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Safety Data Sheet EN

ORTHO-TDA

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
ORTHO-TDA
Product Code
04243900

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Intermediate for the production of polyurethane raw materials

Manufacturers & Suppliers

C

Covestro Deutschland AG

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COV-CTO-HSEQ-PSRA-PSI 51365 Leverkusen

+49 214 6009 4068

Emergency Contacts

Chemtrec

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Acute Tox. Cat. 4 H302
Acute Tox. Cat. 4 H312
Skin Sens. Cat. 1 H317
Muta. Cat. 2 H341
Carc. Cat. 1B H350
Aquatic Acute Cat. 1 H400
Aquatic Chronic Cat. 1 H410

GHS Pictograms

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H302 Harmful if swallowed or in contact with skin
H312 Harmful if swallowed or in contact with skin
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

P201 Obtain special instructions before use.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P391 Collect spillage.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type Substance

aromatic diamin, mixture of isomers

Chemical Name CAS Number Concentration Hazardous
methyl-phenylene diamine; diaminotoluene; [technical product reaction mass of 4-methyl-m-phenylene diamine (EC No 202-453-1) and 2 -methyl-m-phenylene diamine (EC No 212-513-9)] EC: 248-145-0 26966-75-6 100% Yes

Notes

This product contains no substances of very high concern in concentrations where an information obligation applies (REACH Regulation (EC) No. 1907/2006, Article 59).

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Take the person into the fresh air and keep him warm, let him rest; if there is difficulty in breathing, medical advice is required.

Symptoms: difficulty in breathing

Skin contact

IN THE CASE OF CONTACT WITH THE HOT PRODUCT: Do not remove product crusts which may have formed neither forcibly nor by applying any solvents to the skin involved. To obtain treatment for possible burns, and appropriate skin care, seek medical advice immediately. In case of skin contact wash affected areas thoroughly with soap and plenty of water. Consult a doctor in the event of a skin reaction.

Symptoms: possible burns, skin reaction

Eye contact

Hold the eyes open and rinse with preferably lukewarm water for a sufficiently long period of time (at least 10 minutes). Contact an ophthalmologist.

Ingestion

DO NOT induce the patient to vomit, medical advice is required.

Immediate Medical Attention

Medical advice is required for difficulty in breathing, hot product skin contact, ingestion, eye contact, or skin reaction. Notes to physician: Basic first aid, decontamination, symptomatic treatment.

Medical Treatment

No information available.

Related Substances

Similar chemicals with comparable safety profiles

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Suitable materials for safety gloves; EN 374: Heat-resistant Kevlar/cotton gloves, resistant to 100 C. Hand protection when handling the product at room temperature: Nitrile rubber - NBR (>= 0.35 mm) Breakthrough time not tested; dispose of immediately after contamination.

Eyes

Wear eye/face protection.

Respiratory

Unless the product is entirely enclosed, do not handle it until you have studied the respiratory precautions issued by the appropriate authority or accident prevention association. If vapors form, respirators must be used. Put on full-mask respirator with filter type ABEK.

Skin/Body

Wear suitable protective clothing.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Relative Density
---
Freezing Point
---
Physical State Data
solid
Explosive Limits
---
State Under Standard Conditions
---
Bulk Density
---
Molecular Weight
---
Colour Intensity
---
Solubility In Water
immiscible at 15 C
Metal Corrosion
---
Decomposition Temperature
not established
Vapor Pressure
< 1 hPa at 20 C < 1 hPa at 50 C < 1 hPa at 55 C
Upper Explosive Limit
not established
Appearance
liquid, hot melt
Crystallisation Point
---
Density
1,0 g/cm at 20 C DIN 51757
Partition Coefficient
0,66
Evaporation Rate
not established
Flammability
not applicable
Flash Point
140 C at 1.013 hPa DIN EN ISO 2719
Ph
9,0
Solubility
---
Boiling Point
260 C DIN 53171
Auto Ignition Temperature
not established
Dynamic Viscosity
---
Lower Explosive Limit
not established
Voc Content
---
Melting Point
70 C DIN 51566
Solidification Point
---
Form
---
Softening Point
---
Cloud Point
---
Vapor Density
---
Kinematic Viscosity
not established
Odor
characteristic
Properties Status
---
Odor Threshold
not established
Solubility In Fat
---
Physical State
solid at 20 C at 1.013 hPa
Relative Evaporation Rate
---
Colour
colourless to pink
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN 3257
Shipping Name
ELEVATED TEMPERATURE LIQUID, N.O.S.
Transport Class
9
Packing Group
III
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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for ORTHO-TDA?

The signal word is danger.

What is the physical form of ORTHO-TDA?

ORTHO-TDA is a solid at 20 c at 1.013 hpa appearing as liquid, hot melt with colourless to pink color. It has characteristic odor.

What is ORTHO-TDA used for?

Intermediate for the production of polyurethane raw materials

What are the hazard statements for ORTHO-TDA?

This substance has 6 hazard statements:

  • H302: Harmful if swallowed or in contact with skin
  • H312: Harmful if swallowed or in contact with skin
  • H317: May cause an allergic skin reaction.
  • H341: Suspected of causing genetic defects.
  • H350: May cause cancer.
  • H410: Very toxic to aquatic life with long lasting effects.

What is the melting point of ORTHO-TDA?

The melting point is 70 C DIN 51566 and the boiling point is 260 C DIN 53171.

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