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Safety Data Sheet EN

SLI-Batteries (Lead-acid battery filled with dilute sulphuric acid)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
SLI-Batteries (Lead-acid battery filled with dilute sulphuric acid)
Product Code
E07900
Chemical Name
SLI-Batteries (Lead-acid battery filled with dilute sulphuric acid)

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Power Supply

Manufacturers & Suppliers

Johnson Controls Autobatteri AB logo

Johnson Controls Autobatteri AB

manufacturer

Ensjøveien 23 B 0660 Oslo Norge

+47 23 03 61 41

http://www.johnsoncontrols.com

Emergency Contacts

Norwegian Poison Information Centre

+47 22 59 13 00

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified na: r-phrases

Hazard Classifications

Acute Tox.
Skin Corr.
Aquatic Chronic

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Lead and inorganic lead compounds EC: 231-100-4 7439-92-1 60 - 100% Yes
Sulphuric acid EC: 231-639-5 7664-93-9 10 - 30% Yes

Lead and inorganic lead compounds are classified as "May cause birth defects (Rep.1)". As this classification does not have its own symbol, lead and leadcompounds have to be labelled with the "skull" symbol. Lead compounds are not classified "toxic". The classification of Lead and inorganic lead compounds have been triggered by the tests from the "1980" for soluble lead acetate. Later tests from 2001, 2005 and 2006 of lead oxide concludes that the lead oxide from the batteries are not toxic to the environment.. As a result of this the Risk Phrase R52-53 (Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment) applies to battery lead oxide and activ mass.

Notes

Lead and inorganic lead compounds are classified as "May cause birth defects (Rep.1)". As this classification does not have its own symbol, lead and leadcompounds have to be labelled with the "skull" symbol. Lead compounds are not classified "toxic". The classification of Lead and inorganic lead compounds have been triggered by the tests from the "1980" for soluble lead acetate. Later tests from 2001, 2005 and 2006 of lead oxide concludes that the lead oxide from the batteries are not toxic to the environment.. As a result of this the Risk Phrase R52-53 (Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment) applies to battery lead oxide and activ mass.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Rinse nose and mouth with water.

Skin contact

Remove contaminated clothes, wash with soap and plenty of water.

Symptoms: Corrosive effect on skin

Eye contact

Rinse immediately with plenty of water for min. 15 minutes (keep the eyelids wide open, remove contact lenses.). If Diphoterine is available, use this instead of water.

Ingestion

Rinse the mouth with water. Drink water, if possible charcoal suspension.

Immediate Medical Attention

Burns should be treated by a physician. Contact immediately a doctor/ophthalmologist. Contact a doctor immediately.

Medical Treatment

Immediate medical treatment is required when not treated burns will lead to difficult wound healing.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

CO2, powder or water spray.

Firefighter Protection

Full Fire-fighting equipment and breathing apparatus with pressure air or fresh air mask. Protective equipment must be acid resistant.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Keep persons and animals away from contaminated area.

Environmental

Must not get into water drains, sewage, soil or groundwater.

Cleanup methods

Absorb with sand, soil or similar, collect and deliver as special waste.

Materials: sand, soil

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle according to good hygiene and safety instructions. Do not attempt to dismantle this product. Avoid all unnecessary exposure.

Storage

Store under cover in a cool area. Store in dry, well ventilated area.

Hygiene

Handle according to good hygiene and safety instructions.

Fire prevention

Keep from heat, sparks, and open flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Ensure sufficient exhaust or ventilation at the working place.

Hands

Use only protective gloves with CE-marking, category III and according to EN374. Recommended Glove Type: Nitrilerubber. Seek advice by the glove manufacturer to choose the right gloves with consideration to chemicals and penetration time. Recommended penetrating time: > 8 hours. Protection gloves have to be changed regularly, especially with long-lasting contact with the product.

Eyes

Not relevant with normal use. Wear goggles when there is a danger of splashing. Tight-fitting protective goggles or face protection shield. (EN166, EN169).

Respiratory

Normally not necessary. Mask type: B2 filter, sour/inorganic vapour.

Skin/Body

Acid-resistant protective clothing and safety shoes.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Relative Evaporation Rate
---
Physical State Data
solid
Properties Status
---
Cloud Point
---
Kinematic Viscosity
---
Solubility In Water
Lead: 0.15 mg/l (25°C); Sulphuric acid: complete
Flash Point
---
Solidification Point
---
Solubility In Fat
---
Evaporation Rate
---
Voc Content
---
Solubility
Lead and lead-acid battery paste is very slightly soluble in water. Lead can dissolve in acidic or alkaline environment.
Explosive Limits
---
Vapor Density
---
Auto Ignition Temperature
---
Metal Corrosion
---
Decomposition Temperature
---
Partition Coefficient
---
Boiling Point
1740 °C; Sulphuric acid: ca. 108 - 144°C
Freezing Point
---
Molecular Weight
---
Colour Intensity
---
Vapor Pressure
Sulphuric acid: 14.6 mbar(20°C)
Odor
Lead: None, Sulphuric acid: odourless
Flammability
---
Melting Point
Lead: 327°C; Sulphuric acid: -35 til -60 °C
Physical State
Lead: Solid, Sulphuric acid: Liquid
Form
paste
Density
Lead: 11,35 g/cm3; Sulphuric acid: 1.2-1.3 g/cm3
Dynamic Viscosity
---
Relative Density
---
Softening Point
---
Crystallisation Point
---
Ph
Sulphuric acid: 0,3 (25°C) (49 mg/l water); Lead: 7-8 (100 mg/l water)
Appearance
Lead: Grey, Sulphuric acid: colourless
Lower Explosive Limit
---
Upper Explosive Limit
---
State Under Standard Conditions
---
Bulk Density
---
Colour
Lead: Grey, Sulphuric acid: colourless
Odor Threshold
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage and handling conditions.

Reactivity

Corrosive. Destroys organic material such as. cardboard, wood and textiles.

Hazardous reactions

Reacts with metals during the development of hydrogen gas. Violent reaction with alkalis. By charging process occurs hydrogen gas which with oxygen can lead to an explosive mixture

Avoid

Avoid high temperatures.

Incompatible

metals, alkalis

Decomposition

hydrogen gas

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

The manufacturers and importers of batteries, respectively the metal dealers take back dead batteries, and render them to the secondary lead smelters for processing

Disposal

Discarded lead-acid batteries should not be mixed with other batteries in order not to complicate the treatment.

Waste Codes

16 06 01 Lead-acid batteries EWC
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
2794
Shipping Name
BATTERIES, WET, FILLED WITH ACID, electric storage
Transport Class
8
ADR

Corrosive

IMDG

Corrosive

IATA

Corrosive

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Administrative standards for pollution of the working atmosphere. ADR/RID 2011. Directive 1999/45/EEC. Regulations on the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), Regulation (EC) No 1907/2006. European Parliament and Council Regulation (EC) No 1272/2008. FOR 2004-06-01 nr. 930: Regulations on the recovery and disposal of waste. (Waste regulations).

Chemical Safety Assessment Not performed

In accordance with the EU Battery Directive and national laws lead-acid batteries have to be marked by a crose out refuse bin with the chemical symbol for lead PB shown below. together wit the ISO return/recycling symbol. The manufacturer, respectively the importer of batteries shall be responsible for placing the symbols (aminimum size is specified) in addition, consumer/user information on the significance of the symbols may be attached

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for SLI-Batteries (Lead-acid battery filled with dilute sulphuric acid)?

The signal word is na: r-phrases.

What is the physical form of SLI-Batteries (Lead-acid battery filled with dilute sulphuric acid)?

SLI-Batteries (Lead-acid battery filled with dilute sulphuric acid) is a lead: solid, sulphuric acid: liquid appearing as lead: grey, sulphuric acid: colourless with lead: grey, sulphuric acid: colourless color. It has lead: none, sulphuric acid: odourless odor.

What is the solubility of SLI-Batteries (Lead-acid battery filled with dilute sulphuric acid)?

Lead and lead-acid battery paste is very slightly soluble in water. Lead can dissolve in acidic or alkaline environment.

What is SLI-Batteries (Lead-acid battery filled with dilute sulphuric acid) used for?

Power Supply

What is the melting point of SLI-Batteries (Lead-acid battery filled with dilute sulphuric acid)?

The melting point is Lead: 327°C; Sulphuric acid: -35 til -60 °C and the boiling point is 1740 °C; Sulphuric acid: ca. 108 - 144°C.