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Safety Data Sheet EN

606865 - R14084A

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
606865 - R14084A

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Passenger Car Oils

Uses advised against

None identified.

Manufacturers & Suppliers

LUBRIZOL FRANCE logo

LUBRIZOL FRANCE

manufacturer

25 QUAI DE FRANCE CS 61062 76173 ROUEN CEDEX, 76173 FR

(33) 02.35.58.14.00

http://www.mylubrizol.com

Emergency Contacts

CHEMTREC

(+1) 703 527 3887

Emergency Contact

09.75.18.14.07

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Aquatic Chronic Cat. 3 H412

GHS Pictograms

GHS07 - Health hazard

GHS07

Hazard Statements

H315 Causes skin irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements

P264 Wash face, hands and any exposed skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/ container to an approved facility in accordance with local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Mineral oil --- 10 - 20% Yes
Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC: 283-392-8 --- 6.25 - 10% Yes
Diphenylamine EC: 204-539-4 --- 0.25 - 1% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove exposed person to fresh air if adverse effects are observed.

Skin contact

Take off contaminated clothing and wash before re-use. Wash skin thoroughly with soap and water. Wash with soap and water. If skin irritation occurs, get medical attention. Get medical attention if symptoms occur. Launder contaminated clothing before reuse.

Eye contact

Flush thoroughly with water. If irritation occurs, get medical assistance. Remove contact lenses, if present and easy to do. Continue rinsing.

Ingestion

Rinse mouth. Get medical attention if symptoms occur.

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, Dry chemical or Foam. Water can be used to cool and protect exposed material.

Unsuitable media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards

Material creates a special hazard because it floats on water. See section 10 for additional information.

Instructions

No data available.

Firefighter Protection

Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full facepiece, coat, pants, gloves and boots.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away.

Large spill

Dike far ahead of larger spill for later recovery and disposal.

Environmental

Avoid release to the environment. Prevent further leakage or spillage if safe to do so.

Cleanup methods

Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material.

Materials: inert material

—

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin. Observe good industrial hygiene practices. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Launder contaminated clothing before reuse. Avoid environmental contamination. Keep container closed when not in use and use with adequate ventilation.

Storage

Keep container closed when not in use.

Hygiene

Observe good industrial hygiene practices. Wash hands thoroughly after handling. Launder contaminated clothing before reuse.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Material should be handled in enclosed vessels and equipment, in which case general (mechanical) room ventilation should be sufficient. Local exhaust ventilation should be used at points where dust, mist, vapors or gases can escape into the room air.

Hands

Use nitrile or neoprene gloves. Use good industrial hygiene practices. In case of skin contact, wash hands and arms with soap and water. Gloves are recommended when handling this material. Unless material is used in a process where the use of gloves would pose sufficient risk of injury to the user/operator. Consult with an industrial hygienist to determine the appropriate clothing protection for your specific use of this material. For typical use and handling of chemical substances, gloves should meet the standards set out in EN 374. For applications involving mechanical risks with potential for abrasion or puncture, the standards set out in EN 388 should be considered. For continuous contact, we suggest gloves with a minimum breakthrough time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

Eyes

Wear tight-fitting goggles or face shield. Eye protection should meet the standards set out in EN 166.

Respiratory

A respiratory protection program compliant with all applicable regulations must be followed whenever workplace conditions require the use of a respirator. Use respirator with an organic vapor and dust/mist cartridge if the recommended exposure limit is exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. Use respirator with an organic vapor cartridge if exposure limit is exceeded. Respiratory Protective Equipment (RPE) is not normally required where there is adequate natural or local exhaust ventilation to control exposure. In case of insufficient ventilation, wear suitable respiratory equipment.

Skin/Body

Wear apron or protective clothing in case of contact. Do not wear rings, watches or similar apparel that could entrap the material. Chemical resistant boots.

Environmental

No data available. See section 6 for details.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Dark amber
Colour
Dark amber
Colour Intensity
---
Form
liquid
Odor
Characteristic
Odor Threshold
No data available.
Ph
Not applicable
Melting Point
---
Boiling Point
No data available.
Flash Point
130 °C (Pensky-Martens Closed Cup)
Freezing Point
No data available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
No data available.
Vapor Pressure
No data available.
Vapor Density
---
Relative Density
0.997 (15.6 °C)
Bulk Density
---
Density
---
Flammability
No data available.
Upper Explosive Limit
No data available.
Lower Explosive Limit
No data available.
Explosive Limits
---
Auto Ignition Temperature
No data available.
Decomposition Temperature
No data available.
Solubility
---
Partition Coefficient
No data available.
Solubility In Water
Insoluble in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
No data available.
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
340 mm2/s (40 °C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Material is stable under normal conditions.

Reactivity

No data available.

Hazardous reactions

Will not occur.

Avoid

Excessive heat.

Incompatible

Strong oxidizing agents.

Decomposition

Thermal decomposition or combustion may generate smoke, carbon monoxide, carbon dioxide, nitrogen oxides, and other products of incomplete combustion. Diphenylamine and alkenes may also be released.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Ecotoxicity

Fish Mineral oil LC 50 (Fathead Minnow, 4 d): > 100 mg/l

12.1 Ecotoxicity

Fish Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts LC 50 (Rainbow Trout, 4 d): 4.5 mg/l LC 50 (Sheepshead Minnow, 4 d): 46 mg/l

12.1 Ecotoxicity

Fish Diphenylamine LC 50 (Not reported, 2 d): 2.2 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Mineral oil EC 50 (Water flea (Daphnia magna), 2 d): > 10,000 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 10 mg/l NOEC (Water flea (Daphnia magna), 21 d): > 10 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Water flea (Daphnia magna), 2 d): 23 mg/l EC 50 (Water flea (Daphnia magna), 21 d): > 0.8 mg/l NOEC (Water flea (Daphnia magna), 21 d): 0.4 mg/l

12.1 Ecotoxicity

Aquatic Invertebrates Diphenylamine EC 50 (Water flea (Daphnia magna), 2 d): 0.31 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Mineral oil EC 50 (Green algae (Scenedesmus quadricauda), 3 Days): > 100 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Green algae (Scenedesmus quadricauda), 3 d): 21 mg/l NOEC (Green algae (Scenedesmus quadricauda), 3 d): 10 mg/l

12.1 Ecotoxicity

Toxicity to Aquatic Plants Diphenylamine EC 50 (Green algae (Selenastrum capricornutum), 3 d): 1.51 mg/l

12.1 Ecotoxicity

Toxicity to microorganisms Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts EC 50 (Sludge, 0.1 d): > 10,000 mg/l

12.2 Persistence and Degradability

Biodegradation Mineral oil OECD TG 301 B, 31 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts OECD TG 301 B, 1.5 %, 28 d, Not readily degradable.

12.2 Persistence and Degradability

Biodegradation Diphenylamine OECD TG 301 D, 26 %, 28 d, Not readily degradable.

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF) No data available Partition Coefficient n-octanol / water (log Kow)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr)esters, zinc salts Log Kow: 0.56 (Measured)

12.3 Bioaccumulative potential

Partition Coefficient n-octanol / water (log Kow) Diphenylamine Log Kow: 3.4 (calculated)

12.4 Mobility

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Endocrine Disruption:

Product: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

The substance/mixture does not contain components considered to have endocrine disrupting properties at levels of 0.1% or higher.

12.7 Other adverse effects

Product: Harmful to aquatic life with long lasting effects.

Harmful to aquatic life with long lasting effects.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

Disposal

Dispose of packaging or containers in accordance with local, regional, national and international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Regulatory compliance information for the product as per SDS Section 15.

Chemical Safety Assessment Not performed

The information that was used to confirm the compliance status of this product may deviate from the chemical information shown in Section 3.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 606865 - R14084A?

The signal word is warning.

What is the physical form of 606865 - R14084A?

606865 - R14084A is a liquid appearing as dark amber with dark amber color. It has characteristic odor.

What is 606865 - R14084A used for?

Passenger Car Oils

What are the hazard statements for 606865 - R14084A?

This substance has 2 hazard statements:

  • H315: Causes skin irritation.
  • H412: Harmful to aquatic life with long lasting effects.