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Safety Data Sheet EN

No. 5 Fuel Oil

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
No. 5 Fuel Oil

Regulatory Identifiers

CAS Number
N/A

Manufacturers & Suppliers

Hess Corporation logo

Hess Corporation

manufacturer

1 Hess Plaza, Woodbridge, NJ 07095-0961

732-750-6000

http://www.hess.com

Emergency Contacts

CHEMTREC

800-424-9300

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 4
Acute Tox. Cat. 2
Skin Irrit. Cat. 2
Eye Irrit. Cat. 2B
Skin Sens. Cat. 1
Carc. Cat. 1B
STOT SE Cat. 3
Aquatic Acute Cat. 3

GHS Pictograms

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H227 Combustible liquid.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H320 Causes eye irritation.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness and dizziness.
H350 May cause cancer.
H402 Harmful to aquatic life.

Precautionary Statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from flames and hot surfaces. – No smoking.
P233 Keep container tightly closed.
P260 Do not breathe fume/gas/mist/vapours/spray.
P264 Wash hands and forearms thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P302 + P352 If on skin: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention.
P304 + P340 If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center or doctor.
P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P370 + P378 In case of fire: Use water spray, fog, hand-held dry chemical or foam to extinguish.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type uvcb

A complex combination of heavy (high boiling point) petroleum hydrocarbons.

Chemical Name CAS Number Concentration Hazardous
Fuel oil 68476-33-5 100% No

Notes

The amount of sulfur varies with product specification and does not affect the health and safety properties as outlined in this Safety Data Sheet.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove person to fresh air. If person is not breathing, provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.

Skin contact

Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or waterless hand cleanser. Obtain medical attention if irritation or redness develops. Thermal burns require immediate medical attention depending on the severity and the area of the body burned.

Symptoms: irritation or redness

Eye contact

In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold eyelids open to ensure adequate flushing. Seek medical attention.

Ingestion

DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Monitor for breathing difficulties. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated.

Immediate Medical Attention

Seek medical attention immediately (inhalation); Obtain immediate medical attention (ingestion); Seek medical attention (eyes); Obtain medical attention if irritation or redness develops (skin).

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, fire fighting foam, CO2, and other gaseous agents. LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers.

Specific hazards

Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard. Tank headspaces should be regarded as potentially flammable.

Instructions

Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and other fire fighting equipment. Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire fighting foam.

Firefighter Protection

Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH approved pressure-demand self-contained breathing apparatus with full facepiece and full protective clothing.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas.

Environmental

Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems, unless system is designed and permitted to handle such material. The use of fire fighting foam may be useful in certain situations to reduce vapors.

Cleanup methods

Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for reclamation or disposal.

Materials: sand or other oil absorbing materials

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle as a combustible liquid. Keep away from heat, sparks, and open flame! Personnel exposed to ash should wear appropriate protective clothing (example, DuPont Tyvek ®), wash skin thoroughly, launder contaminated clothing separately, and wear respiratory protection approved for use against toxic metal dusts (such as HEPA filter cartridges).

Storage

Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers. Keep containers closed and clearly labeled. Store in a well-ventilated area.

Hygiene

wash skin thoroughly, launder contaminated clothing separately

Fire prevention

Keep away from heat, sparks, and open flame! Bond and ground containers during product transfer to reduce the possibility of static-initiated fire or explosion.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces.

Hands

Gloves constructed of nitrile, neoprene, or PVC are recommended.

Eyes

Safety glasses or goggles are recommended where there is a possibility of splashing or spraying.

Respiratory

A NIOSH approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation. Protection provided by air-purifying respirators is limited.

Skin/Body

Chemical protective clothing such as of E.I. DuPont TyChem®, Saranex® or equivalent recommended based on degree of exposure. Note: The resistance of specific material may vary from product to product as well as with degree of exposure. Consult manufacturer specifications for further information.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Softening Point
---
Flash Point
>140 °F (>60 °C) minimum
Molecular Weight
---
Partition Coefficient
ND
Flammability
---
Vapor Density
---
Solubility
---
Boiling Point
300-700+ °F (188-371 °C)
Explosive Limits
---
Solubility In Water
Negligible
Appearance
Black, viscous
Decomposition Temperature
---
Relative Density
0.887-0.9725 (API 28.0-14.0)
Properties Status
---
Kinematic Viscosity
---
Auto Ignition Temperature
ND
Evaporation Rate
Negligible
Melting Point
ND
Lower Explosive Limit
ND
Physical State Data
liquid
Colour Intensity
---
Solubility In Fat
---
Vapor Pressure
<0.004 mm Hg @ 70 °F (21 °C)
Bulk Density
---
Odor
Heavy, petroleum/asphalt-type odor
Voc Content
ND
Relative Evaporation Rate
---
Crystallisation Point
---
Colour
Black
Upper Explosive Limit
ND
Density
---
Cloud Point
---
Physical State
Liquid
Solidification Point
---
State Under Standard Conditions
---
Ph
ND
Form
viscous
Odor Threshold
---
Freezing Point
---
Dynamic Viscosity
---
Metal Corrosion
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

This is a stable material.

Hazardous reactions

Will not occur.

Avoid

Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources.

Incompatible

Keep away from strong oxidizers.

Decomposition

Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
NA 1993
Shipping Name
Combustible liquid, n.o.s. (No. 5 Fuel Oil)
Transport Class
Combustible
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Product components are subject to SARA 313 supplier notification requirements. SARA 311/312 hazard classes include Acute Health, Chronic Health, and Fire. State hazardous substance listing for Fuel oil in PA.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for No. 5 Fuel Oil?

The signal word is danger.

What is the physical form of No. 5 Fuel Oil?

No. 5 Fuel Oil is a liquid appearing as black, viscous with black color. It has heavy, petroleum/asphalt-type odor odor.

What are the hazard statements for No. 5 Fuel Oil?

This substance has 9 hazard statements:

  • H227: Combustible liquid.
  • H315: Causes skin irritation.
  • H317: May cause an allergic skin reaction.
  • H320: Causes eye irritation.
  • H330: Fatal if inhaled.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness and dizziness.
  • H350: May cause cancer.
  • H402: Harmful to aquatic life.

What is the melting point of No. 5 Fuel Oil?

The melting point is ND and the boiling point is 300-700+ °F (188-371 °C).