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Safety Data Sheet EN

Dichloromethane a.r.

CAS 75-09-2
EC 200-838-9

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Dichloromethane a.r.
Product Form
Substance
Product Code
CL00.0404
Chemical Name
Dichloromethane
Synonyms
aerothene MM / DCM (=dichloromethane) / dichloromethane / F 30 (chlorocarbon) / freon 30 / hcc 30 / khmadon 30 / methane dichloride / methane, dichloro- / methylene bichloride / methylene chloride / methylene dichloride / narkotil / R30 / R30 (refrigerant) / solaesthin / soleana vda / solmethine

Regulatory Identifiers

CAS Number
75-09-2 Check regulations →
EC Number
200-838-9 Check regulations →
REACH No.
01-2119487001-48

Identified Uses

Laboratory chemical

Manufacturers & Suppliers

Chem-Lab nv logo

Chem-Lab nv

manufacturer

Industriezone 'De arend 2', Zedelgem – Belgium

+32 50 288320

https://www.chem-lab.be

Emergency Contacts

Emergency Contact

+32 50 28 83 20

Centre Anti-Poisons/Antigifcentrum c/o Hôpital Militaire Reine Astrid

+32 70 245 245

Centre Anti-Poisons/Antigifcentrum c/o Hôpital Militaire Reine Astrid

02 264 96 30

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2 H319
Carc. Cat. 2 H351
STOT SE Cat. 3 H336
STOT SE Cat. 3 H335
STOT RE Cat. 2 H373

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements

P201 Obtain special instructions before use.
P260 Do not breathe dusts or mists.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Dichloromethane a.r. EC: 200-838-9 75-09-2 100% Yes

Notes

Full text of H- and EUH-statements: see section 16

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim into fresh air. In case of respiratory problems, consult a doctor/medical service.

Symptoms: Dry/sore throat. Coughing. EXPOSURE TO HIGH CONCENTRATIONS: Headache. Nausea. Feeling of weakness. Dizziness. Coordination disorders. Impaired concentration. Change in the haemogramme/blood composition. ON CONTINUOUS EXPOSURE/CONTACT: Respiratory difficulties. Disturbances of consciousness.

Skin contact

If possible, wipe up/dry remove chemical. Then rinse/shower immediately with (lukewarm) water.

Symptoms: No effects known.

Eye contact

Rinse immediately with (lukewarm) water. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation persists, consult a doctor/medical service.

Symptoms: No effects known.

Ingestion

Rinse mouth with water. If you feel unwell, consult a doctor/medical service. Do not wait for symptoms to occur to consult Poison Center.

Symptoms: AFTER INGESTION OF HIGH QUANTITIES: Nausea. Dry/sore throat. Gastrointestinal complaints.

Immediate Medical Attention

After possible exposure, consult a doctor/medical service.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Quick-acting ABC powder extinguisher. Quick-acting BC powder extinguisher. Quick-acting class B foam extinguisher. Quick-acting CO2 extinguisher. Class B foam (alcohol-resistant). Water spray if puddle cannot expand.

Unsuitable media

Water (quick-acting extinguisher, reel); risk of puddle expansion. Water; risk of puddle expansion.

Specific hazards

DIRECT FIRE HAZARD: Flammable in the presence of a high energy source. Gas/vapour flammable with air within explosion limits. INDIRECT FIRE HAZARD: Heating increases the fire hazard. Reactions involving a fire hazard: see "Reactivity Hazard". DIRECT EXPLOSION HAZARD: Gas/vapour explosive within explosion limits if energy source high. INDIRECT EXPLOSION HAZARD: Heat may cause pressure rise in tanks/drums: explosion risk. Reactions with explosion hazards: see "Reactivity Hazard".

Instructions

Cool tanks/drums with water spray/remove them into safety. Physical explosion risk: extinguish/cool from behind cover. Do not move the load if exposed to heat. After cooling: persistent risk of physical explosion. Dilute toxic gases with water spray. Take account of toxic/corrosive precipitation water.

Firefighter Protection

Heat/fire exposure: self-contained breathing apparatus (EN 136 + EN 137).

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep upwind. Mark the danger area. Seal off low-lying areas. Close doors and windows of adjacent premises. No naked flames. Keep containers closed. Wash contaminated clothes. Large spills/in confined spaces: consider evacuation. In case of reactivity hazard: consider evacuation.

Large spill

Large spills/in confined spaces: consider evacuation.

Environmental

Prevent spreading in sewers.

Cleanup methods

Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Damaged/cooled tanks must be emptied. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority.

Materials: sand, earth, vermiculite

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use earthed equipment. Keep away from naked flames/heat. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Keep container tightly closed.

Storage

Store in a cool area. Store in a dry area. Store in a dark area. Keep container in a well-ventilated place. Unauthorized persons are not admitted. Store only in a limited quantity.

Hygiene

Observe strict hygiene.

Fire prevention

Keep away from naked flames/heat. Provide the tank with earthing.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No additional information available

Hands

Protective gloves against chemicals (EN 374)

Eyes

Eye protection not required in normal conditions

Respiratory

Full face mask with filter type AX at conc. in air > exposure limit. High vapour/gas concentration: self-contained breathing apparatus (EN 136 + EN 137)

Skin/Body

Protective clothing (EN 14605 or EN 13034)

Environmental

No additional information available

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Liquid
Colour
Colourless
Colour Intensity
---
Form
---
Odor
Ether-like odour
Odor Threshold
Not available
Ph
Not available
Melting Point
-95 °C
Boiling Point
40 °C
Flash Point
Not quantifiable
Freezing Point
Not available
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
27.5 (butylacetate=1), 1.8 (ether=1)
Evaporation Rate
---
Vapor Pressure
584 hPa (25 °C)
Vapor Density
---
Relative Density
1.33 (20 °C)
Bulk Density
---
Density
1.32 g/ml
Flammability
Not available
Upper Explosive Limit
22 vol %
Lower Explosive Limit
13 vol %
Explosive Limits
---
Auto Ignition Temperature
605 °C
Decomposition Temperature
> 120 °C
Solubility
Moderately soluble in water. Substance sinks in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in tetrachloromethane. Soluble in dimethylformamide. Water: 1.3 g/100ml (25 °C)
Partition Coefficient
1.25 (Log Pow)
Solubility In Water
1.3 g/100ml (25 °C)
Solubility In Fat
---
Molecular Weight
84.93 g/mol
Voc Content
100 %
Metal Corrosion
---
Dynamic Viscosity
0.42 mPa·s (20 °C)
Kinematic Viscosity
No data available in the literature
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

On heating under increased oxygen concentration: (increased) risk of fire/explosion. Reacts on exposure to water and heat with (some) metals.

Hazardous reactions

No additional information available

Avoid

No additional information available

Incompatible

No additional information available

Decomposition

Violent to explosive reaction with many compounds e.g. with (some) acids, with (some) metal powders and with (strong) oxidizers: (increased) risk of fire/explosion and formation of small quantities of phosgene. Decomposes slowly on exposure to water (moisture): release of toxic and corrosive gases/vapours (hydrogen chloride).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of at authorized waste collection point. Remove waste in accordance with local and/or national regulations.

Disposal

Do not discharge into surface water (Directive 2000/60/EC, Council Decision 2455/2001/EC). Do not discharge into drains or the environment.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1593
Shipping Name
dichloromethane
Transport Class
6.1
Packing Group
III
ADR

Subject to the provisions

IMDG

Subject to the provisions

IATA

Subject to the provisions

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Dichloromethane a.r. known by?

Dichloromethane a.r. is also known as: aerothene MM / DCM (=dichloromethane) / dichloromethane / F 30 (chlorocarbon) / freon 30 / hcc 30 / khmadon 30 / methane dichloride / methane, dichloro- / methylene bichloride / methylene chloride / methylene dichloride / narkotil / R30 / R30 (refrigerant) / solaesthin / soleana vda / solmethine

What is the hazard signal word for Dichloromethane a.r.?

The signal word is warning.

What is the physical form of Dichloromethane a.r.?

Dichloromethane a.r. is a liquid appearing as liquid with colourless color. It has ether-like odour odor.

What is the solubility of Dichloromethane a.r.?

Moderately soluble in water. Substance sinks in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in tetrachloromethane. Soluble in dimethylformamide. Water: 1.3 g/100ml (25 °C)

What is Dichloromethane a.r. used for?

Laboratory chemical

What are the hazard statements for Dichloromethane a.r.?

This substance has 6 hazard statements:

  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.
  • H373: May cause damage to organs through prolonged or repeated exposure.

What is the melting point of Dichloromethane a.r.?

The melting point is -95 °C and the boiling point is 40 °C.