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Safety Data Sheet EN

Ethyl ether

CAS 60-29-7
EC 200-467-2

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ethyl ether
Product Code
E134-1; E134-20; E134-4
Chemical Name
Ethylether
Synonyms
Ether, Ethyl ether

Regulatory Identifiers

CAS Number
60-29-7 Check regulations →
EC Number
200-467-2 Check regulations →
REACH No.
01-2119535785-29-0000

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use

Manufacturers & Suppliers

F

Fisher Scientific

distributor

One Reagent Lane Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC

800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 1
Acute Tox. Cat. 4
STOT SE Cat. 3
STOT RE Cat. 2
Asp. Tox. Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H224 Extremely flammable liquid and vapor
H302 Harmful if swallowed
H305 May be harmful if swallowed and enters airways
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
May cause damage to organs through prolonged or repeated exposure

Precautionary Statements

Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Do not breathe dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/protective clothing/eye protection/face protection
Keep cool
Get medical attention/advice if you feel unwell
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
In case of fire: Use CO2, dry chemical, or foam for extinction
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Ethylether 60-29-7 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Symptoms: Breathing difficulties. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion

Do not induce vomiting.

Immediate Medical Attention

Get medical attention. Obtain medical attention. Call a physician or Poison Control Center immediately.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO, dry chemical, dry sand, alcohol-resistant foam. Cool closed containers exposed to fire with water spray.

Unsuitable media

Water may be ineffective

Specific hazards

Extremely flammable. Risk of ignition. Vapors may travel to source of ignition and flash back. Vapors may form explosive mixtures with air. Containers may explode when heated. May form explosive peroxides. Vapors may form explosive mixtures with air.

Instructions

Cool closed containers exposed to fire with water spray.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Remove all sources of ignition. Take precautionary measures against static discharges. Avoid contact with skin, eyes and clothing.

Environmental

Should not be released into the environment. See Section 12 for additional ecological information.

Cleanup methods

Soak up with inert absorbent material.

Materials: inert absorbent material

Related Substances

Similar chemicals with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment. Handle under an inert atmosphere. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Do not breathe vapors or spray mist. Keep away from open flames, hot surfaces and sources of ignition. If peroxide formation is suspected, do not open or move container.

Storage

Flammables area. Store under an inert atmosphere. Keep away from open flames, hot surfaces and sources of ignition. May form explosive peroxides. Containers should be dated when opened and tested periodically for the presence of peroxides. Should crystals form in a peroxidizable liquid, peroxidation may have occurred and the product should be considered extremely dangerous. In this instance, the container should only be opened remotely by professionals. Keep away from heat and sources of ignition. Keep container tightly closed in a dry and well-ventilated place.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof electrical/ventilating/lighting/equipment.

Hands

Wear appropriate protective gloves and clothing to prevent skin exposure.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Kinematic Viscosity
---
Solubility In Fat
---
Flammability
Not applicable
Colour
Colorless
Form
---
Colour Intensity
---
Lower Explosive Limit
1.9 vol %
Softening Point
---
Freezing Point
---
Partition Coefficient
No data available
State Under Standard Conditions
---
Odor Threshold
No information available
Vapor Pressure
587 mbar @ 20 °C
Decomposition Temperature
No information available
Solidification Point
---
Physical State
Liquid
Relative Density
0.714
Density
---
Vapor Density
2.55
Bulk Density
---
Auto Ignition Temperature
160 °C / 320 °F
Solubility
Slightly soluble in water
Crystallisation Point
---
Molecular Weight
74.12
Ph
No information available
Explosive Limits
---
Odor
aromatic
Melting Point
-116 °C / -176.8 °F
Cloud Point
---
Evaporation Rate
37.5
Boiling Point
34.6 °C / 94.3 °F
Physical State Data
liquid
Appearance
Colorless
Properties Status
---
Metal Corrosion
---
Dynamic Viscosity
0.2448 cP at 20 °C
Voc Content
---
Upper Explosive Limit
36.0 vol %
Solubility In Water
Slightly soluble in water
Relative Evaporation Rate
---
Flash Point
-45 °C / -49 °F
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

May form explosive peroxides. Air sensitive. Light sensitive. Hygroscopic.

Reactivity

Yes. May form explosive peroxides. Air sensitive. Light sensitive. Hygroscopic.

Hazardous reactions

May form explosive peroxides. Hazardous polymerization does not occur.

Avoid

Incompatible products. Heat, flames and sparks. Exposure to air. Exposure to light. Exposure to moisture. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents, Strong acids

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO2), peroxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Ecotoxicity

Do not empty into drains. | Component | Freshwater Algae | Freshwater Fish | Microtox | Water Flea | | --- | --- | --- | --- | --- | | Ethyl ether | Not listed | LC50: > 10000 mg/L, 96h static (Lepomis macrochirus) LC50: = 2560 mg/L, 96h flow-through (Pimephales promelas) | EC50 = 5600 mg/L 15 min | EC50 = 165 mg/L/24h |

Ethyl ether shows varying levels of toxicity to aquatic organisms, with LC50 values for freshwater fish ranging from 2560 to >10000 mg/L over 96 hours, an EC50 of 5600 mg/L for Microtox over 15 minutes, and an EC50 of 165 mg/L for water fleas over 24 hours. No data is listed for freshwater algae.

Persistence and Degradability

Persistence is unlikely based on information available.

Persistence is unlikely based on information available.

Bioaccumulation/ Accumulation

No information available.

No information available.

Mobility

Will likely be mobile in the environment due to its volatility. | Component | log Pow | | --- | --- | | Ethyl ether | 0.82 |

Ethyl ether is likely to be mobile in the environment due to its volatility, with a log Pow of 0.82.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Waste Codes

U117 Ethyl ether RCRA
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1155
Shipping Name
Diethyl ether
Transport Class
3
Packing Group
I
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Ethyl ether known by?

Ethyl ether is also known as: Ether, Ethyl ether

What is the hazard signal word for Ethyl ether?

The signal word is danger.

What is the physical form of Ethyl ether?

Ethyl ether is a liquid appearing as colorless with colorless color. It has aromatic odor.

What is the solubility of Ethyl ether?

Slightly soluble in water

What is Ethyl ether used for?

Laboratory chemicals.

What are the hazard statements for Ethyl ether?

This substance has 6 hazard statements:

  • H224: Extremely flammable liquid and vapor
  • H302: Harmful if swallowed
  • H305: May be harmful if swallowed and enters airways
  • H335: May cause respiratory irritation
  • H336: May cause drowsiness or dizziness
  • May cause damage to organs through prolonged or repeated exposure

What is the melting point of Ethyl ether?

The melting point is -116 °C / -176.8 °F and the boiling point is 34.6 °C / 94.3 °F.

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