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Safety Data Sheet EN

Kerosene

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Kerosene
Synonyms
Kero, Kerosine Motor Fuel, Ultra Low Sulfur Kero, ULSK, Dyed Kerosene Dye, K1, K2, Fuel Oil No 1, JP-4, JP-5, JP-8 Jet Fuels, Coal-oil, Range-oil, Pesticide Code 063501, SRK Solvent, Low Aromatic Feedstock, Artic Grade Oil (DFA)

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Fuel

Manufacturers & Suppliers

Global Companies LLC logo

Global Companies LLC

distributor

Water Mill Center, 800 South St., Waltham, MA 02454-9161

800-542-0778

http://www.globalp.com

Emergency Contacts

CHEMTREC

(800) 424-9300

24 hrs

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Skin Irrit. Cat. 2 H315
Asp. Tox. Cat. 1 H304
STOT SE Cat. 3 H336
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes Skin irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment pursuant to applicable electrical code.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P331 Do NOT induce vomiting.
P370 + P378 In case of fire use firefighting foam or other appropriate media for Class B fires to extinguish.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulation.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse with water/shower.
If exposed or concerned: Get medical advice/attention.
If swallowed: Immediately call a poison center/doctor/...
Store in a well-ventilated place. Keep cool.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

A complex combination of hydrocarbons including naphthenes, paraffins, and aromatics.

Chemical Name CAS Number Concentration Hazardous
Kerosene 8008-20-6 100% Yes
Naphthalene 91-20-3 0.04% Yes

A complex combination of hydrocarbons including naphthenes, paraffins, and aromatics.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove person to fresh air. If person is not breathing, ensure an open airway and provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately. If inhaled, administer oxygen or establish a patent airway if breathing is labored. Suction if necessary. Monitor closely, anticipate seizures. Consider orotracheal or nostracheal intubation of airway control if patient is unconscious or is in severe respiratory distress.

Symptoms: Irritation, respiratory insufficiency, pulmonary edema.

Skin contact

Remove contaminated clothing and shoes. Wash contaminated areas thoroughly with soap and water or waterless hand cleanser. Obtain medical attention if irritation or redness develops. Thermal burns require immediate medical attention depending on the severity and of the area of the body burned. For contact with skin or eyes, immediately wash or flush contaminated eyes with gently flowing water.

Symptoms: Dermatitis (itching, irritation, pain and swelling).

Eye contact

In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold eyelids open to ensure adequate flushing. Seek medical attention. In case of contact lenses, remove immediately. For contact with skin or eyes, immediately wash or flush contaminated eyes with gently flowing water. If possible, irrigate each eye continuously with 0.9% saline (NS).

Symptoms: Irritation.

Ingestion

Aspiration Hazard: DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated. If ingested, rinse mouth and administer 5 m/kg up to 200 ml of water of dilution if the patient can swallow. Do NOT induce vomiting, as this may cause chemical pneumonia (fluid in the lungs).

Symptoms: Chemical pneumonia (fluid in the lungs).

Immediate Medical Attention

Seek medical attention immediately for inhalation. Obtain immediate medical attention for ingestion. Seek medical attention for eye contact. Obtain medical attention if irritation or redness develops for skin contact.

Medical Treatment

Monitor closely, anticipate seizures. Consider orotracheal or nostracheal intubation of airway control if patient is unconscious or is in severe respiratory distress.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Foam, carbon dioxide, dry chemical are most suitable. SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, firefighting foam, or Halon. LARGE FIRES: Foam, carbon dioxide, dry chemical. Firefighting foam suitable for polar solvents is recommended for fuel with greater than 10% oxygenate concentration.

Unsuitable media

Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers.

Specific hazards

Moderate fire hazard when exposed to heat or flame with a very low flash point. Flammable and easily ignited when exposed to heat, spark, open flame or other source of ignition. Flowing product may be ignited by self-generated static electricity. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard.

Instructions

Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied firefighting foam.

Firefighter Protection

Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH- approved pressure-demand self-contained breathing apparatus with full face piece and protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

ACTIVATE FACILITY SPCC, SPILL CONTINGENCY or EMERGENCY PLAN. Isolate spill or leak area. Secure all ignition sources (flame, spark, hot work, hot metal, etc.) from area. Evaluate the direction of product travel, diking sewers, etc. to confirm spill areas. Do not touch or walk-through spilled material.

Large spill

isolate initial action distance downwind 1,000 ft. (300 m)

Environmental

Stop the spill to prevent environmental release if it can be done safely. Product is toxic to aquatic life. Take action to isolate environmental receptors including drains, storm sewers and natural water bodies.

Cleanup methods

Take up with dry earth, sand or other non-combustible, inert oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container with clean, non-sparking tools for reclamation or disposal.

Materials: dry earth, sand or other non-combustible, inert oil absorbing materials

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle as a combustible liquid. Keep away from heat, sparks, and open flame. No smoking. Bond and ground containers during product transfer. Use good personal hygiene practices. Avoid repeated and/or prolonged skin exposure. Use only outdoors or in well ventilated areas. Wash hands before eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning solvent on the skin. Promptly remove contaminated clothing and launder before reuse. Emergency eye wash capability should be available in the near proximity to operations presenting a potential splash exposure.

Storage

Large quantities stored in cylindrical floating-roof or fixed-roof tanks at an ambient storage temperature. Separate from incompatible chemicals. Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers that are clearly labeled. If stored in small containers, the area should be well ventilated and protected from potential damage or vehicular traffic.

Hygiene

Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this product from exposed skin areas. Promptly remove contaminated clothing and launder before reuse.

Fire prevention

Keep away from heat, sparks, and open flame. No smoking. Bond and ground containers during product transfer. Follow precautions to prevent static initiated fire.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. Intrinsically safe equipment and non-sparking tools shall be used in circumstances where concentrations may exceed lower flammable limits. Grounding and bonding shall be used to prevent accumulation and discharge of static electricity.

Hands

Gloves constructed of nitrile, neoprene or PVC are recommended when handling this material. Note: The resistance of specific material may vary from product to product as well as with degree of exposure.

Eyes

Wear appropriate chemical protective glasses or goggles or face shields to prevent skin and eye contact especially caused from splashing.

Respiratory

A NIOSH/MSHA-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA 29 CFR 1910.134, ANSI Z88.2-1992, NIOSH Respirator Decision Logic, and the manufacturer for additional guidance on respiratory protection selection and limitations. Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection.

Skin/Body

Wear appropriate personal protective clothing to prevent skin contact. Chemical protective clothing such as of E.I. DuPont TyChem®, Saranex® or equivalent recommended based on degree of exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Pale yellow to water-white. May be dyed red.
Colour
---
Colour Intensity
---
Form
---
Odor
Strong characteristic petroleum distillate odor.
Odor Threshold
1 ppm
Ph
Not available
Melting Point
-4 °F (-20 °C)
Boiling Point
300 to 580 °F (149 to 304 °C)
Flash Point
100.4 – 125.6 °F (38 -52 °C)
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Slow, varies with conditions
Vapor Pressure
0.480 mm Hg @ 20 °C
Vapor Density
4.5 (air=1)
Relative Density
0.80 to <1.0 (water=1)
Bulk Density
---
Density
---
Flammability
Flammable liquid
Upper Explosive Limit
5.0%
Lower Explosive Limit
0.7%
Explosive Limits
---
Auto Ignition Temperature
410 °F (210 °C)
Decomposition Temperature
When heated it emits acrid smoke and irritating vapors.
Solubility
Insol in water; miscible with other petroleum solvents.
Partition Coefficient
Log Kow range of 3.3 to >.6.0
Solubility In Water
Insol in water
Solubility In Fat
---
Molecular Weight
---
Voc Content
100
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
1.39 – 1.50 mm2/x (40C)
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

This is a stable material that is flammable liquid (OSHA/GHS hazard category 3). Stable during transport.

Reactivity

Material is not self-reacting. Flammable concentrations may be present in air. Compound can react with oxidizing materials.

Hazardous reactions

Hazardous polymerization will not occur.

Avoid

Avoid high temperatures, open flames, sparks, static electricity, welding, smoking and other ignition sources.

Incompatible

Keep away from strong oxidizers such as nitric and sulfuric acids.

Decomposition

Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Consult federal, state and local waste regulations to determine appropriate disposal options.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1223
Shipping Name
Kerosene
Transport Class
3
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This product is a 'Hazardous Chemical' as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Kerosene known by?

Kerosene is also known as: Kero, Kerosine Motor Fuel, Ultra Low Sulfur Kero, ULSK, Dyed Kerosene Dye, K1, K2, Fuel Oil No 1, JP-4, JP-5, JP-8 Jet Fuels, Coal-oil, Range-oil, Pesticide Code 063501, SRK Solvent, Low Aromatic Feedstock, Artic Grade Oil (DFA)

What is the hazard signal word for Kerosene?

The signal word is danger.

What is the physical form of Kerosene?

Kerosene is a liquid appearing as pale yellow to water-white. may be dyed red. . It has strong characteristic petroleum distillate odor. odor.

What is the solubility of Kerosene?

Insol in water; miscible with other petroleum solvents.

What is Kerosene used for?

Fuel

What are the hazard statements for Kerosene?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapor.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes Skin irritation.
  • H336: May cause drowsiness or dizziness.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of Kerosene?

The melting point is -4 °F (-20 °C) and the boiling point is 300 to 580 °F (149 to 304 °C).