizing agents, Strong acids, Amines

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂), Hydrogen chloride gas, Phosgene

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

| Component | Freshwater Algae | Freshwater Fish | Microtox | Water Flea | | --- | --- | --- | --- | --- | | Methylene chloride | EC50: >660 mg/L/96h | Pimephales promelas: LC50: 193 mg/L/96h | EC50: 1 mg/L/24 h EC50: 2.88 mg/L/15 min | EC50: 140 mg/L/48h |

Persistence and Degradability

Persistence and Degradability Persistence is unlikely based on information available.

Persistence is unlikely based on information available.

Bioaccumulation/ Accumulation

Bioaccumulation/ Accumulation No information available.

No information available.

Mobility

Mobility Will likely be mobile in the environment due to its volatility. | Component | log Pow | | --- | --- | | Methylene chloride | 1.25 |

Will likely be mobile in the environment due to its volatility.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Waste Codes

U080 Methylene chloride RCRA
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1593
Shipping Name
DICHLOROMETHANE
Transport Class
6.1
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Methylene chloride known by?

Methylene chloride is also known as: Dichloromethane; DCM

What is the hazard signal word for Methylene chloride?

The signal word is danger.

What is the physical form of Methylene chloride?

Methylene chloride is a liquid appearing as colorless with colorless color. It has sweet odor.

What is the solubility of Methylene chloride?

No information available

What is Methylene chloride used for?

Laboratory chemicals.

What are the hazard statements for Methylene chloride?

This substance has 4 hazard statements:

  • H315: Causes skin irritation
  • H319: Causes serious eye irritation
  • H336: May cause drowsiness or dizziness
  • H350: May cause cancer

What is the melting point of Methylene chloride?

The melting point is -97 °C / -142.6 °F and the boiling point is 39 °C / 102.2 °F.