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Safety Data Sheet EN

R500

CAS 56275-41-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
R500
Synonyms
dichlorodifluoromethane and difluoroethane azeotropic mixture with about; 74% dichlorodifluoromethane; dichlorodifluoromethane difluoroethane mixture; Freon 500 Propellant 500 Refrigerant 500 chlorofluorocarbon; Fluorocarbon aerosol propellant CFC-12/FC-152a mixture; FC-152a CFC-12 mixture Freon FC-12 FC-152a mixture; F500; R500; Formerly CIG Refrigerant gas R500 Code 1; Forane 500, R-500

Regulatory Identifiers

CAS Number
56275-41-3 Check regulations →

Identified Uses

As a refrigerant, urethane foam blowing agent, aerosol propellant, solvent and degreasing agent. Chlorofluorocarbons (CFCs) are used in a variety of applications because of their low toxicity, reactivity and flammability. Every permutation of fluorine, and chlorine based on methane and ethane has been examined and most have been commercialized. Furthermore, many examples are known for higher numbers of carbon as well as related compounds containing bromine. Uses include refrigerants, blowing agents, propellants in medicinal applications and degreasing solvents.

Manufacturers & Suppliers

A-Gas (U.S. Headquarters) logo

A-Gas (U.S. Headquarters)

manufacturer

1100 Haskins Rd. Bowling Green, OH 43402 United States

14198678990

http://www.agas.com/us

Emergency Contacts

PERS

1-800-633-8253

PERS

International 1-801-629-0667

CHEMWATCH EMERGENCY RESPONSE (24/7)

+1 855-237-5573 (ID#: 12626)

CHEMWATCH EMERGENCY RESPONSE (24/7)

+61 3 9573 3188

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Press. Gas (Comp.)
Acute Tox. Cat. 4

GHS Pictograms

GHS04 - Compressed gas

GHS04

GHS07 - Health hazard

GHS07

Hazard Statements

H280 Contains gas under pressure; may explode if heated.
H302 Harmful if swallowed.

Precautionary Statements

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P264 Wash all exposed external body areas thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.
P330 Rinse mouth.
P410 + P403 Protect from sunlight. Store in a well-ventilated place.
P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

dichlorodifluoromethane/ difluoroethane azeotropic mixture

Chemical Name CAS Number Concentration Hazardous
dichlorodifluoromethane/ difluoroethane azeotropic mixture 56275-41-3 --- No
1,1-difluoroethane 75-37-6 26% No
dichlorodifluoromethane 75-71-8 74% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Following exposure to gas, remove the patient from the gas source or contaminated area. Prostheses such as false teeth, which may block the airway, should be removed, where possible, prior to initiating first aid procedures. If the patient is not breathing spontaneously, administer rescue breathing. If the patient does not have a pulse, administer CPR. If medical oxygen and appropriately trained personnel are available, administer 100% oxygen. Summon an emergency ambulance. If an ambulance is not available, contact a physician, hospital, or Poison Control Centre for further instruction. Keep the patient warm, comfortable and at rest while awaiting medical care. MONITOR THE BREATHING AND PULSE, CONTINUOUSLY. Administer rescue breathing (preferably with a demand-valve resuscitator, bag-valve mask-device, or pocket mask as trained) or CPR if necessary.

Skin contact

Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Symptoms: irritation

Eye contact

If product comes in contact with eyes remove the patient from gas source or contaminated area. Take the patient to the nearest eye wash, shower or other source of clean water. Open the eyelid(s) wide to allow the material to evaporate. Gently rinse the affected eye(s) with clean, cool water for at least 15 minutes. Have the patient lie or sit down and tilt the head back. Hold the eyelid(s) open and pour water slowly over the eyeball(s) at the inner corners, letting the water run out of the outer corners. Ensure that the patient looks up, and side to side as the eye is rinsed in order to better reach all parts of the eye(s). Transport to hospital or doctor. Even when no pain persists and vision is good, a doctor should examine the eye as delayed damage may occur. If the patient cannot tolerate light, protect the eyes with a clean, loosely tied bandage. Ensure verbal communication and physical contact with the patient.

Symptoms: The patient may be in great pain. Delayed damage may occur.

Ingestion

Not considered a normal route of entry. For advice, contact a Poisons Information Centre or a doctor. Avoid giving milk or oils. Avoid giving alcohol.

Immediate Medical Attention

Transport to hospital or doctor. Seek medical attention in event of irritation. Summon an emergency ambulance. If an ambulance is not available, contact a physician, hospital, or Poison Control Centre for further instruction.

Medical Treatment

Use of adrenaline and other catecholamines may be contraindicated due to possible cardiac sensitisation. Tachyarrhythmias caused by increased myocardial sensitisation may be treated with propranolol, 1-2 mg IV or esmolol 25-100 microgm/kg/min IV. Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred. Treat seizures with diazepam. If lavage is performed, suggest endotracheal and/or esophageal control. Analgesia may be necessary while thawing frost-bite.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use extinguishing agent suitable for type of surrounding fire.

Unsuitable media

Do not direct water at source of leak or venting safety devices as icing may occur.

Specific hazards

Fire Incompatibility: Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Instructions

Cool cylinder.

Firefighter Protection

Wear breathing apparatus and protective gloves.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

See section 8

Small spill

Avoid breathing vapour and any contact with liquid or gas. Protective equipment including respirator should be used. DO NOT enter confined spaces where gas may have accumulated. Increase ventilation.

Large spill

Clear area of all unprotected personnel and move upwind. Alert Emergency Authority and advise them of the location and nature of hazard. Wear breathing apparatus and protective gloves. Prevent by any means available, spillage from entering drains and water-courses. Remove leaking cylinders to a safe place. Fit vent pipes. Release pressure under safe, controlled conditions. Burn issuing gas at vent pipes. DO NOT exert excessive pressure on valve; DO NOT attempt to operate damaged valve.

Environmental

See section 12

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Consider use in closed pressurised systems, fitted with temperature, pressure and safety relief valves which are vented for safe dispersal. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. The tubing network design connecting gas cylinders to the delivery system should include appropriate pressure indicators and vacuum or suction lines. Fully-welded types of pressure gauges, where the bourdon tube sensing element is welded to the gauge body, are recommended. Before connecting gas cylinders, ensure manifold is mechanically secure and does not containing another gas. DO NOT transfer gas from one cylinder to another.

Storage

Store below 38 deg. C. Cylinders should be stored in a purpose-built compound with good ventilation, preferably in the open. Such compounds should be sited and built in accordance with statutory requirements. The storage compound should be kept clear and access restricted to authorised personnel only. Cylinders stored in the open should be protected against rust and extremes of weather.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment.

Hands

Butyl rubber gloves. Butyl rubber gloves should be used when handling halogenated aliphatics. Nitrile, PVC-coated nitrile, and PVC protective equipment are not recommended. When handling sealed and suitably insulated cylinders wear cloth or leather gloves.

Eyes

Safety glasses with side shields.Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.

Respiratory

Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent). Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content. The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. Cartridge performance is affected by humidity. Positive pressure, full face, air-supplied breathing apparatus should be used for work in enclosed spaces if a leak is suspected or the primary containment is to be opened (e.g. for a cylinder change). Air-supplied breathing apparatus is required where release of gas from primary containment is either suspected or demonstrated.

Skin/Body

Protective overalls, closely fitted at neck and wrist.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Dynamic Viscosity
Not Available
Relative Density
1.16
Evaporation Rate
Very Rapid
Ph
Not Applicable
Voc Content
100
Softening Point
---
Physical State Data
gas
Boiling Point
-33 °C
Solubility In Fat
---
Explosive Limits
---
Solidification Point
---
Physical State
Compressed Gas
Auto Ignition Temperature
Not Applicable
State Under Standard Conditions
---
Density
---
Vapor Pressure
770 kPa
Flash Point
Not Applicable
Relative Evaporation Rate
380 (butyl acetate=1)
Vapor Density
3.7
Melting Point
Not Available
Appearance
Colourless liquefied / compressed non flammable gas. Slight ethereal odour. An azeotropic mixture of liquefiable gases, critical temperature 105.5 deg. C., critical pressure 4430 KPa Cylinder white or galvanised body, golden tan shoulder and valve guard. Does not mix with water, (Solubility of R12 0.028 cm3/cm3 and R152a 0.054 cm3/cm3 @ STP). Dissolves many urethane components. Evaporation rate 380 (butyl acetate=1) i.e. very rapid vaporisation.Chlorofluorocarbons (CFCs) are fully halogenated paraffin hydrocarbons that contain only carbon (C), chlorine (Cl), and fluorine (F), produced as volatile derivative of methane, ethane, and propane. They are also commonly known by brand name Freon.Because CFCs contribute to ozone depletion in the upper atmosphere, the manufacture of such compounds has been phased out under the Montreal Protocol, and they are being replaced with other products such as hydrofluorocarbons (HFCs).The physical properties of CFCs and HCFCs are tunable by changes in the number and identity of the halogen atoms. In general, they are volatile but less so than their parent alkanes. The decreased volatility is attributed to the molecular polarity induced by the halides, which induces intermolecular interactions.The CFCs have still higher boiling points because the chloride is even more polarizable than fluoride.
Colour
---
Freezing Point
Not Available
Properties Status
---
Solubility
Immiscible
Colour Intensity
---
Form
---
Metal Corrosion
---
Flammability
Not Applicable
Molecular Weight
97.8 g/mol
Decomposition Temperature
Not Available
Odor Threshold
Not Available
Bulk Density
---
Lower Explosive Limit
Not Applicable
Cloud Point
---
Crystallisation Point
---
Odor
Not Available
Upper Explosive Limit
Not Applicable
Kinematic Viscosity
---
Partition Coefficient
Not Available
Solubility In Water
Immiscible
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Unstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.Extremely high temperatures.

Reactivity

See section 7

Hazardous reactions

See section 7

Avoid

See section 7

Incompatible

See section 7

Decomposition

See section 5

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Toxicity | R500 | Endpoint | Test Duration (hr) | Species | Value | Source | | --- | --- | --- | --- | --- | --- | Continued... On the basis of the available evidence concerning properties and predicted or observed environmental fate and behavior, the material may present a danger to the structure and/or functioning of the stratospheric ozone layer. Following release of CFCs into the atmosphere, they eventually enter the troposphere where they persist undegraded. Subsequently they diffuse into the stratosphere and degrade slowly (half-lives of about 20 years). In the stratosphere, CFCs react slowly with oxygen free radicals and release chlorine atoms which catalytically destroy ozone producing irreversible damage. Use of CFCs has been restricted by the Montreal Protocol on Substances that Deplete the Ozone Layer (1988) and also by US EPA Regulation 3093/94. For dichlorodifluoromethane: #### Environmental fate: Based on a vapour pressure of 4,850 mm Hg at 25 deg C, dichlorodifluoromethane is expected to exist solely in the gas-phase in the ambient atmosphere. Gas-phase dichlorodifluoromethane is extremely stable in the troposphere. This compound does not react with photochemically produced hydroxyl radicals, ozone molecules or nitrate radicals in the troposphere. This compound will gradually diffuse into the stratosphere above the ozone layer where it will slowly degrade due to direct photolysis from UV-C radiation and contribute to the catalytic removal of stratospheric ozone. for 1,1-difluorethane: #### Environmental fate: According to model of gas/ particle partitioning of semi-volatile organic compounds in the atmosphere, 1,1-difluoroethane is expected to exist solely as a vapour in the ambient atmosphere. The atmospheric half-life of about 472 days at an atmospheric concentration. This long atmosphere lifetime of this chemical suggests some 1,1-difluoroethane is expected to diffuse into the stratosphere above the ozone layer where it will slowly degrade due to direct photolysis from UV-radiation. The estimated half-life for a model river and model lake are 2 and 77 hours respectively. For haloalkanes and haloalkenes: #### Environmental fate: Certain haloalkane gases in the atmosphere can also contribute to the greenhouse effect by restricting heat loss from the Earth's atmosphere through absorbing infrared emissions from the surface. Generally haloalkanes contributing to the greenhouse effect consist of a fully or partly fluorinated carbon backbone. Gas-phase reactions with OH radicals are the major tropospheric loss process for the haloalkanes. In addition photooxidation reactions with O3 and NO3 radicals can result in transformation.

Persistence and degradability

| Ingredient | Persistence: Water/Soil | Persistence: Air | | --- | --- | --- |

12.2 Persistence and degradability

Ingredient: 1,1-difluoroethane, Persistence: Water/Soil: LOW, Persistence: Air: LOW

Persistence and degradability

dichlorodifluoromethane | HIGH (Half-life = 360 days) | HIGH (Half-life = 882.5 days)

12.1 Toxicity

Not available

12.2 Persistence and degradability

Not available

12.3 Bioaccumulative potential

1,1-difluoroethane | LOW (LogKDW = 0.75)

12.4 Mobility in soil

Not available

12.5 Results of PBT and vPvB assessment

Not available

12.6 Endocrine disrupting properties

Not available

12.7 Other adverse effects

Not available

12.3 Bioaccumulative potential

dichlorodifluoromethane | LOW (BCF = 10)

Mobility in soil

Mobility in soil | Ingredient | Mobility | | --- | --- | | 1,1-difluoroethane | LOW (Log KDC = 35.04) | | dichlorodifluoromethane | LOW (Log KDC = 48.64) |

Other adverse effects

One or more ingredients within this SDS has the potential of causing ozone depletion and/or photochemical ozone creation.

The product contains ingredients with the potential to cause ozone depletion and/or photochemical ozone creation.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Evaporate residue at an approved site.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2602
Shipping Name
Refrigerant gas R 500 (contains dichlorodifluoromethane/ difluoroethane azeotropic mixture); Dichlorodifluoromethane and difluoroethane azeotropic mixture with approximately 74 percent dichlorodifluoromethane (contains dichlorodifluoromethane/ difluoroethane azeotropic mixture)
Transport Class
2.2
Packing Group
Not Applicable
ADR

Hazard Label 2.2; Special provisions T50

IMDG

EMS Number: F-C, S-V

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is R500 known by?

R500 is also known as: dichlorodifluoromethane and difluoroethane azeotropic mixture with about; 74% dichlorodifluoromethane; dichlorodifluoromethane difluoroethane mixture; Freon 500 Propellant 500 Refrigerant 500 chlorofluorocarbon; Fluorocarbon aerosol propellant CFC-12/FC-152a mixture; FC-152a CFC-12 mixture Freon FC-12 FC-152a mixture; F500; R500; Formerly CIG Refrigerant gas R500 Code 1; Forane 500, R-500

What is the hazard signal word for R500?

The signal word is warning.

What is the physical form of R500?

R500 is a compressed gas appearing as colourless liquefied / compressed non flammable gas. slight ethereal odour. an azeotropic mixture of liquefiable gases, critical temperature 105.5 deg. c., critical pressure 4430 kpa cylinder white or galvanised body, golden tan shoulder and valve guard. does not mix with water, (solubility of r12 0.028 cm3/cm3 and r152a 0.054 cm3/cm3 @ stp). dissolves many urethane components. evaporation rate 380 (butyl acetate=1) i.e. very rapid vaporisation.chlorofluorocarbons (cfcs) are fully halogenated paraffin hydrocarbons that contain only carbon (c), chlorine (cl), and fluorine (f), produced as volatile derivative of methane, ethane, and propane. they are also commonly known by brand name freon.because cfcs contribute to ozone depletion in the upper atmosphere, the manufacture of such compounds has been phased out under the montreal protocol, and they are being replaced with other products such as hydrofluorocarbons (hfcs).the physical properties of cfcs and hcfcs are tunable by changes in the number and identity of the halogen atoms. in general, they are volatile but less so than their parent alkanes. the decreased volatility is attributed to the molecular polarity induced by the halides, which induces intermolecular interactions.the cfcs have still higher boiling points because the chloride is even more polarizable than fluoride. . It has not available odor.

What is the solubility of R500?

Immiscible

What is R500 used for?

As a refrigerant, urethane foam blowing agent, aerosol propellant, solvent and degreasing agent. Chlorofluorocarbons (CFCs) are used in a variety of applications because of their low toxicity, reactivity and flammability. Every permutation of fluorine, and chlorine based on methane and ethane has been examined and most have been commercialized. Furthermore, many examples are known for higher numbers of carbon as well as related compounds containing bromine. Uses include refrigerants, blowing agents, propellants in medicinal applications and degreasing solvents.

What are the hazard statements for R500?

This substance has 2 hazard statements:

  • H280: Contains gas under pressure; may explode if heated.
  • H302: Harmful if swallowed.

What is the melting point of R500?

The melting point is Not Available and the boiling point is -33 °C.