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Safety Data Sheet EN

Zephex® 152a

CAS 75-37-6
EC 200-866-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Zephex® 152a
Chemical Name
1,1-Difluoroethane (HFC 152a)

Regulatory Identifiers

CAS Number
75-37-6 Check regulations →
EC Number
200-866-1 Check regulations →
REACH No.
UK-01-6870906490-8-0001; EU 01-2119474440-43-0013

Identified Uses

medical propellant

Uses advised against

Not known.

Manufacturers & Suppliers

M

Mexichem UK Limited

manufacturer

The Heath Business and Technical Park, Runcorn, Cheshire, WA7 4QX

Emergency Contacts

Emergency Contact

999

Emergency Contact

+44(0) 1928 572000

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Aerosol Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

Hazard Statements

H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
1,1-Difluoroethane (HFC 152a) EC: 200-866-1 75-37-6 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove patient from exposure, keep warm and at rest. Administer oxygen if necessary. Apply artificial respiration if breathing has ceased or shows signs of failing. In the event of cardiac arrest apply external cardiac massage.

Symptoms: Very high atmospheric concentrations may cause anaesthetic effects and asphyxiation.

Skin contact

Thaw affected areas with water. Remove contaminated clothing. Caution: clothing may adhere to the skin in the case of freeze burns. After contact with skin, wash immediately with plenty of warm water.

Symptoms: Irritation or blistering.

Eye contact

Immediately irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 10 minutes.

Ingestion

Do not induce vomiting. Provided the patient is conscious, wash out mouth with water and give 200-300 ml (half a pint) of water to drink.

Immediate Medical Attention

Obtain immediate medical attention.

Medical Treatment

Symptomatic treatment and supportive therapy as indicated.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Allow gas fires to burn until exhausted. Keep fire exposed containers cool by spraying with water.

Unsuitable media

None.

Specific hazards

Combustion or thermal decomposition will evolve very toxic and corrosive vapours. (hydrogen fluoride). Containers may burst if overheated.

Firefighter Protection

A self contained breathing apparatus and full protective clothing must be worn in fire conditions. See Also Section 8

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure suitable personal protection (including respiratory protection) during removal of spillages.

Small spill

Allow small spillages to evaporate provided there is adequate ventilation.

Large spill

Ventilate area. Contain spillages with sand, earth or any suitable adsorbent material.

Environmental

Prevent liquid from entering drains, sewers, basements and workpits since the vapour may create an explosive or suffocating atmosphere.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. Avoid inhalation of high concentrations of vapours. Avoid contact between the liquid and skin and eyes.

Storage

Keep in a well ventilated place. Avoid storing near to the intake of air conditioning units, boiler units and open drains. Avoid high temperatures.

Hygiene

Atmospheric levels should be controlled in compliance with the occupational exposure limit. Atmospheric concentrations well below the occupational exposure limit can be achieved by good occupational hygiene practice.

Fire prevention

Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Provide adequate ventilation. Atmospheric levels should be controlled in compliance with the occupational exposure limit.

Hands

Wear thermal insulating gloves when handling liquefied gases.

Eyes

Wear protective eyewear (goggles, face shield, or safety glasses).

Respiratory

In cases of insufficient ventilation, where exposure to high concentrations of vapour is possible, suitable respiratory protective equipment with positive air supply should be used.

Environmental

Prevent liquid from entering drains, sewers, basements and workpits since the vapour may create an explosive or suffocating atmosphere.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquefied gas
Physical State Data
gas
State Under Standard Conditions
---
Appearance
Liquefied gas. Colour: Colourless.
Colour
Colourless
Colour Intensity
---
Form
---
Odor
Slight ethereal
Odor Threshold
No information available.
Ph
Not applicable.
Melting Point
-117°C
Boiling Point
-24.8°C
Flash Point
Not applicable.
Freezing Point
---
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable.
Vapor Pressure
3966 mm Hg @ 20°C
Vapor Density
2.4
Relative Density
0.95 @ 4°C
Bulk Density
---
Density
---
Flammability
Extremely flammable gas.
Upper Explosive Limit
18.0
Lower Explosive Limit
3.7
Explosive Limits
---
Auto Ignition Temperature
440°C
Decomposition Temperature
No information available.
Solubility
Solubility (Water): marginally soluble Solubility (Other): Soluble in: Most organic solvents
Partition Coefficient
Log Pow = 1.13 @ 25°C
Solubility In Water
---
Solubility In Fat
---
Molecular Weight
---
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

See Section: Possibility of hazardous reactions

Hazardous reactions

Can react violently if in contact with alkali metals and alkaline earth metals - sodium, potassium, barium. May react violently with oxidising agents.

Avoid

Keep away from heat and sources of ignition.

Incompatible

finely divided metals, magnesium and alloys containing more than 2% magnesium.

Decomposition

hydrogen fluoride by thermal decomposition and hydrolysis.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

12.1 Toxicity

The product is predicted to have low toxicity to aquatic organisms. Toxicity - Aquatic invertebrates Low toxicity to aquatic invertebrates. Toxicity - Fish Low toxicity to fish. Toxicity - Algae Low toxicity to algae. Toxicity - Sediment Compartment Not classified. Toxicity - Terrestrial Compartment Not classified. Environmental Fate and Distribution High tonnage material produced in wholly contained systems. High tonnage material used in open systems. Gas.

The product is predicted to have low toxicity to aquatic organisms.

12.2 Persistence and Degradation

Decomposed comparatively rapidly in the lower atmosphere (troposphere). Atmospheric lifetime is 1.4 years. Products of decomposition will be highly dispersed and hence will have a very low concentration. Does not influence photochemical smog (i.e. is not a VOC under the terms of the UNECE agreement). Does not deplete ozone. Has a Global Warming Potential (GWP) of 124 (relative to a value of 1 for carbon dioxide at 100 years) according to Annex I of Regulation (EU) No. 517/2014 on certain fluorinated greenhouse gases. Values in Annex I are taken from the fourth assessment report (AR4) of the Intergovernmental Panel on Climate Change. United Nations Framework Convention on Climate Change (UNFCCC) reporting GWP is 140.

The substance decomposes in the troposphere with an atmospheric lifetime of 1.4 years. It does not contribute to photochemical smog or ozone depletion. It has a Global Warming Potential (GWP) of 124 (EU) or 140 (UNFCCC).

12.3 Bioaccumulative potential

The product has no potential for bioaccumulation.

The product has no potential for bioaccumulation.

12.4 Mobility in soil

Not applicable.

12.5 Results of PBT and vPvB assessment

Not classified as PBT or vPvB.

The substance is not classified as PBT or vPvB.

12.6 Other adverse effects

None known. Effect on Effluent Treatment Discharges of the product will enter the atmosphere and will not result in long term aqueous contamination.

No known adverse effects; product enters the atmosphere and does not cause long-term aqueous contamination.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Best to recover and recycle. If this is not possible, destruction is to be in an approved facility which is equipped to absorb and neutralise acid gases and other toxic processing products.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1950
Shipping Name
AEROSOLS, FLAMMABLE
Transport Class
2.1
Packing Group
Not applicable.
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Zephex® 152a?

The signal word is danger.

What is the physical form of Zephex® 152a?

Zephex® 152a is a liquefied gas appearing as liquefied gas. colour: colourless. with colourless color. It has slight ethereal odor.

What is the solubility of Zephex® 152a?

Solubility (Water): marginally soluble Solubility (Other): Soluble in: Most organic solvents

What is Zephex® 152a used for?

medical propellant

What are the hazard statements for Zephex® 152a?

This substance has 2 hazard statements:

  • H222: Extremely flammable aerosol.
  • H229: Pressurised container: May burst if heated.

What is the melting point of Zephex® 152a?

The melting point is -117°C and the boiling point is -24.8°C.