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Safety Data Sheet EN

Plastic-Bond Hardener

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Plastic-Bond Hardener
Product Code
105654

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Hardener for resins. Adhesives

Manufacturers & Suppliers

WEICON GmbH & Co. KG logo

WEICON GmbH & Co. KG

manufacturer

Königsberger Str. 25, 48157 Münster, Germany

+49 251 93220

http://www.weicon.de

WEICON Australia Pty. Ltd logo

WEICON Australia Pty. Ltd

national supplier

1/55-65 Christensen Road, Stapylton QLD 4207

+61 493473383

http://www.weicon.com.au

Emergency Contacts

National Poison Information Center

131126

TRANSPORT / EMERGENCY CONTACT

+61 2 8014 4558

24h

EN

TRANSPORT / EMERGENCY CONTACT

1800 074 234

24h

EN

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
Skin Irrit. Cat. 2
Skin Sens. Cat. 1
STOT SE Cat. 3

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

Hazard Statements

H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing vapor.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P312 IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice or attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of waste according to applicable legislation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

The total concentration of ingredients in this product, reported or not in this section, is 100%.

Chemical Name CAS Number Concentration Hazardous
methyl methacrylate 80-62-6 30 - 60% Yes
3,5-diethyl-1,2-dihydro-1-phenyl-2-propylpyridine 34562-31-7 3% Yes

Notes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: respiratory tract irritation, coughing

Skin contact

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: irritation, redness

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Symptoms: pain or irritation, watering, redness

Ingestion

Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: No specific data.

Immediate Medical Attention

Get medical attention.

Medical Treatment

No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Materials: water, inert dry material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. Recommended : 1 - 4 hours (breakthrough time): Protective gloves made of nitrile rubber (material thickness of 0,4 mm); EN 374-5 Cat. III ; 4 - 8 hours (breakthrough time): Protective gloves made of Viton®/ butyl rubber (material thickness of 0,7 mm); EN388 Cat.II / EN374 Cat.III / EN374-2

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Recommended : organic vapor (Type AX) and particulate filter

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Ph
Not applicable.
Cloud Point
---
Colour Intensity
---
Solubility In Water
Not available.
Upper Explosive Limit
Not available.
Partition Coefficient
Not applicable.
Crystallisation Point
---
Bulk Density
---
Physical State
Liquid.
Explosive Limits
---
Auto Ignition Temperature
Not applicable.
Vapor Pressure
methyl methacrylate: 27.75236 mm Hg (3.7 kPa); 1-methoxy-2-propanol: 8.5 mm Hg (1.1 kPa); aniline: 0.30003 mm Hg (0.04 kPa); oxydipropyl dibenzoate: 0.0000012 mm Hg (0.00000016 kPa) at 20°C, 0.000011 mm Hg (0.0000015 kPa) at 50°C
Odor Threshold
Not available.
Density
0.97 to 1.01 g/cm³
Evaporation Rate
Not available.
Decomposition Temperature
Not available.
Lower Explosive Limit
Not available.
Solubility
Not available.
Physical State Data
liquid
Form
---
Kinematic Viscosity
>40 mm²/s (>40 cSt)
Relative Density
Not available.
Boiling Point
>35°C (>95°F)
Dynamic Viscosity
---
Odor
Sharp.
Freezing Point
---
Flammability
Highly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge. Flammable in the presence of the following materials or conditions: heat.
Molecular Weight
---
Softening Point
---
Colour
White.
Voc Content
---
Properties Status
---
Metal Corrosion
---
Solidification Point
---
Flash Point
10°C (50°F)
Solubility In Fat
---
Relative Evaporation Rate
---
Appearance
---
State Under Standard Conditions
---
Vapor Density
---
Melting Point
Not available.
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible

Reactive or incompatible with the following materials: oxidizing materials

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Disposal

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1133
Shipping Name
ADHESIVES
Transport Class
3
Packing Group
II
ADR

The environmentally hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.

IMDG

223, 955

IATA

The environmentally hazardous substance mark may appear if required by other transportation regulations.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Plastic-Bond Hardener?

The signal word is danger.

What is the physical form of Plastic-Bond Hardener?

Plastic-Bond Hardener is a liquid. with white. color. It has sharp. odor.

What is the solubility of Plastic-Bond Hardener?

Not available.

What is Plastic-Bond Hardener used for?

Hardener for resins. Adhesives

What are the hazard statements for Plastic-Bond Hardener?

This substance has 4 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H335: May cause respiratory irritation.

What is the melting point of Plastic-Bond Hardener?

The melting point is Not available. and the boiling point is >35°C (>95°F).

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