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Safety Data Sheet EN

Hempadur 15579 Base

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Hempadur 15579 Base
Product Form
epoxy primer (base for multi-component product)
Product Code
1557950630, 00137C27

Regulatory Identifiers

CAS Number
N/A

Identified Uses

buildings and metal industry. ships and shipyards. Consumer applications, Industrial applications, Professional applications, Used by spraying.

Manufacturers & Suppliers

H

Hempel (The Netherlands) B.V.

national supplier

Karel Doormanweg 7c 3115 JD Schiedam Nederland

+31 10 4454000

Emergency Contacts

CENTRE ANTIPOISONS

070/245.245

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H332
Skin Irrit. Cat. 2 H315
Eye Dam. Cat. 1 H318
Skin Sens. Cat. 1 H317

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H226 Flammable liquid and vapor.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing vapor.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves.
P282 Wear eye or face protection.
P304 + P312 IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
P310 Immediately call a POISON CENTER or doctor.
P333 + P313 If skin irritation or rash occurs: Get medical advice or attention.
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P351 IF IN EYES: Rinse cautiously with water for several minutes.
P352 IF ON SKIN: Wash with plenty of water.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
xylene EC: 215-535-7 1330-20-7 10 - 25% Yes
middle molecular epoxy resin 25068-38-6 10 - 25% Yes
ethylbenzene EC: 202-849-4 100-41-4 3 - 5% Yes
butan-1-ol EC: 200-751-6 71-36-3 3 - 5% Yes
n-butyl acetate EC: 204-658-1 123-86-4 1 - 3% Yes
1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene EC: 423-300-7 --- 1% Yes

Notes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air and keep at rest in a position comfortable for breathing. Give nothing by mouth. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If unconscious, place in recovery position and get medical attention immediately.

Skin contact

Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes.

Symptoms: Causes skin irritation. May cause an allergic skin reaction. Adverse symptoms may include: pain or irritation, redness, blistering may occur.

Eye contact

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention/advice.

Symptoms: Causes serious eye damage. Adverse symptoms may include: pain, watering, redness.

Ingestion

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that vomit will not re-enter the mouth and throat.

Symptoms: No known significant effects or critical hazards. Adverse symptoms may include: stomach pains.

Immediate Medical Attention

In all cases of doubt, or when symptoms persist, seek medical attention. Call 112 and give immediate treatment (first aid) if breathing is irregular, drowsiness, loss of consciousness or cramps. Seek immediate medical attention/advice for eye contact. If unconscious due to inhalation, get medical attention immediately. If swallowed, seek medical advice immediately. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Medical Treatment

Treat symptomatically. No specific treatment.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

alcohol resistant foam, CO₂, powders, water spray.

Unsuitable media

waterjet.

Specific hazards

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.

Instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Cool closed containers exposed to fire with water.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training.

Environmental

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Cleanup methods

Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material... and place in container for disposal according to local regulations (see Section 13).

Materials: non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving container with bonding strap. No sparking tools should be used. Contains epoxy constituents. Avoid all possible skin contact with epoxy and amine containing products, they may cause allergic reactions. Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers made from the same material as the original one.

Storage

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

Hygiene

Eating, drinking and smoking should be prohibited in area where this material is handled, stored and processed. Avoid all possible skin contact with epoxy and amine containing products, they may cause allergic reactions. Avoid contact with skin and eyes.

Fire prevention

Prevent the creation of flammable or explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the product should be used only in areas from which all naked lights and other sources of ignition have been excluded.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the workstation location.

Hands

Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. The quality of the chemical-resistant protective gloves must be chosen as a function of the specific workplace concentrations and quantity of hazardous substances. Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the appropriate type. Below listed glove(s) should be regarded as generic advice: May be used: neoprene rubber (>0.1 mm), butyl rubber (>0.5 mm), nitrile rubber (>0.3 mm) Recommended: Silver Shield / Barrier / 4H gloves, Viton®, polyvinyl alcohol (PVA) Short term exposure: polyvinyl chloride (PVC), butyl rubber (>0.3 mm), nitrile rubber (>0.1 mm), natural rubber (latex) (>0.4 mm)

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

Respiratory

When the product is applied by spraying and for continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or compressed air or a full face, powered air purifying filter. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If working areas have insufficient ventilation: When the product is applied by means that will not generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle filter of type P. (EN140) Be sure to use an approved/certified respirator or equivalent.

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved handling this product. Wear suitable protective clothing. Always wear protective clothing when spraying. Chemical-resistant apron.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid.
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
---
Colour
Brown.
Colour Intensity
---
Form
---
Odor
Solvent-like
Odor Threshold
---
Ph
Testing not relevant or not possible due to nature of the product.
Melting Point
Testing not relevant or not possible due to nature of the product.
Boiling Point
Testing not relevant or not possible due to nature of the product.
Flash Point
25°C (77°F)
Freezing Point
Testing not relevant or not possible due to nature of the product.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Testing not relevant or not possible due to nature of the product.
Vapor Pressure
Not applicable. [50°C (122°F)]
Vapor Density
Not available.
Relative Density
---
Bulk Density
---
Density
1.4 g/cm³
Flammability
Highly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and heat. Flammable in the presence of the following materials or conditions: oxidizing materials.
Upper Explosive Limit
---
Lower Explosive Limit
---
Explosive Limits
---
Auto Ignition Temperature
432°C (809.6°F)
Decomposition Temperature
Testing not relevant or not possible due to nature of the product.
Solubility
---
Partition Coefficient
Testing not relevant or not possible due to nature of the product.
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
453.5 g/l
Metal Corrosion
---
Dynamic Viscosity
Dynam ic ( r oom t em per at ur e) : Not available.
Kinematic Viscosity
Testing not relevant due to nature of the product.
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible

Highly reactive or incompatible with the following materials: oxidizing materials. Reactive or incompatible with the following materials: reducing materials.

Decomposition

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed: Decomposition products may include the following materials: carbon oxides halogenated compounds metal oxide/oxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Do not allow to enter drains or watercourses. Product/ingredient name Result Species Exposure middle molecular epoxy resin MMW 700-1200 Acute - LC50 Fish >100 mg/l [96 hours] Acute - EC50 Daphnia >100 mg/l [48 hours] ethylbenzene Chronic - NOEC - Fresh water Algae - Green algae - _Pseudokirchneriella_ <1000 g/l [96 hours] _subcapitata_ Acute - EC50 Daphnia >100 mg/l [48 hours] ethylbenzene Chronic - NOEC - Fresh water Algae - Green algae - _Pseudokirchneriella_ <1000 g/l [96 hours] _subcapitata_ butan-1-ol Acute - LC50 Fish 1.376 mg/l [96 hours] Acute - EC50 Daphnia 1328 mg/l [96 hours] n-butyl acetate Acute - EC50 Daphnia 44 mg/l [48 hours] Acute - EC50 Algae 648 mg/l [72 hours] 1,3-bis(12-hydroxyocta-decanamide- Acute - LC50 Fish >100 mg/l [96 hours] N-methyle)benzene Acute - LC50 Algae >100 mg/l [72 hours] butan-1-ol Acute - LC50 Fish 1.376 mg/l [96 hours] Acute - EC50 Daphnia 1328 mg/l [96 hours] n-butyl acetate Acute - EC50 Daphnia 44 mg/l [48 hours] Acute - EC50 Algae 648 mg/l [72 hours] 1,3-bis(12-hydroxyocta-decanamide- Acute - LC50 Fish >100 mg/l [96 hours] N-methyle)benzene

Persistence and degradability

Product/ingredient name Test Result xylene >60% [28 days] - Readily OECD Ready Biodegradability - Manometric 90 - 98% [28 days] - Readily Respirometry Test ethylbenzene >70% [28 days] - Readily butan-1-ol OECD Ready Biodegradability - Closed Bottle Test 92% [20 days] n-butyl acetate 90% [28 days] - Readily OECD Ready Biodegradability - Closed Bottle Test 80% [5 days] - Readily 1,3-bis(12-hydroxyocta-decanamide- 5% [28 days] N-methyle)benzene Product/ingredient name Aquatic half-life Photolysis Biodegradability xylene Readily ethylbenzene Readily butan-1-ol Readily n-butyl acetate Readily 1,3-bis(12-hydroxyocta-decanamide- Not readily N-methyle)benzene

Bioaccumulative potential

Product/ingredient name LogP ow BCF Potential xylene 3.12 8.1 - 25.9 Low middle molecular epoxy resin MMW 700-1200 2.64 - 3.78 31 Low ethylbenzene 3.6 - Low butan-1-ol 1 3.16 Low n-butyl acetate 2.3 3.1 Low

Mobility in soil

Soil/Water partition coefficient Product/ingredient name logKoc Koc xylene 1.6 - 2.6 39 - 365 ethylbenzene 2.2 170.406 butan-1-ol 0.51 3.22078 n-butyl acetate 1.5 33.2139 Results of PMT and vPvM assessment P M T vPvM vP vM xylene No No Yes No No No No middle molecular epoxy resin MMW 700-1200 No No N/A No No No No ethylbenzene No No Yes No No No No butan-1-ol No No Yes No No No No n-butyl acetate No No Yes No No No No 1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene No No N/A No No No No Mobility : The product does not meet the criteria to be considered as a PMT or vPvM.

The product does not meet the criteria to be considered as a PMT or vPvM.

Results of PBT and vPvB assessment

Conclusion/Summary : The product does not meet the criteria to be considered as a PBT or vPvB.

The product does not meet the criteria to be considered as a PBT or vPvB.

Endocrine disrupting properties

The product does not meet the criteria to be considered as having endocrine disrupting properties according to the criteria set out in either Regulation (EC) No. 1907/2006 or Regulation (EC) No 1272/2008.

The product does not meet the criteria to be considered as having endocrine disrupting properties according to the criteria set out in either Regulation (EC) No. 1907/2006 or Regulation (EC) No 1272/2008.

Other adverse effects

No known significant effects or critical hazards.

No known significant effects or critical hazards.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The generation of waste should be avoided or minimized wherever possible.

Disposal

Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable regulations.

Waste Codes

08 01 11* EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1263
Shipping Name
PAINT
Transport Class
3
Packing Group
III
ADR

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IATA

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Hempadur 15579 Base?

The signal word is danger.

What is the physical form of Hempadur 15579 Base?

Hempadur 15579 Base is a liquid. with brown. color. It has solvent-like odor.

What is Hempadur 15579 Base used for?

buildings and metal industry. ships and shipyards. Consumer applications, Industrial applications, Professional applications, Used by spraying.

What are the hazard statements for Hempadur 15579 Base?

This substance has 5 hazard statements:

  • H226: Flammable liquid and vapor.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H318: Causes serious eye damage.
  • H332: Harmful if inhaled.

What is the melting point of Hempadur 15579 Base?

The melting point is Testing not relevant or not possible due to nature of the product. and the boiling point is Testing not relevant or not possible due to nature of the product..