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Safety Data Sheet EN

Monoethylene Glycol

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Monoethylene Glycol

Regulatory Identifiers

CAS Number
N/A
02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified warning

Hazard Classifications

Acute Tox.
Eye Irrit.

GHS Pictograms

GHS06 - Acute toxicity

GHS06

Hazard Statements

H301 Harmful or fatal if swallowed.
H319 May cause eye irritation.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type substance
Chemical Name CAS Number Concentration Hazardous
Ethylene glycol 107-21-1 99% No
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Move person to fresh air; if effects occur, consult a physician.

Symptoms: Respiratory symptoms, including pulmonary edema, may be delayed.

Skin contact

Immediately flush skin with water while removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Destroy contaminated leather items such as shoes, belts, and watchbands. Suitable emergency safety shower facility should be immediately available.

Eye contact

Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist.

Ingestion

Do not induce vomiting. Seek medical attention immediately. If person is fully conscious give 1 cup or 8 ounces (240 ml) of water. If medical advice is delayed and if an adult has swallowed several ounces of chemical, then give 3-4 ounces (1/3-1/2 Cup) (90-120 ml) of hard liquor such as 80 proof whiskey. For children, give proportionally less liquor at a dose of 0.3 ounce (1 ½ tsp.) (8 ml) liquor for each 10 pounds of body weight, or 2 ml per kg body weight [e.g., 1.2 ounce (2 1/3 tbsp.) for a 40 pound child or 36 ml for an 18 kg child].

Symptoms: anion gap metabolic acidosis, CNS depression, renal tubular injury, and possible late stage cranial nerve involvement.

Immediate Medical Attention

Seek medical attention immediately. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress.

Medical Treatment

If several ounces (60 - 100 ml) of ethylene glycol have been ingested, early administration of ethanol may counter the toxic effects (metabolic acidosis, renal damage). Consider hemodialysis or peritoneal dialysis & thiamine 100 mg plus pyridoxine 50 mg intravenously every 6 hours. 4-Methyl pyrazole (Antizol®) is an effective blocker of alcohol dehydrogenase and should be used in the treatment of ethylene glycol (EG), di- or triethylene glycol (DEG, TEG), ethylene glycol butyl ether (EGBE), or methanol intoxication if available. Fomepizole protocol: loading dose 15 mg/kg intravenously, follow by bolus dose of 10 mg/kg every 12 hours; after 48 hours, increase bolus dose to 15 mg/kg every 12 hours. In severe poisoning, respiratory support with mechanical ventilation and positive end expiratory pressure may be required. Maintain adequate ventilation and oxygenation of the patient. If lavage is performed, suggest endotracheal and/or esophageal control.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.

Unsuitable media

Do not use direct water stream. May spread fire.

Specific hazards

Container may rupture from gas generation in a fire situation. Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.

Instructions

Keep people away. Isolate fire and deny unnecessary entry. Use water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reinition has passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.

Firefighter Protection

Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Isolate area. Keep unnecessary and unprotected personnel from entering the area.

Small spill

Absorb with materials such as: Cat litter. Sand. Sawdust. Zorb-all®. Hazorb®.

Large spill

Dike area to contain spill. Pump into suitable and properly labeled containers.

Environmental

Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.

Cleanup methods

Collect in suitable and properly labeled containers. Pump into suitable and properly labeled containers.

Materials: Cat litter, Sand, Sawdust, Zorb-all®, Hazorb®

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not swallow. Avoid contact with eyes. Wash thoroughly after handling. Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.

Storage

Do not store near food, foodstuffs, drugs or potable water supplies.

Hygiene

Wash thoroughly after handling.

Fire prevention

Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations.

Hands

Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. If hands are cut or scratched, use gloves chemically resistant to this material even for brief exposures. Use gloves with insulation for thermal protection, when needed. Examples of preferred glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl alcohol ("PVA"). Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Eyes

Use safety glasses (with side shields). If there is a potential for exposure to particles which could cause eye discomfort, wear chemical goggles. If exposure causes eye discomfort, use a full-face respirator.

Respiratory

Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions, no respiratory protection should be needed; however, if material is heated or sprayed, use an approved air-purifying respirator. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter

Skin/Body

Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. When handling hot material, protect skin from thermal burns as well as from skin absorption.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Cloud Point
---
Decomposition Temperature
No test data available
Upper Explosive Limit
15.3 % (V)
Molecular Weight
62 g/mol
Colour
Colorless
Kinematic Viscosity
---
Metal Corrosion
---
Bulk Density
---
Ph
9
Flammability
No
Physical State Data
liquid
Lower Explosive Limit
3.2 % (V)
Appearance
Colorless
Odor Threshold
No test data available
Form
---
Melting Point
Not applicable to liquids
Relative Evaporation Rate
---
Dynamic Viscosity
19.83 mPa.s @ 20 °C
Softening Point
---
Flash Point
111 °C (232 °F)
Vapor Pressure
0.067 hPa @ 20 °C
Evaporation Rate
0.01
Auto Ignition Temperature
398 °C (748 °F)
Relative Density
1.115 20 °C/20 °C
Solidification Point
---
State Under Standard Conditions
---
Explosive Limits
---
Boiling Point
197.4 °C (387.3 °F)
Partition Coefficient
-1.36
Solubility
---
Freezing Point
-11.2 °C (11.8 °F)
Density
---
Crystallisation Point
---
Vapor Density
2.1
Solubility In Water
100 %
Physical State
Liquid
Properties Status
---
Voc Content
---
Solubility In Fat
---
Odor
Sweet
Colour Intensity
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Thermally stable at recommended temperatures and pressures.

Reactivity

No dangerous reaction known under conditions of normal use.

Hazardous reactions

Polymerization will not occur.

Avoid

Exposure to elevated temperatures can cause product to decompose. Generation of gas during decomposition can cause pressure in closed systems.

Incompatible

Avoid contact with: Strong acids. Strong bases. Strong oxidizers.

Decomposition

Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Aldehydes. Alcohols. Ethers.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Recycler, Reclaimer, Incinerator or other thermal destruction device.

Disposal

For unused & uncontaminated product, the preferred options include sending to a licensed, permitted: Recycler, Reclaimer, Incinerator or other thermal destruction device.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3082
Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport Class
9
Packing Group
PG III
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Chemical Safety Assessment Not performed
?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Monoethylene Glycol?

The signal word is warning.

What is the physical form of Monoethylene Glycol?

Monoethylene Glycol is a liquid appearing as colorless with colorless color. It has sweet odor.

What are the hazard statements for Monoethylene Glycol?

This substance has 2 hazard statements:

  • H301: Harmful or fatal if swallowed.
  • H319: May cause eye irritation.

What is the melting point of Monoethylene Glycol?

The melting point is Not applicable to liquids and the boiling point is 197.4 °C (387.3 °F).