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Safety Data Sheet EN

Benzoyl chloride

CAS 98-88-4
EC 202-710-8

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Benzoyl chloride
Product Code
AC105750000; AC105750010; AC105750025; AC105750100
Chemical Name
Benzoylchloride
Synonyms
Benzene carbonyl chloride

Regulatory Identifiers

CAS Number
98-88-4 Check regulations →
EC Number
202-710-8 Check regulations →

Identified Uses

Laboratory chemicals.

Uses advised against

Food, drug, pesticide or biocidal product use.

Manufacturers & Suppliers

F

Fisher Scientific Company

distributor

One Reagent Lane Fair Lawn, NJ 07410

(201) 796-7100

A

Acros Organics

distributor

One Reagent Lane Fair Lawn, NJ 07410

Emergency Contacts

Emergency Contact

001-800-ACROS-01

Emergency Contact

+32 14 57 52 11

Emergency Contact

001-201-796-7100

Emergency Contact

+32 14 57 52 99

CHEMTREC

001-800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 4
Acute Tox. Cat. 4
Acute Tox. Cat. 3
Acute Tox. Cat. 3
Skin Corr. Cat. 1
Eye Dam. Cat. 1
Skin Sens. Cat. 1
STOT SE Cat. 3

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

GHS08 - Serious health hazard

GHS08

Hazard Statements

H227 Combustible liquid
H302 Harmful if swallowed
H311 + H331 Toxic in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H335 May cause respiratory irritation

Precautionary Statements

Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep cool
Immediately call a POISON CENTER or doctor/physician
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Wash contaminated clothing before reuse
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
If skin irritation or rash occurs: Get medical advice/attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Rinse mouth
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam for extinction
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Dispose of contents/container to an approved waste disposal plant

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Benzoylchloride 98-88-4 95% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Symptoms: trouble breathing

Skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Symptoms: May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, tingling of the hands and feet, muscle pain or flushing. Causes burns by all exposure routes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Symptoms: Causes burns by all exposure routes.

Ingestion

Do NOT induce vomiting. Call a physician or poison control center immediately.

Symptoms: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation. Causes burns by all exposure routes.

Immediate Medical Attention

Immediate medical attention is required.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use:. Carbon dioxide (CO2), Dry chemical, soda ash or lime. Water mist may be used to cool closed containers.

Unsuitable media

Do not use water or foam

Specific hazards

Combustible material. Corrosive material. Water reactive. Contact with water liberates toxic gas. Containers may explode when heated. Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear self-contained breathing apparatus and protective suit. Evacuate personnel to safe areas. Ensure adequate ventilation. Remove all sources of ignition. Do not get in eyes, on skin, or on clothing.

Environmental

Should not be released into the environment. See Section 12 for additional Ecological Information.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not get in eyes, on skin, or on clothing. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from open flames, hot surfaces and sources of ignition. Do not allow contact with water.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area. Keep away from heat, sparks and flame. Keep away from water or moist air. Store under an inert atmosphere.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.

Hands

Wear appropriate protective gloves and clothing to prevent skin exposure.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate protective gloves and clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Solubility In Water
---
Properties Status
---
Colour
Colorless
Form
---
Partition Coefficient
No data available
Odor Threshold
No information available
Evaporation Rate
No information available
Auto Ignition Temperature
600 °C / 1112 °F
Decomposition Temperature
No information available
Crystallisation Point
---
Boiling Point
198 °C / 388.4 °F
Relative Evaporation Rate
---
Freezing Point
---
Melting Point
-1 °C / 30.2 °F
Density
---
Vapor Density
4.88
Odor
pungent
State Under Standard Conditions
---
Upper Explosive Limit
4.9 vol %
Physical State Data
liquid
Colour Intensity
---
Appearance
Colorless
Metal Corrosion
---
Cloud Point
---
Flammability
Not applicable
Vapor Pressure
0.5 hPa @ 20 °C
Physical State
Liquid
Voc Content
---
Softening Point
---
Flash Point
93 °C / 199.4 °F
Molecular Weight
140.57
Kinematic Viscosity
---
Explosive Limits
---
Solubility In Fat
---
Solidification Point
---
Ph
2 1 g/L (20°C)
Dynamic Viscosity
0.0012 Pa.s at 30 °C
Relative Density
1.210
Lower Explosive Limit
1.2 vol %
Bulk Density
---
Solubility
Reacts with water
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Water reactive. Air sensitive. Moisture sensitive.

Reactivity

Yes. Contact with water liberates toxic gas.

Hazardous reactions

Contact with water liberates toxic gas. Hazardous polymerization does not occur.

Avoid

Excess heat. Incompatible products. Keep away from open flames, hot surfaces and sources of ignition. Exposure to air. Exposure to moist air or water.

Incompatible

Water, Strong oxidizing agents, Strong bases, Alcohols, Amines, Metals

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO2), Thermal decomposition can lead to release of irritating gases and vapors, Phosgene, Hydrogen chloride gas

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1736
Shipping Name
Benzoyl chloride
Transport Class
8
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Benzoyl chloride known by?

Benzoyl chloride is also known as: Benzene carbonyl chloride

What is the hazard signal word for Benzoyl chloride?

The signal word is danger.

What is the physical form of Benzoyl chloride?

Benzoyl chloride is a liquid appearing as colorless with colorless color. It has pungent odor.

What is the solubility of Benzoyl chloride?

Reacts with water

What is Benzoyl chloride used for?

Laboratory chemicals.

What are the hazard statements for Benzoyl chloride?

This substance has 6 hazard statements:

  • H227: Combustible liquid
  • H302: Harmful if swallowed
  • H311 + H331: Toxic in contact with skin or if inhaled
  • H314: Causes severe skin burns and eye damage
  • H317: May cause an allergic skin reaction
  • H335: May cause respiratory irritation

What is the melting point of Benzoyl chloride?

The melting point is -1 °C / 30.2 °F and the boiling point is 198 °C / 388.4 °F.

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