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Safety Data Sheet EN

4,4'-Methylenebis(2-methylcyclohexylamine)

CAS 6864-37-5
EC 229-962-1

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
4,4'-Methylenebis(2-methylcyclohexylamine)
Product Code
369500
Chemical Name
2,2'-dimethyl-4,4'- methylenebis(cyclohexyl amine)

Regulatory Identifiers

CAS Number
6864-37-5 Check regulations →
EC Number
229-962-1 Check regulations →

Identified Uses

Laboratory chemicals, Manufacture of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

manufacturer

3050 Spruce Street, SAINT LOUIS MO 63103, USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 3 H331
Acute Tox. Cat. 3 H311
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318
Aquatic Acute Cat. 2 H401
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS05 - Corrosive

GHS05

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed.
H311 + H331 Toxic in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.
P322 Specific measures (see supplemental first aid instructions on this label).
P361 Remove/Take off immediately all contaminated clothing.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
2,2'-dimethyl-4,4'- methylenebis(cyclohexyl amine) EC: 229-962-1 6864-37-5 100% Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Continue rinsing eyes during transport to hospital.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: Nitrile rubber Minimum layer thickness: 0.4 mm Break through time: 480 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 30 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Boiling Point
93 - 100 °℃ (199 - 212 ºF)
Softening Point
---
Auto Ignition Temperature
No data available
Solubility
No data available
Colour Intensity
---
Odor
No data available
Lower Explosive Limit
No data available
Flash Point
113 °℃ (235 ºF)
Appearance
colourless
Dynamic Viscosity
---
Solidification Point
---
State Under Standard Conditions
---
Explosive Limits
---
Vapor Density
No data available
Physical State Data
liquid
Odor Threshold
No data available
Vapor Pressure
No data available
Voc Content
---
Relative Density
0.94 g/cm3 at 25 °℃ (77 ºF)
Molecular Weight
---
Form
viscous liquid
Evaporation Rate
No data available
Solubility In Water
No data available
Metal Corrosion
---
Decomposition Temperature
No data available
Freezing Point
No data available
Crystallisation Point
---
Melting Point
No data available
Relative Evaporation Rate
---
Flammability
No data available
Bulk Density
---
Cloud Point
---
Upper Explosive Limit
No data available
Solubility In Fat
---
Physical State
viscous liquid
Colour
---
Partition Coefficient
No data available
Properties Status
---
Kinematic Viscosity
---
Ph
No data available
Density
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2927
Shipping Name
Toxic liquids, corrosive, organic, n.o.s. (2,2'-Dimethyl-4,4'methylenebis(cyclohexylamine))
Transport Class
6.1 (8)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for 4,4'-Methylenebis(2-methylcyclohexylamine)?

The signal word is danger.

What is the physical form of 4,4'-Methylenebis(2-methylcyclohexylamine)?

4,4'-Methylenebis(2-methylcyclohexylamine) is a viscous liquid appearing as colourless . It has no data available odor.

What is the solubility of 4,4'-Methylenebis(2-methylcyclohexylamine)?

No data available

What is 4,4'-Methylenebis(2-methylcyclohexylamine) used for?

Laboratory chemicals, Manufacture of substances

What are the hazard statements for 4,4'-Methylenebis(2-methylcyclohexylamine)?

This substance has 4 hazard statements:

  • H302: Harmful if swallowed.
  • H311 + H331: Toxic in contact with skin or if inhaled.
  • H314: Causes severe skin burns and eye damage.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of 4,4'-Methylenebis(2-methylcyclohexylamine)?

The melting point is No data available and the boiling point is 93 - 100 °℃ (199 - 212 ºF).

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