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Safety Data Sheet EN

Hempadur 15579 Base

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hempadur 15579 Base
Product Code
1557950630, 00137C27

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Consumer applications, Industrial applications, Professional applications, Used by spraying.

Manufacturers & Suppliers

H

Hempel (The Netherlands) B.V.

national supplier

Karel Doormanweg 7c, 3115 JD Schiedam, Nederland

+31 10 4454000

Emergency Contacts

CENTRE ANTIPOISONS

070/245.245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapor.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing vapor.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves.
P282 Wear eye or face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor.
P312 IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice or attention.
P352 IF ON SKIN: Wash with plenty of water.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Chemical Name CAS Number Concentration Hazardous
Xylene EC: 215-535-7 1330-20-7 10 - 25% Yes
middle molecular epoxy resin MMW 700-1200 25068-38-6 10 - 25% Yes
ethylbenzene EC: 202-849-4 100-41-4 3 - 5% Yes
butan-1-ol EC: 200-751-6 71-36-3 3 - 5% Yes
n-butyl acetate EC: 204-658-1 123-86-4 1 - 3% Yes
1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene EC: 423-300-7 --- 1% Yes

Notes

See Section 16 for the full text of the H statements declared above.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air and keep at rest in a position comfortable for breathing. Give nothing by mouth. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately.

Symptoms: Harmful if inhaled.

Skin contact

Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove contaminated clothing and shoes.

Symptoms: Causes skin irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: pain or irritation, redness, blistering may occur.

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention/advice.

Symptoms: Causes serious eye damage. Adverse symptoms may include the following: pain, watering, redness.

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that vomit will not re-enter the mouth and throat.

Symptoms: No known significant effects or critical hazards. Adverse symptoms may include the following: stomach pains.

Immediate Medical Attention

Seek immediate medical attention/advice (Eyes), get medical attention immediately (Inhalation/Unconscious), seek medical advice immediately (Ingestion).

Medical Treatment

Treat symptomatically.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

alcohol resistant foam, CO₂, powders, water spray

Unsuitable media

waterjet

Specific hazards

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Cool closed containers exposed to fire with water.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid all direct contact with the spilled material. No action shall be taken involving any personal risk or without suitable training.

Environmental

If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

Cleanup methods

Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material.

Materials: sand, earth, vermiculite or diatomaceous earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the product should be used only in areas from which all naked lights and other sources of ignition have been excluded. No sparking tools should be used. Contains epoxy constituents. Avoid all possible skin contact with epoxy and amine containing products, they may cause allergic reactions. Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area where this material is handled, stored and processed.

Storage

Store in accordance with local regulations. Store in a cool, well-ventilated area. Keep out of the reach of children. Prevent unauthorized access.

Hygiene

Eating, drinking and smoking should be prohibited in area where this material is handled, stored and processed.

Fire prevention

Used only in areas from which all naked lights and other sources of ignition have been excluded.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Hands

Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. The quality of the chemical-resistant protective gloves must be chosen as a function of the specific workplace concentrations and quantity of hazardous substances. Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the appropriate type. Below listed glove(s) should be regarded as generic advice: May be used: neoprene rubber (>0.1 mm), butyl rubber (>0.5 mm), nitrile rubber (>0.3 mm) Recommended: Silver Shield / Barrier / 4H gloves, Viton®, polyvinyl alcohol (PVA) Short term exposure: polyvinyl chloride (PVC), butyl rubber (>0.3 mm), nitrile rubber (>0.1 mm), natural rubber (latex) (>0.4 mm)

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

Respiratory

When the product is applied by spraying and for continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or compressed air or a full face, powered air purifying filter. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If working areas have insufficient ventilation: When the product is applied by means that will not generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle filter of type P. (EN140) Be sure to use an approved/certified respirator or equivalent.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved handling this product. Wear suitable protective clothing. Always wear protective clothing when spraying. Chemical-resistant apron.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Density
1.4 g/cm³
Voc Content
33.5 g/l
Partition Coefficient
Testing not relevant or not possible due to nature of the product.
Boiling Point
Testing not relevant or not possible due to nature of the product.
Relative Density
---
Bulk Density
---
Lower Explosive Limit
---
Cloud Point
---
Flash Point
Closed cup: 25°C (77°F)
Odor
Solvent-like
Colour Intensity
---
Freezing Point
Testing not relevant or not possible due to nature of the product.
Solidification Point
---
Evaporation Rate
Testing not relevant or not possible due to nature of the product.
Molecular Weight
---
Ph
Testing not relevant or not possible due to nature of the product.
Auto Ignition Temperature
432°C (809.6°F) (xylene)
Physical State
Liquid.
Vapor Density
Not available.
Upper Explosive Limit
---
Flammability
Highly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and heat. Flammable in the presence of the following materials or conditions: oxidizing materials.
Kinematic Viscosity
Testing not relevant due to nature of the product.
Vapor Pressure
Not applicable. [50°C (122°F)]
Crystallisation Point
---
State Under Standard Conditions
---
Dynamic Viscosity
Dynam ic ( r oom t em per at ur e) : Not available.
Appearance
---
Melting Point
Testing not relevant or not possible due to nature of the product.
Decomposition Temperature
Testing not relevant or not possible due to nature of the product.
Solubility In Fat
---
Solubility In Water
---
Solubility
---
Relative Evaporation Rate
---
Physical State Data
liquid
Odor Threshold
---
Colour
Brown.
Metal Corrosion
---
Properties Status
---
Softening Point
---
Form
---
Explosive Limits
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible

Highly reactive or incompatible with the following materials: oxidizing materials. Reactive or incompatible with the following materials: reducing materials.

Decomposition

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed: Decomposition products may include the following materials: carbon oxides halogenated compounds metal oxide/oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | middle molecular epoxy resin MMW 700-1200 | Acute - LC50 | Fish | >100 mg/l [96 hours] |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | ethylbenzene | Acute - EC50 Chronic - NOEC - Fresh water | Daphnia Algae - Green algae - Pseudokirchneriella subcapitata | >100 mg/l [48 hours] <1000 μg/l [96 hours] |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | butan-1-ol | Acute - LC50 | Fish | 1.376 mg/l [96 hours] |

12.1 Toxicity

| Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | n-butyl acetate | Acute - EC50 Acute - EC50 Acute - EC50 | Daphnia Daphnia Algae | 1328 mg/l [96 hours] 44 mg/l [48 hours] 648 mg/l [72 hours] |

12.1 Toxicity

Product/ingredient name | Result | Species | Exposure | | --- | --- | --- | --- | | 1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene | Acute - LC50 Acute - LC50 | Fish Algae | >100 mg/l [96 hours] >100 mg/l [72 hours] |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | | --- | --- | --- | | xylene | OECD Ready Biodegradability - Manometric Respirometry Test | >60% [28 days] - Readily 90 - 98% [28 days] - Readily |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | | --- | --- | --- | | ethylbenzene | OECD Ready Biodegradability - Closed Bottle Test | >70% [28 days] - Readily 92% [20 days] |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | | --- | --- | --- | | butan-1-ol | OECD Ready Biodegradability - Closed Bottle Test | 90% [28 days] - Readily 80% [5 days] - Readily |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | | --- | --- | --- | | n-butyl acetate | | 5% [28 days] |

12.2 Persistence and degradability

| Product/ingredient name | Test | Result | | --- | --- | --- | | 1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene | | |

12.2 Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | xylene | | | Readily |

12.2 Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | ethylbenzene | | | Readily |

12.2 Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | butan-1-ol | | | Readily |

12.2 Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | n-butyl acetate | | | Readily |

12.2 Persistence and degradability

| Product/ingredient name | Aquatic half-life | Photolysis | Biodegradability | | --- | --- | --- | --- | | 1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene | | | Not readily |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | ylene | 3.12 | 8.1 - 25.9 | Low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | middle molecular epoxy resin MMW 700-1200 | 2.64 - 3.78 | 31 | Low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | ethylbenzene | 3.6 | - | Low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | butan-1-ol | 1 | 3.16 | Low |

12.3 Bioaccumulative potential

| Product/ingredient name | LogP_{ow} | BCF | Potential | | --- | --- | --- | --- | | n-butyl acetate | 2.3 | 3.1 | Low |

12.4 Mobility in soil

Soil/Water partition coefficient | Product/ingredient name | logKoc | Koc | | --- | --- | --- | | ylene | 1.6 - 2.6 | 39 - 365 | | ethylbenzene | 2.2 | 170.406 | | butan-1-ol | 0.51 | 3.22078 | | n-butyl acetate | 1.5 | 33.2139 | Results of PMT and vPvM assessment | Product/ingredient name | PMT | P | M | T | vPvM | vP | vM | | --- | --- | --- | --- | --- | --- | --- | --- | | ylene | No | No | Yes | No | No | No | No | | middle molecular epoxy resin MMW 700-1200 | No | No | N/A | No | No | No | No | | ethylbenzene | No | No | Yes | No | No | No | No | | butan-1-ol | No | No | Yes | No | No | No | No | | n-butyl acetate | No | No | Yes | No | No | No | No | | 1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene | No | No | N/A | No | No | No | No | Mobility : The product does not meet the criteria to be considered as a PMT or vPvM.

The product does not meet the criteria to be considered as a PMT or vPvM.

12.5 Results of PBT and vPvB assessment

Conclusion/Summary : The product does not meet the criteria to be considered as a PBT or vPvB.

The product does not meet the criteria to be considered as a PBT or vPvB.

12.6 Endocrine disrupting properties

The product does not meet the criteria to be considered as having endocrine disrupting properties according to the criteria set out in either Regulation (EC) No. 1907/2006 or Regulation (EC) No 1272/2008.

The product does not meet the criteria to be considered as having endocrine disrupting properties.

12.7 Other adverse effects

No known significant effects or critical hazards.

No known significant effects or critical hazards.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible.

Disposal

Dispose of according to all state and local applicable regulations.

Waste Codes

08 01 11* EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
PAINT
Transport Class
3
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This product is controlled under the Seveso III Directive.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hempadur 15579 Base?

The signal word is danger.

What is the physical form of Hempadur 15579 Base?

Hempadur 15579 Base is a liquid. with brown. color. It has solvent-like odor.

What is Hempadur 15579 Base used for?

Consumer applications, Industrial applications, Professional applications, Used by spraying.

What are the hazard statements for Hempadur 15579 Base?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapor.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H318: Causes serious eye damage.
  • H332: Harmful if inhaled.

What is the melting point of Hempadur 15579 Base?

The melting point is Testing not relevant or not possible due to nature of the product. and the boiling point is Testing not relevant or not possible due to nature of the product..