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Safety Data Sheet EN

Benzoyl chloride

CAS 98-88-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Benzoyl chloride
Product Code
AC105750000; AC105750010; AC105750025; AC105750100
Synonyms
Benzoic acid, chloride; alpha-Chlorobenzaldehyde; Benzene carbonyl chloride

Regulatory Identifiers

CAS Number
98-88-4 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

distributor

One Reagent Lane, Fair Lawn, NJ 07410

(201) 796-7100

A

Acros Organics

distributor

One Reagent Lane, Fair Lawn, NJ 07410

Emergency Contacts

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 4
Acute Tox. Cat. 4
Acute Tox. Cat. 3
Acute Tox. Cat. 3
Skin Corr. Cat. 1
Eye Dam. Cat. 1
Skin Sens. Cat. 1
STOT SE Cat. 3

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H302 Harmful if swallowed
H311 + H331 Toxic in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H335 May cause respiratory irritation
Combustible liquid

Precautionary Statements

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P235 Keep cool
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P280 Wear protective gloves/protective clothing/eye protection/face protection
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
P304 + P341 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER or doctor/physician
P330 Rinse mouth
P331 Do NOT induce vomiting
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P363 Wash contaminated clothing before reuse
P370 + P378 In case of fire: Use CO2, dry chemical, or foam for extinction
P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container to an approved waste disposal plant
Wash face, hands and any exposed skin thoroughly after handling

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Benzoyl chloride 98-88-4 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required.

Skin contact

Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide (CO₂), Dry chemical, soda ash or lime. Water mist may be used to cool closed containers.

Unsuitable media

Do not use water or foam

Specific hazards

Combustible material. Corrosive material. Water reactive. Contact with water liberates toxic gas. Containers may explode when heated. Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Evacuate personnel to safe areas.

Environmental

Should not be released into the environment.

Cleanup methods

Soak up with inert absorbent material.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Keep away from heat, sparks and flame.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.

Hands

Wear appropriate protective gloves

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate protective clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Auto Ignition Temperature
600 °C / 1112 °F
Vapor Density
4.88
Vapor Pressure
0.5 hPa @ 20 °C
Odor
pungent
Solubility
Reacts with water
Decomposition Temperature
No information available
Kinematic Viscosity
---
Ph
2 1 g/L (20°C)
Crystallisation Point
---
Properties Status
---
Solidification Point
---
Solubility In Water
---
Form
---
Partition Coefficient
No data available
Cloud Point
---
Softening Point
---
Flammability
Not applicable
Physical State Data
liquid
Explosive Limits
---
Density
---
Dynamic Viscosity
0.0012 Pa.s at 30 °C
Colour Intensity
---
Colour
Colorless
Relative Density
1.210
Relative Evaporation Rate
---
Upper Explosive Limit
4.9 vol %
Melting Point
-1 °C / 30.2 °F
Physical State
Liquid
State Under Standard Conditions
---
Odor Threshold
No information available
Evaporation Rate
No information available
Appearance
Colorless
Freezing Point
---
Voc Content
---
Boiling Point
198 °C / 388.4 °F
Metal Corrosion
---
Lower Explosive Limit
1.2 vol %
Bulk Density
---
Flash Point
93 °C / 199.4 °F
Solubility In Fat
---
Molecular Weight
140.57
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Water reactive. Air sensitive. Moisture sensitive.

Reactivity

Reactive Hazard Yes

Hazardous reactions

Contact with water liberates toxic gas.

Avoid

Excess heat. Incompatible products. Keep away from open flames, hot surfaces and sources of ignition. Exposure to air. Exposure to moist air or water.

Incompatible

Water, Strong oxidizing agents, Strong bases, Alcohols, Amines, Metals

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO₂), Thermal decomposition can lead to release of irritating gases and vapors, Phosgene, Hydrogen chloride gas

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1736
Shipping Name
BENZOYL CHLORIDE
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Benzoyl chloride known by?

Benzoyl chloride is also known as: Benzoic acid, chloride; alpha-Chlorobenzaldehyde; Benzene carbonyl chloride

What is the hazard signal word for Benzoyl chloride?

The signal word is danger.

What is the physical form of Benzoyl chloride?

Benzoyl chloride is a liquid appearing as colorless with colorless color. It has pungent odor.

What is the solubility of Benzoyl chloride?

Reacts with water

What is Benzoyl chloride used for?

Laboratory chemicals.

What are the hazard statements for Benzoyl chloride?

This substance has 6 hazard statements:

  • H302: Harmful if swallowed
  • H311 + H331: Toxic in contact with skin or if inhaled
  • H314: Causes severe skin burns and eye damage
  • H317: May cause an allergic skin reaction
  • H335: May cause respiratory irritation
  • Combustible liquid

What is the melting point of Benzoyl chloride?

The melting point is -1 °C / 30.2 °F and the boiling point is 198 °C / 388.4 °F.