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Safety Data Sheet EN

Benzyl bromide

CAS 100-39-0
EC 202-847-3

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Benzyl bromide
Product Code
A13535, L03395

Regulatory Identifiers

CAS Number
100-39-0 Check regulations →
EC Number
202-847-3 Check regulations →

Identified Uses

SU24 Scientific research and development

Manufacturers & Suppliers

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc. logo

Alfa Aesar, Thermo Fisher Scientific Chemicals, Inc.

manufacturer

30 Bond Street, Ward Hill, MA 01835-8099

http://www.alfa.com

Emergency Contacts

Emergency Contact

(800) 343-0660

Monday-Friday, 8am-7pm EST

Carechem 24

(866) 928-0789

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Skin Corr. Cat. 1C H314
Eye Irrit. Cat. 2A H319
STOT SE Cat. 3 H335
Flam. Liq. Cat. 4 H227

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

Hazard Statements

H227 Combustible liquid.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER/doctor/physician

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance

Chemical characterization: Substances

Chemical Name CAS Number Concentration Hazardous
Benzyl bromide 100-39-0 100% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.

Skin contact

Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.

Symptoms: Causes severe skin burns.

Eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

Symptoms: Causes serious eye irritation.

Ingestion

Seek medical treatment.

Immediate Medical Attention

Seek immediate medical advice.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Specific hazards

If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide, Hydrogen bromide (HBr)

Firefighter Protection

Wear self-contained respirator. Wear fully protective impervious suit.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wear protective equipment. Keep unprotected persons away.

Environmental

Do not allow product to reach sewage system or any water course.

Cleanup methods

Absorb with liquid-binding material

Materials: sand, diatomite, acid binders, universal binders, sawdust

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Handle under dry protective gas. Keep container tightly sealed. Ensure good ventilation at the workplace.

Storage

Store in cool, dry place in tightly closed containers. Store under dry inert gas. Store in cool, dry conditions in well sealed containers.

Fire prevention

Keep ignition sources away.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

Hands

Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.

Eyes

Safety glasses with side shields / NIOSH (US) or EN 166(EU)

Respiratory

Use suitable respirator when high concentrations are present.

Skin/Body

Protective work clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
Liquid
Physical State Data
liquid
Voc Content
---
Solidification Point
---
Explosive Limits
---
Relative Evaporation Rate
---
Solubility In Fat
---
Ph
Not determined.
Form
Liquid
Solubility In Water
Not miscible or difficult to mix
Odor Threshold
Not determined.
Bulk Density
---
Properties Status
---
Lower Explosive Limit
Not determined
Upper Explosive Limit
Not determined
Vapor Density
Not determined.
Melting Point
-4 °C (25 °F)
Colour Intensity
---
Dynamic Viscosity
Not determined.
Freezing Point
---
State Under Standard Conditions
---
Appearance
Form: Liquid
Kinematic Viscosity
Not determined.
Colour
---
Cloud Point
---
Vapor Pressure
0.5 hPa
Molecular Weight
---
Boiling Point
198-199 °C (388-390 °F)
Partition Coefficient
Not determined.
Flammability
Not determined.
Evaporation Rate
Not determined.
Auto Ignition Temperature
Not determined
Flash Point
87 °C (189 °F)
Solubility
Not miscible or difficult to mix
Decomposition Temperature
Not determined
Softening Point
---
Relative Density
Not determined.
Odor
Pungent, makes eyes water
Metal Corrosion
---
Density
1.438 g/cm³ (12 lbs/gal)
Crystallisation Point
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Reactivity

No information known.

Hazardous reactions

Reacts with strong oxidizing agents

Avoid

No further relevant information available.

Incompatible

Oxidizing agents, Water/moisture

Decomposition

Carbon monoxide and carbon dioxide, Hydrogen bromide

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Consult state, local or national regulations to ensure proper disposal.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1737
Shipping Name
Benzyl bromide
Transport Class
6.1 Toxic substances
Packing Group
II
ADR

Warning: Toxic substances

IMDG

Warning: Toxic substances

IATA

Warning: Toxic substances

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Benzyl bromide?

The signal word is danger.

What is the physical form of Benzyl bromide?

Benzyl bromide is a liquid appearing as form: liquid . It has pungent, makes eyes water odor.

What is the solubility of Benzyl bromide?

Not miscible or difficult to mix

What is Benzyl bromide used for?

SU24 Scientific research and development

What are the hazard statements for Benzyl bromide?

This substance has 3 hazard statements:

  • H227: Combustible liquid.
  • H314: Causes severe skin burns and eye damage.
  • H335: May cause respiratory irritation.

What is the melting point of Benzyl bromide?

The melting point is -4 °C (25 °F) and the boiling point is 198-199 °C (388-390 °F).