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Safety Data Sheet EN

M-NIMH NICKEL METAL HYDRIDE BATTERY PACK

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
M-NIMH NICKEL METAL HYDRIDE BATTERY PACK
Product Form
Nickel Metal Hydride Battery Pack
Product Code
M-NIMH
Synonyms
Nickel Metal Hydride Battery Pack

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Nickel Metal Hydride Battery Pack (Metal Hydride Chemistry)

Manufacturers & Suppliers

B

Brady Worldwide Inc.

manufacturer

6555 West Good Hope Road, Milwaukee, WI 53223, USA

(414) 358-6600

W

WH Brady NV

distributor

Lindestraat 20, Industriepark C3, B - 9240 Zele, Belgium

0032/(0)52.45.79.05

Emergency Contacts

Infotrac

1-800-535-5053

24 hours

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified no signal word

Hazard Classifications

Not Classified

GHS Pictograms

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

M-NIMH (Nickel Hydride Battery Pack) SDS. The product consists of materials used in the battery case, polyolefin non-woven separator, electrolyte mixture, and battery cell electrodes.

Chemical Name CAS Number Concentration Hazardous
Aluminum (non-pyrophoric solid) EC: 231-072-3 7429-90-5 --- No
Iron EC: 231-096-4 7439-89-6 --- No
Plastic --- --- No
Inert polymers and other trace compounds --- --- No
Ethene Polymer EC: 618-339-3 9002-88-4 --- No
Poly (hexamethylene adipamide) EC: 608-706-6 32131-17-2 --- Yes
Polypropylene EC: 618-352-4 9003-07-0 --- No
Nickel foam EC: 231-111-4 7440-02-0 --- Yes
Potassium Hydroxide EC: 215-181-3 1310-58-3 --- Yes
Sodium Hydroxide EC: 215-185-5 1310-73-2 --- Yes
Cobalt EC: 213-158-0 7440-48-4 --- Yes
Cobalt Dihydroxide EC: 244-166-4 21041-93-0 --- Yes
Manganese EC: 231-105-1 7439-96-5 --- Yes
Nickel Dihydroxide EC: 235-008-5 12054-48-7 --- Yes
04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

If any adverse effect occurs as a result of inhalation of fumes from thermal decomposition of the electrolyte solution during fire or other heating of battery, remove individual to fresh air. Seek medical attention if adverse effect occurs after removal to fresh air.

Skin contact

If skin or eye contact occurs to electrolyte solution, flush for 20 minutes. Contact physician or other medical health professional.

Eye contact

If skin or eye contact occurs to electrolyte solution, flush for 20 minutes. Contact physician or other medical health professional.

Ingestion

Not a potential route of exposure.

Immediate Medical Attention

Treat symptoms and eliminate exposure.

Medical Treatment

Treat symptoms and eliminate exposure.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Fires involving nickel metal hydride batteries should be extinguished with a Class D (combustible metal) smothering extinguishing agent that excludes the oxygen from the atmosphere such as METL-X, dry sand, dolomite, and soda ash.

Unsuitable media

Water, due to the formation of highly corrosive hydrofluoric acid. If water is to cool containers in a fire, it should be used in flooding quantities only.

Specific hazards

Batteries can explode in a fire. Contact with the electrolyte solution and water can produce hydrofluoric acid. Contact with water and the charged anode will produce hydrogen gas. Products of thermal decomposition can include toxic gases (e.g., carbon, manganese, nickel and cobalt oxides). Damaged or opened cells or batteries can result in rapid heating and the release of flammable vapors; during a fire, batteries may explode. During fire conditions, the electrode materials can form carcinogenic nickel and cobalt oxides. Leaking electrolyte solution is highly corrosive.

Firefighter Protection

Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

Eliminate all sources of ignition before cleanup begins. Use non-sparking tools. Clear the area and protect people.

Small spill

Wipe up spilled liquid with polypads or other suitable absorbent materials. Wash contaminated area with soap and water, absorb with paper towels, and rinse with water.

Large spill

Trained personnel following pre-planned procedures should handle non-incidental releases. Absorb spilled liquid with dry sand or other suitable non-reactive absorbent materials. Prevent material from entering sewer or confined spaces, waterways, soil or public waters. Monitor area.

Environmental

Prevent material from entering sewer or confined spaces, waterways, soil or public waters.

Cleanup methods

Wipe up spilled liquid, absorb with dry sand or other suitable non-reactive absorbent materials, wash contaminated area with soap and water.

Materials: Polypads, paper towels, dry sand, soap and water.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Do not disassemble, open, or modify the battery pack. Do not short circuit. Do not expose to heat or fire. Do not expose to water or rain. Do not crush, drop, or damage. Observe polarity. Recharge outside printer using specific charger. Use only for specified purpose. If crushed/damaged, use rubber gloves.

Storage

Store the battery pack in a cool, dry place. Do not store where temperatures may exceed 60°C (140°F) such as in direct sunlight, a vehicle or metal building during summer.

Hygiene

In the event of skin or eye exposure to the electrolyte, refer to Section 4, First Aid Measures.

Fire prevention

Store away from sources of heat or flame. Do not expose to heat or fire.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

No engineering controls are required for handling batteries that have not been damaged.

Hands

No special hand protection is normally required for use of this product. If batteries are damaged or leaking use wear butyl rubber, polyvinyl alcohol gloves or another appropriate glove.

Eyes

No special eye protection is required for use of this product. If batteries are damaged or leaking use safety goggles when handling the batteries.

Respiratory

No special respiratory protection is required for use of this product during normal use.

Skin/Body

No special body or skin protection is normally required for use of this product. If a hazard of injury to the feet exists due to falling objects or rolling objects use foot protection, as described in U.S. OSHA 29 CFR 1910.136 and the Canadian CSA Standard Z195-02, Protective Footwear.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State
---
Physical State Data
solid
State Under Standard Conditions
---
Appearance
---
Colour
Various parts have different colors.
Colour Intensity
---
Form
Manufactured article containing electrolyte solution.
Odor
Not applicable.
Odor Threshold
Not applicable.
Ph
Not determined, but will be highly basic and corrosive.
Melting Point
Not available.
Boiling Point
Not applicable.
Flash Point
Not applicable.
Freezing Point
Not available.
Softening Point
---
Solidification Point
---
Cloud Point
---
Crystallisation Point
---
Relative Evaporation Rate
---
Evaporation Rate
Not applicable.
Vapor Pressure
Not applicable.
Vapor Density
---
Relative Density
Not available.
Bulk Density
---
Density
---
Flammability
Not flammable.
Upper Explosive Limit
Not applicable.
Lower Explosive Limit
Not applicable.
Explosive Limits
---
Auto Ignition Temperature
Not available.
Decomposition Temperature
---
Solubility
---
Partition Coefficient
Not applicable.
Solubility In Water
Insoluble.
Solubility In Fat
---
Molecular Weight
Mixture.
Voc Content
---
Metal Corrosion
---
Dynamic Viscosity
---
Kinematic Viscosity
---
Properties Status
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

Stable under normal conditions of use and handling.

Reactivity

The electrolyte solution can react with water.

Hazardous reactions

If the electrolyte solution inside the battery contacts water, a reaction generating heat may occur. Polymerization will not occur.

Avoid

Avoid damaging batteries in any way that could release electrolyte solution. Avoid exposure to heat, flame, or other ignition source. Avoid contact with water. Avoid overcharging of batteries or other conditions as described in Section 7 (Handling or Storage).

Incompatible

potassium tert-butoxide, oxidizers, reducing agents, acids and alkalis, base metals.

Decomposition

Combustion: Carbon, nickel, cobalt and manganese oxides. Hydrolysis: Contact with the electrolyte solution and water can produce hydrofluoric acid. Contact with water and the charged anode will produce hydrogen gas.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of in accordance with applicable International, Federal, State, and local procedures and standards. Batteries should be completely discharged prior to disposal and/or the terminals taped or capped to prevent short circuit.

Disposal

Nickel hydride batteries must be handled in accordance with all applicable state and federal laws and regulations.

Waste Codes

16 06 05 Other batteries and accumulators EWC
16 06 06 Electrolyte from batteries and accumulators EWC
17 04 07 Mixed metals EWC
40 CFR 273.2 Universal Waste Regulations national code
14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
3496
Shipping Name
Batteries, nickel-metal hydride
Transport Class
9
IMDG

Special Provisions: 117,963

IATA

Under Special Provision A199 The UN number UN 3496 is only applicable in sea transport. Nickel-metal hydride batteries or nickel-metal hydride battery-powered devices, equipment or vehicles having the potential of a dangerous evolution of heat are not subject to these Regulations provided they are prepared for transport so as to prevent: (a) a short circuit (e.g., in the case of batteries, by the effective insulation of exposed terminals; or, in the case of equipment, by disconnection of the battery and protection of exposed terminals); and (b) unintentional activation.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

As an article, this product is exempt from listing on several chemical inventories, though components are listed or exempt. No requirements under various international regulations.

Chemical Safety Assessment Not performed

Internal circuitry of this nickel-hydride battery is RoHS compliant.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What other names is M-NIMH NICKEL METAL HYDRIDE BATTERY PACK known by?

M-NIMH NICKEL METAL HYDRIDE BATTERY PACK is also known as: Nickel Metal Hydride Battery Pack

What is the hazard signal word for M-NIMH NICKEL METAL HYDRIDE BATTERY PACK?

The signal word is no signal word.

What is M-NIMH NICKEL METAL HYDRIDE BATTERY PACK used for?

Nickel Metal Hydride Battery Pack (Metal Hydride Chemistry)

What is the melting point of M-NIMH NICKEL METAL HYDRIDE BATTERY PACK?

The melting point is Not available. and the boiling point is Not applicable..