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Styrene Monomer

DANGER Oily liquid. SDS/MSDS

Chemical Product Identification & Regulatory Data

Official chemical identifiers, CAS numbers, and regulatory compliance information

Basic Product Information

Product Name
Styrene Monomer
Product Code
Q9211, Q9215

Regulatory Identifiers

CAS Number
N/A

Chemical Abstracts Service registry number - unique identifier for chemical substances

Uses Information

Identified Uses
Base chemical for the production of polystyrene, rubbers and resins.
Uses Advised Against
resins.

Overview

Styrene Monomer is a colourless to yellowish oily liquid. substance commonly used base chemical for the production of polystyrene, rubbers and resins..

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GHS Hazard Classification & Safety Warnings

Globally Harmonized System (GHS) hazard pictograms, signal words, and safety classifications

Classification Status

Classified

Signal Word

danger (Danger)

Hazard Classifications

Flam. Liq. Category 3
Acute Tox. Category 4
Skin Irr. Category 2
Eye Irrit. Category 2
Asp. Tox. Category 1
STOT SE Category 3
STOT RE Category 1
Aquatic Acute Category 2

GHS Hazard Pictograms & Safety Symbols

GHS02 GHS Hazard Pictogram: Flammable hazard - Fire risk materials including gases, liquids, and solids

GHS02

GHS07 GHS Hazard Pictogram: Health hazard warning - Materials harmful to health including irritants and sensitizers

GHS07

GHS08 GHS Hazard Pictogram: Serious health hazard - Carcinogenic, mutagenic, or toxic to organs

GHS08

GHS (Globally Harmonized System) pictograms indicate specific chemical hazard categories and safety precautions

Hazard Statements

  • H226: Flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H332: Harmful if inhaled.
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.
  • H372: Causes damage to organs through prolonged or repeated exposure.
  • H401: Toxic to aquatic life.

Precautionary Statements

  • P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
  • P233: Keep container tightly closed.
  • P240: Ground/bond container and receiving equipment.
  • P241: Use explosion-proof electrical/ventilating/lighting equipment.
  • P242: Use only non-sparking tools.
  • P243: Take precautionary measures against static discharge.
  • P260: Do not breathe dust/fume/gas/mist/vapours/spray.
  • P264: Wash hands thoroughly after handling.
  • P271: Use only outdoors or in a well-ventilated area.
  • P273: Avoid release to the environment.
  • P280: Wear protective gloves/protective clothing/eye protection/face protection.
  • P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
  • P303+P361+P353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower.
  • P332+P313: If skin irritation occurs: Get medical advice/attention.
  • P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P337+P313: If eye irritation persists: Get medical advice/attention.
  • P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
  • P312: Call a POISON CENTER or doctor/physician if you feel unwell.
  • P370+P378: In case of fire: Use appropriate media for extinction.
  • P403+P233: Store in a well-ventilated place. Keep container tightly closed.
  • P405: Store locked up.
  • P235: Keep cool.
  • P501: Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

Chemical Manufacturers & Supply Chain

Authorized suppliers, manufacturers, and distribution network information

Shell Eastern Trading (PTE) Ltd

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๐Ÿ“

9 North Buona Vista Drive, #07-01 Tower 1, The Metropolis Singapore 138588 Singapore

๐ŸŒ

SG

๐Ÿ“ž

+65-6384 8000

24/7 Emergency Response & Poison Control

Critical emergency contact numbers for chemical spills, exposure incidents, and medical emergencies

Emergency Contact

๐Ÿ“ž

+44 (0) 151 350 4595

๐ŸŒ

GB

Chemical Composition & Hazardous Ingredients

Detailed component analysis, concentration ranges, and hazardous substance identification

Chemical Components & Hazardous Substances

Chemical Name CAS Number Concentration Hazardous
Styrene Monomer
EC: 202-851-5
100-42-5 100% โš ๏ธ Hazardous

Additional Information

Stabilised with tertiary butyl catechol. 10-15 ppm.

Emergency First Aid Measures

Critical first aid procedures for chemical exposure incidents and medical emergencies

๐Ÿซ Inhalation Exposure

Remove to fresh air. Do not attempt to rescue the victim unless proper respiratory protection is worn. If the victim has difficulty breathing or tightness of the chest, is dizzy, vomiting, or unresponsive, give 100% oxygen with rescue breathing or CPR as required and transport to the nearest medical facility.

Symptoms:

difficulty breathing or tightness of the chest, is dizzy, vomiting, or unresponsive, dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness and death. Respiratory irritation signs and symptoms may include a temporary burning sensation of the nose and throat, coughing, and/or difficulty breathing.

๐Ÿ–๏ธ Skin Contact

DO NOT DELAY. Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment.

Symptoms:

redness, swelling, pain and/or blisters, burning sensation.

๐Ÿ‘๏ธ Eye Contact

Immediately flush eyes with large amounts of water for at least 15 minutes while holding eyelids open. Transport to the nearest medical facility for additional treatment.

Symptoms:

burning sensation, redness, swelling, and/or blurred vision.

๐Ÿฝ๏ธ Ingestion/Swallowing

If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Give nothing by mouth. Do NOT induce vomiting.

Symptoms:

fever greater than 101 F (38.3 C), shortness of breath, chest congestion or continued coughing or wheezing.

๐Ÿšจ Immediate Medical Attention Required

Potential for chemical pneumonitis. Call a doctor or poison control center for guidance.

Medical Treatment

Potential for chemical pneumonitis. Call a doctor or poison control center for guidance.

Related Chemical Substances & Alternative Products

Similar chemicals with comparable safety profiles and industrial applications

Technical Specifications & Material Properties

Physical state, chemical properties, melting point, boiling point, and material characteristics

๐Ÿงช Physical State
Oily liquid.
Critical Property
๐Ÿ“Š Physical State Data
liquid
๐Ÿ“Š State Under Standard Conditions
Not available
๐Ÿ‘๏ธ Appearance
Colourless to yellowish Oily liquid.
๐ŸŽจ Colour
Colourless to yellowish
๐Ÿ“Š Colour Intensity
Not available
๐Ÿ“Š Form
Oily liquid.
๐Ÿ‘ƒ Odor
Aromatic hydrocarbon.
๐Ÿ“Š Odor Threshold
0.1 ppm
๐Ÿงช Ph
Not applicable
๐ŸงŠ Melting Point
-31 C / -24 F
Critical Property
๐Ÿ’จ Boiling Point
145 C / 293 F
Critical Property
๐Ÿ”ฅ Flash Point
32 C / 90 F(Abel)
Critical Property
๐Ÿ“Š Freezing Point
-31 C / -24 F
๐Ÿ“Š Softening Point
Not available
๐Ÿ“Š Solidification Point
Not available
๐Ÿ“Š Cloud Point
Not available
๐Ÿ“Š Crystallisation Point
Not available
๐Ÿ“Š Relative Evaporation Rate
Not available
๐Ÿ’จ Evaporation Rate
12.4 (ASTM D 3539, nBuAc=1)
๐Ÿ’จ Vapor Pressure
670 Pa at 20 C / 68 F
๐Ÿ“Š Vapor Density
3.6
๐Ÿ“Š Relative Density
Data not available.
๐Ÿ“Š Bulk Density
Not available
โš–๏ธ Density
906 kg/m3 at 20 C / 68 F
Critical Property
๐Ÿ”ฅ Flammability
Yes, in certain circumstances product can ignite due to static electricity.
๐Ÿ“Š Upper Explosive Limit
6.1 %(V)
๐Ÿ“Š Lower Explosive Limit
1.1 %(V)
๐Ÿ“Š Explosive Limits
Not available
๐Ÿ“Š Auto Ignition Temperature
490 C / 914 F
๐Ÿ“Š Decomposition Temperature
Not applicable
๐Ÿ’ง Solubility
Organic solvents Soluble.
๐Ÿ“Š Partition Coefficient
2.95
๐Ÿ“Š Solubility In Water
0.29 kg/m3 at 20 C / 68 F
๐Ÿ“Š Solubility In Fat
Not available
๐Ÿ“Š Molecular Weight
104.15 g/mol
๐Ÿ“Š Voc Content
Not available
๐Ÿ“Š Metal Corrosion
Not available
๐Ÿ“Š Dynamic Viscosity
0.7 mPa.s at 25 C / 77 F
๐Ÿ“Š Kinematic Viscosity
Data not available.
๐Ÿ“Š Properties Status
Not available

Exposure Controls & Personal Protective Equipment (PPE)

Occupational exposure limits, engineering controls, and required safety equipment

๐Ÿญ Engineering Controls

The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Use sealed systems as far as possible. Adequate explosion-proof ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Firewater monitors and deluge systems are recommended. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Eye washes and showers for emergency use.

๐Ÿงค Hand Protection

Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739, AS/NZS:2161) made from the following materials may provide suitable chemical protection: Longer term protection: Viton. Incidental contact/Splash protection: Nitrile rubber. For continuous contact we recommend gloves with breakthrough time of more 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended.

๐Ÿ‘๏ธ Eye Protection

Chemical splash goggles (chemical monogoggles).

๐Ÿ˜ท Respiratory Protection

If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are unsuitable (e.g., airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. If air-filtering respirators are suitable for conditions of use: Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65 C (149 F)].

๐Ÿฆบ Skin/Body Protection

Chemical resistant gloves/gauntlets, boots, and apron. For spillage clean up use chemical resistant knee length boots. Wear antistatic and flame retardant clothing if a local risk assessment deems it so. Protective clothing approved to EU Standard EN14605.

๐ŸŒ Environmental Exposure Controls

Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. Take appropriate measures to fulfill the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water.

Transportation & Shipping Information

UN numbers, shipping names, transport classes, and regulatory transport requirements

๐Ÿท๏ธ UN Number

2055

๐Ÿ“ฆ Proper Shipping Name

STYRENE MONOMER, STABILIZED

โš ๏ธ Transport Hazard Class

3

๐Ÿ“‹ Packing Group

III

๐Ÿš› ADR Transport Precautions

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

๐Ÿšข IMDG Maritime Transport Precautions

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

โœˆ๏ธ IATA Air Transport Precautions

Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport.

Chemical Safety FAQ & Common Questions

Most frequently asked questions about safety, handling, storage, and regulatory compliance

What is the hazard signal word for Styrene Monomer?

The signal word for this substance is "danger".

What is the physical form of Styrene Monomer?

Styrene Monomer is a oily liquid. appearing as colourless to yellowish oily liquid. with colourless to yellowish color. It has aromatic hydrocarbon. odor.

What is the solubility of Styrene Monomer?

Organic solvents Soluble.

What is Styrene Monomer used for?

Base chemical for the production of polystyrene, rubbers and resins.

What are the hazard statements for Styrene Monomer?

This substance has 8 hazard statements: H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H332: Harmful if inhaled. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H372: Causes damage to organs through prolonged or repeated exposure. H401: Toxic to aquatic life.

What is the melting point of Styrene Monomer?

The melting point is -31 C / -24 F and the boiling point is 145 C / 293 F.