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Safety Data Sheet EN

Silicon

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Silicon

Regulatory Identifiers

CAS Number
N/A
REACH No.
01-2119480401-47-0287

Identified Uses

Alloying into aluminium, Production of silicones (siloxanes) via (CH₃)₂SiCl₂, Production of electronic grade silicon via HSiCl₃, Production of synthetic amorphous silica via SiCl₄, Other industrial applications.

Manufacturers & Suppliers

PCC BakkiSilicon hf logo

PCC BakkiSilicon hf

manufacturer

Bakkavegur 2, 640 Húsavík

+354 4640060

http://www.pcc.is

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Silicon EC: 231-130-8 7440-21-3 --- No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Fresh air.

Symptoms: Irritation caused by dust

Skin contact

Wash contaminated skin with water and/or mild detergent

Eye contact

Rinse eyes with water/saline solution. If discomfort persists, obtain medical attention.

Ingestion

Remove the person affected from the dust-exposed area. See inhalation.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Dry sand, CO₂ or dry powder.

Specific hazards

Lump silicon is not combustible. Dusts of silicon with particle diameter < 75 µm can be ignited and will propagate flame. Silicon dust suspended in air may under certain conditions cause dust explosions.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Cleanup methods

Released material should be collected in suitable containers. Dry dust can be vacuumed or swept up.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid dust generation. Avoid ignition sources (e.g. welding) in areas with high dust concentrations. Addition of wet material to molten silicon may cause explosions.

Storage

Keep product dry.

Fire prevention

Avoid ignition sources (e.g. welding) in areas with high dust concentrations.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Adequate ventilation

Hands

Use protective gloves

Eyes

Use eye protection

Respiratory

Wear a particulate respirator according to EN 149 FFP 2S in areas of inadequate ventilation.

Environmental

Target value and limit value for PM10 and PM2.5 (Directive 2008/50/EC): PM10 (One day: 50 μg/m³*, Calendar year: 40 μg/m³), PM2.5 (Calendar year: 25 μg/m³). *Not to be exceeded more than 35 times a calendar year.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Evaporation Rate
---
Form
Lump material
Softening Point
---
Relative Evaporation Rate
---
Solubility In Fat
---
Flash Point
---
Voc Content
---
Kinematic Viscosity
---
Decomposition Temperature
---
Odor
Odourless
Freezing Point
---
Cloud Point
---
Partition Coefficient
---
Flammability
---
Physical State Data
solid
Colour Intensity
---
Properties Status
---
Appearance
Silvery material
Molecular Weight
---
Vapor Density
---
Physical State
Crystalline
Melting Point
Approx. 1410°C
Lower Explosive Limit
---
Auto Ignition Temperature
---
Bulk Density
---
Metal Corrosion
---
Boiling Point
Approx. 2355°C
Solubility
---
Explosive Limits
---
Crystallisation Point
---
Relative Density
Approx. 2.3
Odor Threshold
---
Vapor Pressure
---
Ph
---
Dynamic Viscosity
---
Solubility In Water
Insoluble/slightly soluble
Density
---
Colour
Silvery
Upper Explosive Limit
---
Solidification Point
---
State Under Standard Conditions
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Reactivity

Silicon is insoluble in most acids, but dissolves in a mixture of hydrofluoric acid (HF) and nitric acid (HNO3) evolving hazardous gases. Impurities present in silicon (e.g. Al and Ca) may react with dilute acids evolving hazardous gases. Silicon dissolves readily in dilute lye.

Hazardous reactions

Silicon-particles suspended in air at concentrations above 100 g/m³ can cause dust explosions. Addition of wet material to molten silicon may cause explosions.

Avoid

Avoid generating sparks or other ignition sources (e.g. welding) in areas with high dust concentrations. Addition of wet material to molten silicon may cause explosions.

Incompatible

Acids (hydrofluoric acid, nitric acid), dilute lye.

Decomposition

A reaction with hydrofluoric acid (HF) and nitric acid (HNO3) leads to the formation of toxic gases such as silicon tetrafluoride (SiF4) or nitrous gases (NOx). Impurities in silicon may react with dilute acids forming flammable and harmful gases such as hydrogen (H2) and silane (SiH4). Wet product will form flammable hydrogen gas if added to molten silicon, due to decomposition of water.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The material should be recovered for recycling if possible.

Disposal

Dispose of waste product according to applicable federal, state and local rules for non-hazardous solid waste materials.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
Not applicable
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Silicon?

The signal word is no signal word.

What is the physical form of Silicon?

Silicon is a crystalline appearing as silvery material with silvery color. It has odourless odor.

What is Silicon used for?

Alloying into aluminium, Production of silicones (siloxanes) via (CH₃)₂SiCl₂, Production of electronic grade silicon via HSiCl₃, Production of synthetic amorphous silica via SiCl₄, Other industrial applications.

What is the melting point of Silicon?

The melting point is Approx. 1410°C and the boiling point is Approx. 2355°C.