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Safety Data Sheet EN

Wood Ash

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Wood Ash
Chemical Name
Chemical Residue; by-product of wood combustion
Synonyms
Biomass Fuel Ash, Wood Boiler Ash, Wood Fly Ash, Fly Ash, CDK Ash, Batch Kiln Ash

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Soil amendment and treatment

Manufacturers & Suppliers

W

Weyerhaeuser

manufacturer

220 Occidental Ave S., Seattle, WA 98104

(206) 539-3910

Emergency Contacts

3E Company

(844) 523-4081

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Carc. Cat. 1A H350
STOT RE Cat. 1 H372
Eye Dam. Cat. 1 H314
Skin Irrit. Cat. 2 H314
STOT SE H335
Acute Tox. Cat. 4 H332
Combustible Dust

GHS Pictograms

GHS05 - Corrosive

GHS05

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H314 Causes skin burns and serious eye damage
H332 Corrosive, harmful if swallowed
H335 May cause respiratory irritation
H350 Crystalline silica may cause lung cancer
H372 May Cause Damage to The Respiratory System Through Prolonged or Repeated Exposures If Inhaled

Precautionary Statements

P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from sparks flames or other heat sources.
P243 Take precautionary measures against static discharge.
P260 Avoid breathing dust. In case of inadequate ventilation wear an approved respirator suitable for conditions of use.
P261 Avoid breathing dust. In case of inadequate ventilation wear an approved respirator suitable for conditions of use.
P262 Avoid breathing dust. In case of inadequate ventilation wear an approved respirator suitable for conditions of use.
P264 If on skin wash with plenty of soap and water.
P271 Use outdoors or in a well-ventilated area.
P280 Wear appropriate protective equipment for eye and skin exposure.
P305 + P351 + P338 If in eyes, rinse cautiously for several minutes. Remove contact lenses if present and easy to do so.
P333 + P313 If skin irritation or rash occurs get medical advice/attention.
P352 If on skin wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P362 Take off contaminated clothing and wash before reuse.
P363 Take off contaminated clothing and wash before reuse.
P364 Take off contaminated clothing and wash before reuse.
P501 Dispose of in accordance with federal, state, and local regulations.
If inhaled and breathing becomes difficult, remove person to fresh air and keep comfortable for breathing. If symptoms persist, call a doctor or other qualified medical professional.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

Wood ash is a highly variable material whose composition depends on wood source/mix, combustion type and conditions, amount and composition of any tramp soil material, mixture of different ash streams, solids size distribution and degree of wetting before shipment. Final composition and form can affect health and physical hazards. Although wood ash residual is often wetted before shipment and is also hydrophilic, water was not included in the ingredients as it may evaporate.

Chemical Name CAS Number Concentration Hazardous
Wood Char (incompletely burned wood material containing residual Carbon) --- 5 - 50% No
Silica (amorphous, non-crystalline) (SiO₂) 7631-86-9 1 - 10% No
Silica (crystalline, quartz) (SiO₂) 14808-60-7 0.1 - 1% No
Aluminum Oxide (Al₂O₃) 1344-28-1 1 - 10% No
Calcium Oxide (CaO) 1305-78-8 30 - 70% No
Iron Oxide (FeO) 1309-37-1 1 - 5% No
Magnesium Oxide (MgO) 1309-48-4 5 - 10% No
Manganese (Mn) 7439-96-5 0.1 - 1% No
Potassium Hydroxide (and other potassium compounds such as potassium oxide K₂O) (KOH) 1310-58-3 10 - 30% No
Sodium Hydroxide (and other sodium compounds) (NaOH) 1310-73-2 1 - 5% No

Wood ash is a highly variable material whose composition depends on wood source/mix, combustion type and conditions, amount and composition of any tramp soil material, mixture of different ash streams, solids size distribution and degree of wetting before shipment. Final composition and form can affect health and physical hazards. Although wood ash residual is often wetted before shipment and is also hydrophilic, water was not included in the ingredients as it may evaporate.

Notes

Wood char and ash may contain trace (ppt levels) amounts of dioxin compounds; the non-metallic portion in the char can contain variable but significant residual carbon content which can affect dust combustibility. The non-char portion of the material is true ash from more completely combusted wood containing metals and their oxides. Common names:[1] Limestone;[2] burnt lime, quicklime[3] potash;[4] alumina;[ 5] ferric oxide;[6] magnesia. Oxide compounds’ presence, oxide and hydroxide combinations and corresponding concentrations will vary depending on source and combustion conditions. Some oxides may also exist as their metal carbonates (e.g., calcium carbonate) although the oxides are expected to predominate. Silica in its quartz form may be present if tramp soil material carries over into the combustion process.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If inhaled, remove person to fresh air and keep comfortable for breathing. Get medical attention if breathing difficulties do not quickly resolve or if exposure was extensive.

Symptoms: unpleasant obstruction to the nasal passages, nosebleed, chemical irritation, and possible corrosive burns to the membranes of the upper respiratory tract.

Skin contact

If on skin or hair, rinse off using water or otherwise remove immediately (vacuum, gentle brushing), take off contaminated clothing and wash before reuse. Obtain medical attention for signs or symptoms of persisting skin irritation or any skin damage.

Symptoms: irritation and corrosive burns; skin irritation and possibly corrosive type burns. Prolonged direct contact inside boots and gloves can exacerbate skin damage and lead to ulceration.

Eye contact

If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Medical evaluation is recommended if symptoms persist or if exposure was extensive.

Symptoms: irritation and corrosive burns to the eyes; burning and corrosive damage of the eyes.

Ingestion

Rinse mouth and do not induce vomiting.

Symptoms: severe irritation and burning of the mouth and digestive tract.

Immediate Medical Attention

Get medical attention if breathing difficulties do not quickly resolve or if exposure was extensive. Medical evaluation is recommended if symptoms persist or if exposure was extensive. Obtain medical attention for signs or symptoms of persisting skin irritation or any skin damage.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use fine water mist or fog spray on smoldering wood ash taking care to avoid stirring and causing increased mixing with and exposure to air. Use sand or other noncombustible solids to smother the fire with care if water application not feasible.

Unsuitable media

Avoid using a high-pressure stream of water directed at smoldering wood ash.

Specific hazards

Depending on the source, amount of residual combustible material and moisture content, airborne suspensions of ash dust may form a combustible dust hazard and be ignited if sufficient concentration and ignition energy is present.

Instructions

Avoid using a high-pressure stream of water directed at smoldering wood ash. This may cause a flare up. Beware of potential combustible dust explosion hazard.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Wood ash may be vacuumed or shoveled after wetting for recovery or disposal.

Small spill

Wood ash may be vacuumed or shoveled after wetting for recovery or disposal.

Cleanup methods

vacuumed or shoveled after wetting

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Use proper personal protective equipment (gloves and goggles) when handling. Barrier cream may protect the skin from drying and provide some protection against corrosivity. Use a NIOSH-approved filtering facepiece respirator ("dust mask") and dust goggles when recommended allowable exposure limits may be exceeded. Care is needed to avoid dust accumulation between the respirator sealing surface and the skin.

Storage

Keep bulk and bagged ash dry until used. Stack bagged material in a secure manner to prevent falling. Wood ash should be stored and transported to the extent possible in a covered bin or container.

Hygiene

Barrier cream may protect the skin from drying.

Fire prevention

Keep ignition sources away from airborne dust clouds.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

LOCAL EXHAUST – Provide local exhaust as needed so that exposure limits are met. Ensure that combustible dust aspect is investigated if enclosed systems including conveyors are used to capture and convey ash dust. MECHANICAL (GENERAL) – Provide general ventilation in processing and storage areas so that exposure limits are met. SPECIAL – Material may clog ventilation systems, requiring ongoing inspection and cleaning. Other Engineering Controls: NAP

Hands

Cloth, canvas, or leather gloves are recommended when handling the dry product to minimize potential mechanical irritation. If product becomes wet, neoprene, butyl, or nitrile gloves are recommended. Ensure glove interior is kept clean. Discard gloves with contaminated interiors.

Eyes

An emergency eye wash fountain should be present near areas of potential eye exposure. Goggles or safety glasses are recommended when handling this product.

Respiratory

Use NIOSH-approved filtering face piece respirator (“dust mask”) or higher level of respiratory protection as indicated and goggles where ventilation is not possible and exposure limits may be exceeded or for additional worker comfort or symptom relief. Following a determination of risk from potential exposures, use respiratory protection in accordance with requirements such as US-OSHA respiratory protection standard 29CFR 1910.134.

Skin/Body

Protective clothing with long sleeves or disposable outer garments may be desirable in extremely dusty areas. The use of barrier skin cream may prevent skin irritation in susceptible individuals.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Odor
odorless
Melting Point
NAP
Boiling Point
NAP
Explosive Limits
---
Solidification Point
---
Auto Ignition Temperature
450° – 5,000°F, (232° – 2760°C)
Dynamic Viscosity
NAP
Solubility In Fat
---
Evaporation Rate
NAP
Cloud Point
---
Solubility In Water
---
Colour Intensity
---
Relative Density
NAV
Solubility
Slightly (<5%)
Decomposition Temperature
NAV
Appearance
Wood ash is a solid, grey/black or black/tan odorless powder which may contain solidified masses.
Metal Corrosion
---
Partition Coefficient
NAP
Colour
grey/black or black/tan
Odor Threshold
NAV
Flash Point
NAP
Vapor Pressure
NAP
State Under Standard Conditions
---
Relative Evaporation Rate
---
Bulk Density
---
Lower Explosive Limit
NAV
Vapor Density
NAP
Form
powder
Voc Content
---
Softening Point
---
Properties Status
---
Physical State Data
solid
Crystallisation Point
---
Physical State
solid
Flammability
NAP
Freezing Point
NAP
Density
---
Molecular Weight
---
Upper Explosive Limit
NAV
Kinematic Viscosity
NAP
Ph
>11-13 (if CaO present in high concentration and wetted)
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable

Reactivity

Depending on concentration and degree of hydration of any Calcium Oxide, heat may be generated from the chemical reaction of CaO and water. Depending on amount and concentration, significant heat buildup may occur when calcium oxide initially reacts with water.

Hazardous reactions

Will not occur

Avoid

Avoid open flames.

Incompatible

Avoid contact with oxidizing agents and strong acids.

Decomposition

Carbon monoxide and carbon dioxide.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dry land disposal is acceptable

Disposal

Do not dispose in areas of high ground water or where surface runoff is adjacent to waterways. It is, however, the user's responsibility to determine at the time of disposal whether the product meets EPA RCRA criteria for hazardous waste.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
NAP
Shipping Name
NAP
Transport Class
NAP
Packing Group
NAP
IMDG

NAP

IATA

NAP

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Wood ash is considered to be a hazardous chemical in accordance with OSHA classification criteria.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is Wood Ash known by?

Wood Ash is also known as: Biomass Fuel Ash, Wood Boiler Ash, Wood Fly Ash, Fly Ash, CDK Ash, Batch Kiln Ash

What is the hazard signal word for Wood Ash?

The signal word is danger.

What is the physical form of Wood Ash?

Wood Ash is a solid appearing as wood ash is a solid, grey/black or black/tan odorless powder which may contain solidified masses. with grey/black or black/tan color. It has odorless odor.

What is the solubility of Wood Ash?

Slightly (<5%)

What is Wood Ash used for?

Soil amendment and treatment

What are the hazard statements for Wood Ash?

This substance has 5 hazard statements:

  • H314: Causes skin burns and serious eye damage
  • H332: Corrosive, harmful if swallowed
  • H335: May cause respiratory irritation
  • H350: Crystalline silica may cause lung cancer
  • H372: May Cause Damage to The Respiratory System Through Prolonged or Repeated Exposures If Inhaled

What is the melting point of Wood Ash?

The melting point is NAP and the boiling point is NAP.

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