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Safety Data Sheet EN

2-Methyl-5-pyridylzinc bromide, 0.5M in THF

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
2-Methyl-5-pyridylzinc bromide, 0.5M in THF
Product Code
H58043

Regulatory Identifiers

CAS Number
N/A

Identified Uses

SU24 Scientific research and development

Manufacturers & Suppliers

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc. logo

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

http://www.alfa.com

Emergency Contacts

Emergency Contact

(800) 343-0660

Monday-Friday, 8am-7pm EST

Carechem 24

(866) 928-0789

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
Water-react. Cat. 2 H261
Carc. Cat. 2 H351
Skin Corr. Cat. 1B H314
STOT SE Cat. 3 H335

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor.
H261 In contact with water releases flammable gas.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P231 + P232 Handle under inert gas. Protect from moisture.
P303 + P361 + P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Mixtures

Chemical Name CAS Number Concentration Hazardous
Tetrahydrofuran 109-99-9 87.64% Yes
2-Methyl-5-pyridylzinc bromide --- 12.36% Yes

None known.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Ingestion

Seek medical treatment.

Immediate Medical Attention

Seek immediate medical advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

sand, carbon dioxide or powdered extinguishing agent

Unsuitable media

Water

Specific hazards

If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide, Nitrogen oxides (NOx), Hydrogen bromide (HBr), Zinc oxide

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation. Keep away from ignition sources.

Environmental

Do not allow product to reach sewage system or any water course.

Cleanup methods

Absorb with liquid-binding material

Materials: sand, diatomite, acid binders, universal binders, sawdust

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle under dry protective gas. Keep container tightly sealed. Ensure good ventilation at the workplace. Open and handle container with care. Reacts violently with water.

Storage

Refrigerate. Store under dry inert gas. Protect from heat. Protect from humidity and water.

Fire prevention

Protect against electrostatic charges. Keep ignition sources away.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Penetration time of glove material (in minutes) Not determined

Eyes

Tightly sealed goggles Full face protection

Respiratory

Use suitable respirator when high concentrations are present. Recommended filter device for short term use: Use a respirator with organic vapor/acid gas cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards such as NIOSH (USA) or CEN (EU).

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid
Colour
Yellow to brown to black
Colour Intensity
---
Form
Liquid
Odor
Not determined
Odor Threshold
Not determined.
Ph
Not determined.
Melting Point
Not determined
Boiling Point
66 °C (151 °F) (THF)
Flash Point
-17 °C (1 °F) (THF)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not determined.
Vapor Pressure
200 hPa (150 mm Hg) (THF)
Vapor Density
Not determined.
Relative Density
Not determined.
Bulk Density
---
Density
Not determined
Flammability
Not determined (solid, gaseous)
Upper Explosive Limit
11.8 Vol % (THF)
Lower Explosive Limit
2.0 Vol % (THF)
Explosive Limits
---
Auto Ignition Temperature
-321 °C (610 °F) (THF)
Decomposition Temperature
Not determined
Solubility
Contact with water releases flammable gases
Partition Coefficient
Not determined.
Solubility In Water
Contact with water releases flammable gases
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
Not determined.
Kinematic Viscosity
Not determined.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

In contact with water releases flammable gases which may ignite spontaneously. May form explosive peroxides.

Hazardous reactions

Reacts with strong oxidizing agents Contact with water releases flammable gases May form explosive peroxides.

Avoid

No further relevant information available.

Incompatible

Acids, Air, Oxidizing agents, Acid chlorides, Heat, Water/moisture

Decomposition

Carbon monoxide and carbon dioxide, Zinc oxide, Hydrogen bromide, Nitrogen oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3399
Shipping Name
Organometallic substance, liquid, water-reactive, flammable (3,4-Difluorobenzylzinc bromide, Tetrahydrofuran)
Transport Class
4.3
Packing Group
II
IMDG

Warning: Substances which, in contact with water, emit flammable gases

IATA

Warning: Substances which, in contact with water, emit flammable gases

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 2-Methyl-5-pyridylzinc bromide, 0.5M in THF?

The signal word is danger.

What is the physical form of 2-Methyl-5-pyridylzinc bromide, 0.5M in THF?

2-Methyl-5-pyridylzinc bromide, 0.5M in THF is a liquid appearing as liquid with yellow to brown to black color. It has not determined odor.

What is the solubility of 2-Methyl-5-pyridylzinc bromide, 0.5M in THF?

Contact with water releases flammable gases

What is 2-Methyl-5-pyridylzinc bromide, 0.5M in THF used for?

SU24 Scientific research and development

What are the hazard statements for 2-Methyl-5-pyridylzinc bromide, 0.5M in THF?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor.
  • H261: In contact with water releases flammable gas.
  • H314: Causes severe skin burns and eye damage.
  • H335: May cause respiratory irritation.
  • H351: Suspected of causing cancer.

What is the melting point of 2-Methyl-5-pyridylzinc bromide, 0.5M in THF?

The melting point is Not determined and the boiling point is 66 °C (151 °F) (THF).