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Safety Data Sheet EN

Ethyl ether

CAS 60-29-7

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Ethyl ether
Product Code
E134-1; E134-20; E134-4
Synonyms
Ethyl ether; Ether

Regulatory Identifiers

CAS Number
60-29-7 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use

Manufacturers & Suppliers

F

Fisher Scientific

distributor

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC®

800-424-9300

CHEMTREC®

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Flam. Liq. Cat. 1
Acute Tox. Cat. 4
STOT SE Cat. 3
STOT RE Cat. 2
Asp. Tox. Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Ethyl ether 60-29-7 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Obtain medical attention.

Symptoms: Breathing difficulties. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Ingestion

Do not induce vomiting. Call a physician or Poison Control Center immediately.

Immediate Medical Attention

Get medical attention (for eyes), Obtain medical attention (for skin/inhalation), Call a physician or Poison Control Center immediately (for ingestion).

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO₂, dry chemical, dry sand, alcohol-resistant foam. Cool closed containers exposed to fire with water spray.

Unsuitable media

Water may be ineffective

Specific hazards

Extremely flammable. Risk of ignition. Vapors may travel to source of ignition and flash back. Vapors may form explosive mixtures with air. Containers may explode when heated. May form explosive peroxides. Vapors may form explosive mixtures with air.

Instructions

Cool closed containers exposed to fire with water spray.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Environmental

Should not be released into the environment. See Section 12 for additional ecological information.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment. Handle under an inert atmosphere. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Do not breathe vapors or spray mist. Keep away from open flames, hot surfaces and sources of ignition. If peroxide formation is suspected, do not open or move container. Use only non-sparking tools. Use explosion-proof equipment. Take precautionary measures against static discharges. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded.

Storage

Flammables area. Store under an inert atmosphere. Keep away from open flames, hot surfaces and sources of ignition. May form explosive peroxides. Containers should be dated when opened and tested periodically for the presence of peroxides. Keep container tightly closed in a dry and well-ventilated place.

Hygiene

Avoid contact with skin, eyes and clothing. Do not breathe vapors or spray mist.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Use explosion-proof equipment. Take precautionary measures against static discharges. All metal parts of the equipment must be grounded.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof electrical/ventilating/lighting/equipment.

Hands

Wear appropriate protective gloves

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate protective clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
State Under Standard Conditions
---
Appearance
Colorless
Colour
Colorless
Colour Intensity
---
Form
---
Odor
aromatic
Odor Threshold
No information available
Ph
No information available
Melting Point
-116 °C / -176.8 °F
Boiling Point
34.6 °C / 94.3 °F
Flash Point
-45 °C / -49 °F
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
37.5
Vapor Pressure
587 mbar @ 20 °C
Vapor Density
2.55
Relative Density
0.714
Bulk Density
---
Density
---
Flammability
Not applicable
Upper Explosive Limit
36.0 vol %
Lower Explosive Limit
1.9 vol %
Explosive Limits
---
Auto Ignition Temperature
160 °C / 320 °F
Decomposition Temperature
No information available
Solubility
Slightly soluble in water
Partition Coefficient
No data available
Solubility In Water
Slightly soluble in water
Solubility In Fat
---
Molecular Weight
74.12
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
0.2448 cP at 20 °C
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

May form explosive peroxides. Air sensitive. Light sensitive. Hygroscopic.

Reactivity

Reactive Hazard Yes

Hazardous reactions

May form explosive peroxides.

Avoid

Incompatible products. Heat, flames and sparks. Exposure to air. Exposure to light. Exposure to moisture. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents, Strong acids

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂), peroxides

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Ecotoxicity

Do not empty into drains. | Component | Freshwater Algae | Freshwater Fish | Microtox | Water Flea | | --- | --- | --- | --- | --- | | Ethyl ether | Not listed | LC50: > 10000 mg/L, 96h static (Lepomis macrochirus) LC50: = 2560 mg/L, 96h flow-through (Pimephales promelas) | EC50 = 5600 mg/L 15 min | EC50 = 165 mg/L/24h |

Ethyl ether shows varying levels of toxicity to aquatic organisms, with LC50 values for freshwater fish ranging from 2560 to >10000 mg/L over 96 hours, an EC50 of 5600 mg/L for Microtox over 15 minutes, and an EC50 of 165 mg/L for water fleas over 24 hours. No data is listed for freshwater algae.

Persistence and Degradability

Persistence is unlikely based on information available.

Persistence is unlikely based on information available.

Bioaccumulation/ Accumulation

No information available.

No information available.

Mobility

Will likely be mobile in the environment due to its volatility. | Component | log Pow | | --- | --- | | Ethyl ether | 0.82 |

Ethyl ether is likely to be mobile in the environment due to its volatility, with a log Pow of 0.82.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Waste Codes

U117 Ethyl ether RCRA
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1155
Shipping Name
Diethyl ether
Transport Class
3
Packing Group
I
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Ethyl ether known by?

Ethyl ether is also known as: Ethyl ether; Ether

What is the hazard signal word for Ethyl ether?

The signal word is no signal word.

What is the physical form of Ethyl ether?

Ethyl ether is a liquid appearing as colorless with colorless color. It has aromatic odor.

What is the solubility of Ethyl ether?

Slightly soluble in water

What is Ethyl ether used for?

Laboratory chemicals.

What is the melting point of Ethyl ether?

The melting point is -116 °C / -176.8 °F and the boiling point is 34.6 °C / 94.3 °F.