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Safety Data Sheet EN

denatured (A407)

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
denatured (A407)
Product Code
A407-1; A407-4; A407-20; A407-200; A407-500; A407P-4; A407RB-19; A407RB-115; A407RB-200; A407S-4; A407SK-4

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Laboratory chemicals.

Uses advised against

Not for food, drug, pesticide or biocidal product use

Manufacturers & Suppliers

F

Fisher Scientific

distributor

One Reagent Lane Fair Lawn, NJ 07410

(201) 796-7100

Emergency Contacts

CHEMTREC

800-424-9300

CHEMTREC

001-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2
STOT SE Cat. 1
STOT RE Cat. 1

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

Hazard Statements

H225 Highly flammable liquid and vapor
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
Causes damage to organs
Causes damage to organs through prolonged or repeated exposure

Precautionary Statements

Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/protective clothing/eye protection/face protection
Keep cool
IF exposed: Call a POISON CENTER or doctor/physician
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
In case of fire: Use CO2, dry chemical, or foam for extinction
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Dispose of contents/container to an approved waste disposal plant

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Manage SDS
03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture
Chemical Name CAS Number Concentration Hazardous
Ethylalcohol 64-17-5 88.785% No
Water 7732-18-5 4.673% No
Methylalcohol 67-56-1 3.738% No
Methylisobutyl ketone 108-10-1 0.935% No
Ethylacetate 141-78-6 0.935% No
Hexane 110-54-3 0.822% No
Toluene 108-88-3 0.075% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move to fresh air. If breathing is difficult, give oxygen. Give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Symptoms: Breathing difficulties. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting

Skin contact

Wash off immediately with plenty of water for at least 15 minutes.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion

Do not induce vomiting. Call a physician or Poison Control Center immediately.

Immediate Medical Attention

Immediate medical attention is required for skin contact and inhalation. Seek medical advice for eye contact. Call a physician or Poison Control Center immediately for ingestion.

Medical Treatment

Treat symptomatically

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Cool closed containers exposed to fire with water spray.

Unsuitable media

Water may be ineffective

Specific hazards

Flammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Vapors may form explosive mixtures with air.

Firefighter Protection

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Ensure adequate ventilation. Use personal protective equipment. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. Remove all sources of ignition. Take precautionary measures against static discharges.

Environmental

Should not be released into the environment. Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information.

Cleanup methods

Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

Materials: inert absorbent material

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Do not breathe vapors or spray mist. Do not ingest.

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Flammables area.

Hygiene

Do not ingest.

Fire prevention

Keep away from open flames, hot surfaces and sources of ignition. Keep away from heat and sources of ignition.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. Use explosion-proof electrical/ventilating/lighting/equipment.

Hands

Wear appropriate protective gloves to prevent skin exposure.

Eyes

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Respiratory

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Skin/Body

Wear appropriate protective clothing to prevent skin exposure.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Form
---
Lower Explosive Limit
No data available
Solubility In Fat
---
Voc Content
---
Freezing Point
---
Flammability
Not applicable
Bulk Density
---
Colour
Colorless
Upper Explosive Limit
No data available
Decomposition Temperature
No information available
Solubility
Soluble in water
Crystallisation Point
---
Boiling Point
78.5 °C / 173.3 °F
Appearance
Clear, Colorless
Partition Coefficient
No data available
Physical State Data
liquid
Evaporation Rate
2.0
Odor
aromatic
Solidification Point
---
Auto Ignition Temperature
362.8 °C / 685 °F
Melting Point
-90.0 °C / -130 °F
Softening Point
---
Solubility In Water
Soluble in water
Metal Corrosion
---
Density
---
Physical State
Liquid
Relative Evaporation Rate
---
Kinematic Viscosity
No information available
Colour Intensity
---
Cloud Point
---
Vapor Pressure
40.9 mmHg @ 20 °C
Odor Threshold
No information available
Ph
No information available
Dynamic Viscosity
No information available
Flash Point
13.9 °C / 57 °F
State Under Standard Conditions
---
Molecular Weight
---
Vapor Density
No information available
Relative Density
0.7905
Properties Status
---
Explosive Limits
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions.

Reactivity

None known, based on information available

Hazardous reactions

Hazardous polymerization does not occur. None under normal processing.

Avoid

Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible

Strong oxidizing agents, Strong acids, Acid anhydrides, Acid chlorides

Decomposition

Carbon monoxide (CO), Carbon dioxide (CO2)

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Ecotoxicity

Ecotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment. | Component | Freshwater Algae | Freshwater Fish | Microtox | Water Flea | | --- | --- | --- | --- | --- | | Ethyl alcohol | EC50 (72h) = 275 mg/l (Chlorella vulgaris) | Fathead minnow (Pimephales promelas) LC50 = 14200 mg/l/96h | Photobacterium phosphoreum:EC50 = 34634 mg/L/30 min Photobacterium phosphoreum:EC50 = 35470 mg/L/5 min | EC50 = 9268 mg/L/48h EC50 = 10800 mg/L/24h | | Methyl alcohol | Not listed | Pimephales promelas: LC50 > 10000 mg/L 96h | EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min | EC50 > 10000 mg/L 24h | | Methylisobutyl ketone | EC50: 400 mg/L/96h | LC50: 496 - 514 mg/L, 96h flow-through (Pimephales promelas) | EC50 = 79.6 mg/L 5 min | EC50: 4280.0 mg/L/24h EC50: 170 mg/L/48h EC50: 4280.0 mg/L/24h | | Ethyl acetate | EC50 = 3300 mg/L/48h | Fathead minnow: LC50: 230 mg/l/ 96h Gold orfe: LC50: 270 mg/L/48h | EC50 = 1180 mg/L 5 min EC50 = 1500 mg/L 15 min EC50 = 5870 mg/L 15 min EC50 = 7400 mg/L 2 h | EC50 = 717 mg/L/48h | | Hexane | Not listed | LC50: 2.1 - 2.98 mg/L, 96h flow-through (Pimephales promelas) | Not listed | EC50: 3.87 mg/L/48h | | Toluene | EC50: = 12.5 mg/L, 72h static (Pseudokirchneriella subcapitata) EC50: > 433 mg/L, 96h (Pseudokirchneriella subcapitata) | 50-70 mg/L LC50 96 h 5-7 mg/L LC50 96 h 15-19 mg/L LC50 96 h 28 mg/L LC50 96 h 12 mg/L LC50 96 h | EC50 = 19.7 mg/L 30 min | EC50: = 11.5 mg/L, 48h (Daphnia magna) EC50: 5.46 - 9.83 mg/L, 48h Static (Daphnia magna) |

The product is toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment. Several components are identified as hazardous, with detailed ecotoxicity data for freshwater algae, fish, microtox, and water flea.

Persistence and Degradability

Persistence and Degradability Persistence is unlikely based on information available.

Persistence is unlikely based on information available.

Bioaccumulation/ Accumulation

Bioaccumulation/ Accumulation No information available.

No information available.

Mobility

Mobility Will likely be mobile in the environment due to its volatility. | Component | log Pow | | --- | --- | | Ethyl alcohol | -0.32 | | Methyl alcohol | -0.74 | | Methylisobutyl ketone | 1.19 | | Ethyl acetate | 0.6 | | Hexane | 4.11 | | Toluene | 2.7 |

The substance will likely be mobile in the environment due to its volatility. Log Pow values are provided for several components.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Waste Codes

U154 Methyl alcohol - 67-56-1 RCRA
U161 Methyl isobutyl ketone - 108-10-1 RCRA
U112 Ethyl acetate - 141-78-6 RCRA
U220 Toluene - 108-88-3 RCRA
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN1170
Shipping Name
ETHANOL SOLUTION
Transport Class
3
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for denatured (A407)?

The signal word is danger.

What is the physical form of denatured (A407)?

denatured (A407) is a liquid appearing as clear, colorless with colorless color. It has aromatic odor.

What is the solubility of denatured (A407)?

Soluble in water

What is denatured (A407) used for?

Laboratory chemicals.

What are the hazard statements for denatured (A407)?

This substance has 5 hazard statements:

  • H225: Highly flammable liquid and vapor
  • H335: May cause respiratory irritation
  • H336: May cause drowsiness or dizziness
  • Causes damage to organs
  • Causes damage to organs through prolonged or repeated exposure

What is the melting point of denatured (A407)?

The melting point is -90.0 °C / -130 °F and the boiling point is 78.5 °C / 173.3 °F.

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