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Safety Data Sheet EN

Zinc and Zinc Alloys

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Zinc and Zinc Alloys
Product Form
Ingots, Feeder Bars, Sticks, Cast Shapes.

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Industrial: Melted to produce castings; Consumer: It is thought that there will be no consumer use of alloy ingot

Manufacturers & Suppliers

The Brock Metal Company Limited logo

The Brock Metal Company Limited

manufacturer

Walsall Road, Norton Canes, Cannock, Staffordshire. WS11 9NR

(01543) 276666

http://brock-metal.co.uk

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

All Brock alloys are based on high purity Zinc with additions of Aluminium, Copper and Magnesium. Impurities include Iron, Lead, Cadmium, Tin, Nickel, and Silicon.

Chemical Name CAS Number Concentration Hazardous
Zinc EC: 231-175-3 7440-66-6 --- No
Aluminium EC: 231-072-3 7429-90-5 4.05 - 28% No
Copper EC: 231-159-6 7440-50-8 0.03 - 3.3% No
Magnesium EC: 231-104-6 7439-95-4 0.005 - 0.06% No
Iron --- 0.02 - 0.07% No
Lead --- 0.003 - 0.005% No
Cadmium --- 0.003 - 0.005% No
Tin --- 0.001 - 0.002% No
Nickel --- 0.001 - 0.02% No
Silicon --- 0.02 - 0.07% No

Notes

These elements are not known to constitute a risk to health or safety at the levels stated. Other impurities may be present in the alloys but at levels less than stated above.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim from exposure to processing fumes or dusts to fresh air. Seek medical attention immediately.

Skin contact

If dust, remove contaminated clothing and wash effected area with soap and water. Seek medical attention if irritation persists. Molten Metal – flood contact area to solidify and cool but do not attempt to remove encrusted metal on skin or clothing. Continue to flush for at least 10 minutes. Cover burns, if bigger than a 50 pence piece. Seek further medical attention immediately.

Eye contact

If dust enters eyes flush for 10 – 20 minutes with cold water. Seek medical attention if required.

Ingestion

Not regarded as a normal occupational hazard. Do not induce vomiting – Seek medical attention immediately if large quantities of dust or fume are ingested.

Immediate Medical Attention

Seek medical attention immediately.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use suitable extinguishing media for surrounding combustibles. If present in molten form use dry sand.

Unsuitable media

Do not use water as this may present an explosion hazard.

Specific hazards

Finely divided metallic dust form flammable or explosive dust clouds when mixed with air. Bulk dust in a damp state may heat spontaneously and ignite on exposure to air.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

In solid state pick up and reuse if not contaminated.

Cleanup methods

In solid state pick up and reuse if not contaminated.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Store metal in a dry area away from incompatible materials. Ingots suspected of containing moisture should be thoroughly dried before adding to a molten bath. Ensure all ingots are dry prior to use. Do not allow water to come into contact with molten metal. When handling molten alloys, observe relevant HSE regulations for personal protection. Wear gloves when handling ingots manually to avoid minor cuts and abrasions. Observe normal precautions for industrial lifting.

Storage

Store in a dry area. Stacks should be well aligned and stable. One tonne pallets or bundles should not be stacked more than four units high. Any stack should consist of only one pallet type.

Hygiene

Wear gloves when handling ingots manually to avoid minor cuts and abrasions.

Fire prevention

Do not allow water to come into contact with molten metal. Avoid contact with acids and alkali hydroxides. Avoid mixtures with potassium chlorate or ammonium nitrate. Manage Zinc dust to prevent fire risk from explosive mixtures in air.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use adequate local or general ventilation to maintain the concentration of zinc and aluminum oxide fumes in the working environment well below recommended occupational exposure limits. Supply sufficient replacement air to make up for air removed by the exhaust system. Where metallic dust particles of zinc and aluminum metals are being collected and transported by a ventilation system, use a non-sparking, grounded ventilation system separate from other exhaust ventilation systems. Locate dust collectors and fans outdoors if possible and provide dust collectors with explosion vents or blow out panels.

Hands

Gloves are recommended to prevent prolonged or repeated direct skin contact when this product is processed. Where hot or molten metal is handled, heat-resistant gloves should be worn.

Eyes

Eye protection should be worn where fume or dust is generated. Where hot or molten metal is handled, full face visor should be worn.

Respiratory

Respiratory protection may be required where oxide fume is generated. Where zinc or aluminium oxide fumes are generated and cannot be controlled to within acceptable levels by engineering means, use appropriate respiratory protection equipment.

Skin/Body

Coveralls, shop coat or other work clothing are recommended to prevent prolonged or repeated direct skin contact when this product is processed. Where hot or molten metal is handled, molten metal resistant clothing to protect from hot metal splash should be worn. Foundry or safety type boots are recommended.

Environmental

Water: Do not release to water. Air: Local Exhaust ventilation may be required. Soil: Do not release to soil.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Dynamic Viscosity
---
Solubility In Fat
---
Colour Intensity
---
Colour
silver grey
Vapor Density
---
Kinematic Viscosity
---
Upper Explosive Limit
---
Partition Coefficient
---
Decomposition Temperature
---
Odor Threshold
---
Evaporation Rate
---
Flash Point
---
Crystallisation Point
---
Bulk Density
---
Form
Ingot, Feeder Bar, Sticks, Cast Shapes
Solubility In Water
Insoluble
Freezing Point
---
Ph
Not applicable
Molecular Weight
---
State Under Standard Conditions
---
Voc Content
---
Melting Point
ZL2 379 – 390 °C, ZL3 381 – 387 °C, ZL5 380 – 386 °C, ZL6 375 – 395 °C, ZL7 381 – 387°C, ZL8 375 – 404 °C, ZL12 375 – 432 °C, ZL27 375 – 484 °C
Boiling Point
907 °C
Properties Status
---
Cloud Point
---
Vapor Pressure
Negligible @ 20°C
Physical State Data
solid
Relative Density
---
Auto Ignition Temperature
---
Flammability
---
Solubility
Soluble in acids and Alkalis
Odor
None in solid form
Lower Explosive Limit
---
Metal Corrosion
---
Solidification Point
---
Physical State
All ingots carry the manufacturers name, alloy type and batch or melt numbers which allow chemical analysis to be traced.
Explosive Limits
---
Density
6.7 g/cm³ approx – dependent on the alloy.
Softening Point
---
Appearance
Zinc is a silver grey metal
Relative Evaporation Rate
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Zinc is stable at room temperature.

Reactivity

Zinc is stable under normal conditions but can react vigorously with acids and alkali's.

Hazardous reactions

Contact with acids and alkalis will generate highly flammable hydrogen gas. Acidic arsenic or antimony compounds in contact with Zinc metal may evolve highly toxic arsine or stibine gas.

Incompatible

strong oxidising agents such as chlorine, fluorine, bromine, sodium potassium or barium peroxide, sodium or potassium chlorate, chromium trioxide and fused ammonium nitrate. Also incompatible with elemental sulphur dust, halogenated hydrocarbons or chlorinated solvents and chlorinated rubber.

Decomposition

Thermal oxidation of this metal or dust will generate Zinc oxide fume which on inhalation in sufficient quantity can produce metal fume fever, a transient influenza like illness.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Disposal

If material cannot be returned to process or salvage, dispose of in accordance with applicable local regulations. Your supplier may be able to recycle this material for you.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

Neither zinc nor aluminium is listed as a dangerous substance.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Zinc and Zinc Alloys?

The signal word is no signal word.

What is the physical form of Zinc and Zinc Alloys?

Zinc and Zinc Alloys is a all ingots carry the manufacturers name, alloy type and batch or melt numbers which allow chemical analysis to be traced. appearing as zinc is a silver grey metal with silver grey color. It has none in solid form odor.

What is the solubility of Zinc and Zinc Alloys?

Soluble in acids and Alkalis

What is Zinc and Zinc Alloys used for?

Industrial: Melted to produce castings; Consumer: It is thought that there will be no consumer use of alloy ingot

What is the melting point of Zinc and Zinc Alloys?

The melting point is ZL2 379 – 390 °C, ZL3 381 – 387 °C, ZL5 380 – 386 °C, ZL6 375 – 395 °C, ZL7 381 – 387°C, ZL8 375 – 404 °C, ZL12 375 – 432 °C, ZL27 375 – 484 °C and the boiling point is 907 °C.