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Safety Data Sheet EN

Styrene Monomer

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Styrene Monomer
Product Code
Q9215

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Base chemical for the production of polystyrene, rubbers and resins.

Uses advised against

resins.

Manufacturers & Suppliers

S

Shell Eastern Trading (PTE) Ltd

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9 North Buona Vista Drive, #07-01 Tower 1, The Metropolis Singapore 138588 Singapore

+65-6384 8000

Emergency Contacts

Emergency Contact

+44 (0) 151 350 4595

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3
Acute Tox. Cat. 4
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2
Asp. Tox. Cat. 1
STOT SE Cat. 3
STOT RE Cat. 1
Aquatic Acute Cat. 2

GHS Pictograms

GHS02 - Flammable

GHS02

GHS08 - Serious health hazard

GHS08

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
H401 Toxic to aquatic life.

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P235 Keep cool.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use appropriate media for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
Styrene EC: 202-851-5 100-42-5 100% Yes

Stabilised with tertiary butyl catechol. 10-15 ppm.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. Do not attempt to rescue the victim unless proper respiratory protection is worn. If the victim has difficulty breathing or tightness of the chest, is dizzy, vomiting, or unresponsive, give 100% oxygen with rescue breathing or CPR as required and transport to the nearest medical facility.

Symptoms: difficulty breathing or tightness of the chest, is dizzy, vomiting, or unresponsive, dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness and death. Respiratory irritation signs and symptoms may include a temporary burning sensation of the nose and throat, coughing, and/or difficulty breathing.

Skin contact

DO NOT DELAY. Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment.

Symptoms: redness, swelling, pain and/or blisters, burning sensation.

Eye contact

Immediately flush eyes with large amounts of water for at least 15 minutes while holding eyelids open. Transport to the nearest medical facility for additional treatment.

Symptoms: burning sensation, redness, swelling, and/or blurred vision.

Ingestion

If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Give nothing by mouth. Do NOT induce vomiting.

Symptoms: fever greater than 101 F (38.3 C), shortness of breath, chest congestion or continued coughing or wheezing.

Immediate Medical Attention

Potential for chemical pneumonitis. Call a doctor or poison control center for guidance.

Medical Treatment

Potential for chemical pneumonitis. Call a doctor or poison control center for guidance.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Use sealed systems as far as possible. Adequate explosion-proof ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Firewater monitors and deluge systems are recommended. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Eye washes and showers for emergency use.

Hands

Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739, AS/NZS:2161) made from the following materials may provide suitable chemical protection: Longer term protection: Viton. Incidental contact/Splash protection: Nitrile rubber. For continuous contact we recommend gloves with breakthrough time of more 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended.

Eyes

Chemical splash goggles (chemical monogoggles).

Respiratory

If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are unsuitable (e.g., airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. If air-filtering respirators are suitable for conditions of use: Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65 C (149 F)].

Skin/Body

Chemical resistant gloves/gauntlets, boots, and apron. For spillage clean up use chemical resistant knee length boots. Wear antistatic and flame retardant clothing if a local risk assessment deems it so. Protective clothing approved to EU Standard EN14605.

Environmental

Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. Take appropriate measures to fulfill the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Oily liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colourless to yellowish Oily liquid.
Colour
Colourless to yellowish
Colour Intensity
---
Form
Oily liquid.
Odor
Aromatic hydrocarbon.
Odor Threshold
0.1 ppm
Ph
Not applicable
Melting Point
-31 C / -24 F
Boiling Point
145 C / 293 F
Flash Point
32 C / 90 F(Abel)
Freezing Point
-31 C / -24 F
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
12.4 (ASTM D 3539, nBuAc=1)
Vapor Pressure
670 Pa at 20 C / 68 F
Vapor Density
3.6
Relative Density
Data not available.
Bulk Density
---
Density
906 kg/m3 at 20 C / 68 F
Flammability
Yes, in certain circumstances product can ignite due to static electricity.
Upper Explosive Limit
6.1 %(V)
Lower Explosive Limit
1.1 %(V)
Explosive Limits
---
Auto Ignition Temperature
490 C / 914 F
Decomposition Temperature
Not applicable
Solubility
Organic solvents Soluble.
Partition Coefficient
2.95
Solubility In Water
0.29 kg/m3 at 20 C / 68 F
Solubility In Fat
---
Molecular Weight
104.15 g/mol
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.7 mPa.s at 25 C / 77 F
Kinematic Viscosity
Data not available.
Properties Status
---
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2055
Shipping Name
STYRENE MONOMER, STABILIZED
Transport Class
3
Packing Group
III
ADR

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

IMDG

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

IATA

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Styrene Monomer?

The signal word is danger.

What is the physical form of Styrene Monomer?

Styrene Monomer is a oily liquid. appearing as colourless to yellowish oily liquid. with colourless to yellowish color. It has aromatic hydrocarbon. odor.

What is the solubility of Styrene Monomer?

Organic solvents Soluble.

What is Styrene Monomer used for?

Base chemical for the production of polystyrene, rubbers and resins.

What are the hazard statements for Styrene Monomer?

This substance has 8 hazard statements:

  • H226: Flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H332: Harmful if inhaled.
  • H335: May cause respiratory irritation.
  • H372: Causes damage to organs through prolonged or repeated exposure.
  • H401: Toxic to aquatic life.

What is the melting point of Styrene Monomer?

The melting point is -31 C / -24 F and the boiling point is 145 C / 293 F.

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