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Safety Data Sheet EN

Iodine

CAS 7553-56-2
EC 231-442-4

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Iodine
Product Code
I8780
Chemical Name
food

Regulatory Identifiers

CAS Number
7553-56-2 Check regulations →
EC Number
231-442-4 Check regulations →
REACH No.
01-2119485285-30

Identified Uses

Laboratory chemicals, Synthesis of substances

Manufacturers & Suppliers

S

Sigma-Aldrich

3050 Spruce Street SAINT LOUIS MO 63103 USA

+1 800-325-5832

Emergency Contacts

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H332
Acute Tox. Cat. 4 H312
Skin Irrit. Cat. 2 H315
Eye Irrit. Cat. 2A H319
STOT SE Cat. 3 H335
STOT RE Cat. 1 H372
Aquatic Acute Cat. 1 H400

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H312 + H332 Harmful in contact with skin or if inhaled
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H372 Causes damage to organs (Thyroid) through prolonged or repeated exposure if swallowed.
H400 Very toxic to aquatic life.

Precautionary Statements

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves/ protective clothing.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or doctor/ physician if you feel unwell.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Iodine EC: 231-442-4 7553-56-2 100% Yes

Notes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

Skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Ingestion

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Immediate Medical Attention

No data available

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Firefighter Protection

Wear self-contained breathing apparatus for firefighting if necessary.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Cleanup methods

Pick up and arrange disposal without creating dust. Sweep up and shovel.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Further processing of solid materials may result in the formation of combustible dusts. The potential for combustible dust formation should be taken into consideration before additional processing occurs.

Storage

Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. Hygroscopic.

Fire prevention

Further processing of solid materials may result in the formation of combustible dusts. The potential for combustible dust formation should be taken into consideration before additional processing occurs.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Handle in accordance with good industrial hygiene and safety practice.

Hands

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Eyes

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Respiratory

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N99 (US) or type P2 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Skin/Body

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Environmental

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Properties Status
---
Relative Evaporation Rate
---
State Under Standard Conditions
---
Physical State
solid
Auto Ignition Temperature
No data available
Vapor Pressure
0.41 hPa (0.31 mmHg) at 25 °C (77 °F)
Upper Explosive Limit
No data available
Vapor Density
8.76 - (Air = 1.0)
Melting Point
113 °C (235 °F)
Odor Threshold
No data available
Explosive Limits
---
Appearance
solid, black, violet
Flash Point
No data available
Flammability
No data available
Freezing Point
---
Solidification Point
---
Solubility In Water
0.3 g/l at 25 °C (77 °F) - slightly soluble
Dynamic Viscosity
---
Form
solid
Lower Explosive Limit
No data available
Physical State Data
solid
Odor
pungent
Metal Corrosion
---
Solubility
---
Evaporation Rate
No data available
Molecular Weight
---
Boiling Point
184 °C (363 °F)
Colour
black, violet
Softening Point
---
Voc Content
---
Relative Density
4.930 g/cm3
Decomposition Temperature
No data available
Bulk Density
---
Partition Coefficient
log Pow: 2.49 at 20 °C (68 °F)
Cloud Point
---
Crystallisation Point
---
Ph
5.4
Kinematic Viscosity
---
Solubility In Fat
---
Density
---
Colour Intensity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under recommended storage conditions.

Incompatible

Rubber, Plastics, Iron and iron salts., Sulphur compounds, Ammonia, Magnesium, Zinc, Aluminum, Metals, Alkalis, Antimony salts, Arsenites, bromides, chlorides, iodides, thiocyanates, ferrous salts, hypophosphites, morphine salts, oils, creosote, phosphates, tannins, tartrates, Mixing iodine, antimony, and ammonia resulted in an explosion. A violent reaction occurs between iodine and acetaldehyde., Acetylene, Acetaldehyde, Strong oxidizing agents

Decomposition

Hazardous decomposition products formed under fire conditions. - Hydrogen iodide Other decomposition products - No data available

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

Toxicity

Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 1.7 mg/l - 96.0 h Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - 0.2 mg/l - 48 h Toxicity to algae Growth inhibition EC50 - Desmodesmus subspicatus (green algae) - 0.13 mg/l (OECD Test Guideline 201)

Persistence and degradability

No data available

No data available

Bioaccumulative potential

No data available

No data available

Mobility in soil

No data available

No data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life.

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

Disposal

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3495
Shipping Name
Iodine
Transport Class
8 (6.1)
Packing Group
III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Chemical Safety Assessment Not performed

SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Iodine?

The signal word is danger.

What is the physical form of Iodine?

Iodine is a solid appearing as solid, black, violet with black, violet color. It has pungent odor.

What is Iodine used for?

Laboratory chemicals, Synthesis of substances

What are the hazard statements for Iodine?

This substance has 6 hazard statements:

  • H312 + H332: Harmful in contact with skin or if inhaled
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H335: May cause respiratory irritation.
  • H372: Causes damage to organs (Thyroid) through prolonged or repeated exposure if swallowed.
  • H400: Very toxic to aquatic life.

What is the melting point of Iodine?

The melting point is 113 °C (235 °F) and the boiling point is 184 °C (363 °F).

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