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Safety Data Sheet EN

Hardener

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hardener
Product Code
LM 4385
Chemical Name
Hardener

Regulatory Identifiers

CAS Number
N/A

Identified Uses

additive

Manufacturers & Suppliers

Lott-Lacke GmbH logo

Lott-Lacke GmbH

manufacturer

Bunsenstrasse 22, 32052 Herford

+49 (0) 5221 - 29794-0

http://www.lott-lacke.de

Emergency Contacts

WISAG FMO Cargo Service GmbH & Co. KG CCN 721219

0800-181-7059

WISAG FMO Cargo Service GmbH & Co. KG CCN 721219

1-800-424-9300

WISAG FMO Cargo Service GmbH & Co. KG CCN 721219

+001 703 527 3867

WISAG FMO Cargo Service GmbH & Co. KG CCN 721219

4001 204937

ZH

WISAG FMO Cargo Service GmbH & Co. KG CCN 721219

800 968 793

ZH

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Resp. Sens. Cat. 1 H334
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary Statements

P260 Wear protective gloves and eye/face protection.
P261 Avoid breathing vapours.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF ANALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P362 + P364 Take off contaminated clothing and wash it before reuse.
In case of inadequate ventilation wear respiratory protection.
Store in a well-ventilated place. Keep container tightly closed.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Isocyanate containing product.

Chemical Name CAS Number Concentration Hazardous
2-Propenoic acid, 2-hydroxyethyl ester, polymer with 1,6-diisocyanatohexane EC: 616-633-6 78067-28-9 20 - 100% Yes
Hexamethylene diisocyanate, oligomers EC: 500-060-2 28162-81-2 5 - 10% Yes
n-butyl acetate EC: 204-858-1 123-86-4 1 - 2.5% Yes
N/A --- 0.5 - 1% Yes
6,5-Butanediol 4083-64-1 0.5% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove casually to fresh air and keep warm and at rest. If unconscious place in recovery position and seek medical advice. In case of irregular breathing or respiratory arrest provide artificial respiration. In all cases of doubt, or when symptoms persist, seek medical advice. In case of accident or unwelness, seek medical advice immediately (show directions for use or safety data sheet if possible).

Skin contact

Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do not use solvents or blinners. Call a physician immediately. Wash contaminated clothing prior to re-use. In case of accident or unwelness, seek medical advice immediately (show directions for use or safety data sheet if possible).

Symptoms: May irritate skin. May cause sensitization by skin contact.

Eye contact

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In case of accident or unwelness, seek medical advice immediately (show directions for use or safety data sheet if possible).

Symptoms: May irritate eyes.

Ingestion

Rinse mouth immediately and drink plenty of water. Seek medical advice immediately. Keep victim calm. Do NOT induce vomiting. Never give anything by mouth to an unconscious person or a person with cramps.

Immediate Medical Attention

Call a physician immediately. Seek medical advice immediately.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Co-ordinate fire-fighting measures to the fire surroundings.

Unsuitable media

strong water jet

Specific hazards

Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.

Instructions

Cool closed containers that are near the source of the fire.

Firefighter Protection

Provide a conveniently located respiratory protective device. Wear full chemical protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep people away from and upwind of spill/leak. Remove persons to safety.

Environmental

Do not allow to enter into surface water or drains.

Cleanup methods

Isolate leaked material using non-flammable absorption agent and collect it for disposal in appropriate containers. Fouled surfaces must be immediately cleaned with suitable solvents. Take up spilled residuals with the same agent and leave them for a few days in unclosed containers until there is no further reaction.

Materials: non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth), suitable solvents (flammable: water 45 vol.% ethanol or i-propanol 50 vol.% ammonia solution (density= 0.88) 5 vol.%; Alternative (non-flammable): sodium carbonate 5 vol.% water 50 vol.%)

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid formation of flammable and explosive vapour concentrations in the air and exceeding the exposure limit values. Avoid contact with skin, eyes and clothes. Do not inhale dusts, particulates and spray mist. Do not eat, drink or smoke. Take off immediately all contaminated clothing. Separate storage of work clothes. Wash hands before breaks and after work.

Storage

Store in a well-ventilated and dry room at temperatures between 15 °C and 30 °C. Protect from heat and direct sunlight. Keep container tightly closed. Store carefully closed containers upright to prevent any leaks.

Hygiene

Wash hands before breaks and after work. Take off immediately all contaminated clothing. Separate storage of work clothes.

Fire prevention

Keep away from heat sources, sparks and open flames. Use only spark proof tools. Take precautionary measures against static discharges. Keep away from sources of ignition - No smoking.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide good ventilation. This can be achieved with local or room suction.

Hands

For prolonged or repeated handling the following glove material must be used: NBR (White rubber). Thickness of the glove material > 0,4 mm; Breakthrough time (maximum wearing time) > 480 min. Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended glove articles DIN EN 374. Bantor creams can help protecting exposed skin areas. In no case should they be used after contact.

Eyes

Wear eye glasses with side protection according to EN 166.

Respiratory

When spraying, wear self-contained breathing apparatus. For other tasks a suitable respiratory system must be used, if local and room suction is not sufficient for keeping aerosol and solvent vapour concentration below the exposure limit values. If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection must be used. Observe the wear time limits according Go®SoftV in combination with the rules for using respiratory protection apparatus (BGR 190). Use only respiratory protection equipment with CE-symbol including four digit test number: respirator with A/P-filler (EN 14387)

Skin/Body

Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers.

Environmental

Do not allow to enter into surface water or drains. See section 7. No additional measures necessary.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Cloud Point
---
Lower Explosive Limit
1,2 Vol-%
Vapor Density
not determined
Melting Point
not applicable
Voc Content
---
Odor
mild
Dynamic Viscosity
---
Metal Corrosion
---
Evaporation Rate
not determined
Density
not determined
Molecular Weight
---
Flash Point
> 80 °C
Solubility In Fat
---
State Under Standard Conditions
---
Properties Status
---
Auto Ignition Temperature
280 °C
Partition Coefficient
see section 12
Upper Explosive Limit
7,8 Vol-%
Bulk Density
---
Boiling Point
not determined
Physical State Data
liquid
Form
---
Freezing Point
not applicable
Ph
not determined
Solubility In Water
Insoluble
Odor Threshold
not determined
Colour
mild
Decomposition Temperature
not determined
Colour Intensity
---
Explosive Limits
---
Relative Evaporation Rate
---
Solidification Point
---
Kinematic Viscosity
---
Softening Point
---
Crystallisation Point
---
Relative Density
not determined
Physical State
Squid colourless
Solubility
---
Vapor Pressure
not determined
Appearance
---
Flammability
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable under storage at normal ambient temperatures.

Reactivity

Reacts with water, forming carbon dioxide, producing bursting hazard in closed containers due to build-up of pressure.

Hazardous reactions

Reacts with water, forming carbon dioxide, producing bursting hazard in closed containers due to build-up of pressure.

Avoid

Hazardous decomposition byproducts may form with exposure to high temperatures.

Incompatible

Alkali (lye), Oxidising agent, Acids, Amines, Alcohols, Reducing agent, Radical former, Peroxides.

Decomposition

Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide, smoke, Nitrogen oxides (NOx), isocyanates. Possible in traces: Hydrogen cyanide (hydrocyanic acid).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Do not allow to enter into surface water or drains. Handle contaminated packages in the same way as the substance itself. Do not dispose of with domestic refuse.

Disposal

This material and its container must be disposed of in a safe way.

Waste Codes

080111 waste paint and varnish containing organic solvents or other dangerous substances EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
not applicable
Shipping Name
not applicable
Transport Class
not applicable
Packing Group
not applicable
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical safety assessments for substances in this preparation were not carried out.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hardener?

The signal word is danger.

What is the physical form of Hardener?

Hardener is a squid colourless with mild color. It has mild odor.

What is Hardener used for?

additive

What are the hazard statements for Hardener?

This substance has 4 hazard statements:

  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H319: Causes serious eye irritation.
  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.

What is the melting point of Hardener?

The melting point is not applicable and the boiling point is not determined.

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