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Safety Data Sheet EN

Formic acid 98-100% for analysis EMSURE

CAS 64-18-6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
Formic acid 98-100% for analysis EMSURE
Product Code
1.00264, 100264

Regulatory Identifiers

CAS Number
64-18-6 Check regulations →

Identified Uses

Reagent for analysis, Chemical production

Uses advised against

The product is being supplied under the TSCA R&D Exemption (40 CFR Section 720.36). It is the recipients responsibility to comply with the requirements of the R&D exemption. The product may not be used for a non-exempt commercial purpose under TSCA unless appropriate consent is granted in writing by MilliporeSigma.

Manufacturers & Suppliers

S

Sigma-Aldrich Inc.

global supplier

3050 SPRUCE ST ST. LOUIS MO 63103 UNITED STATES

+1 314 771-5765

Emergency Contacts

CHEMTREC

800-424-9300

24 Hours/day; 7 Days/week

CHEMTREC

+1-703-527-3887

24 Hours/day; 7 Days/week

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 3 H226
Acute Tox. Cat. 4 H302
Acute Tox. Cat. 3 H331
Skin Corr. Cat. 1A H314
Eye Dam. Cat. 1 H318

GHS Pictograms

GHS02 - Flammable

GHS02

GHS05 - Corrosive

GHS05

GHS06 - Acute toxicity

GHS06

Hazard Statements

H226 Flammable liquid and vapor.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.

Precautionary Statements

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing mist or vapors.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
P310 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Chemical Name CAS Number Concentration Hazardous
N/A --- 100% Yes

For the full text of the H-Statements mentioned in this Section, see Section 16.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

Skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

Eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

Ingestion

After swallowing: make victim drink water (two glasses at most). Call a physician immediately.

Symptoms: Risk of perforation, pulmonary failure possible after aspiration of vomit.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

The data for this section has not been processed yet.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

The data for this section has not been processed yet.

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

The data for this section has not been processed yet.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Hands

Full contact: Material: Chloroprene, Minimum layer thickness: 0.65 mm, Break through time: 480 min, Material tested: KCL 720 Camapren. Splash contact: Material: Latex gloves, Minimum layer thickness: 0.6 mm, Break through time: 60 min, Material tested: Lapren (KCL 706 / Aldrich Z677558, Size M). This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Eyes

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Respiratory

Recommended Filter type: Filter E-(P3). The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Skin/Body

Flame retardant antistatic protective clothing.

Environmental

Do not let product enter drains. Risk of explosion.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Density
1.22 g/cm3 at 20 C (68 F)
Ph
2.2 at 10 g/l at 20 C (68 F)
Boiling Point
100.80 C 213.44 F at 1,013 hPa
Flash Point
49.5 C (121.1 F)
Freezing Point
---
Solubility In Fat
---
Odor Threshold
0.02 ppm
Appearance
liquid, colorless
State Under Standard Conditions
---
Physical State Data
liquid
Voc Content
---
Properties Status
---
Odor
stinging
Solubility
---
Softening Point
---
Bulk Density
---
Cloud Point
---
Kinematic Viscosity
1.47 mm²/s at 20 C (68 F) - 1.02 mm²/s at 40 C (104 F)
Auto Ignition Temperature
528 C (982 F) at 1,008 hPa
Upper Explosive Limit
38 %(V)
Vapor Density
1.59 - (Air = 1.0)
Lower Explosive Limit
18 %(V)
Partition Coefficient
log Pow: -2.1 at 23 C (73 F)
Decomposition Temperature
350 C (662 F)
Form
liquid
Solubility In Water
miscible in all proportions, (experimental)
Crystallisation Point
---
Dynamic Viscosity
---
Vapor Pressure
171 hPa at 50 C (122 F)
Colour Intensity
---
Solidification Point
---
Flammability
No data available
Evaporation Rate
No data available
Molecular Weight
---
Relative Density
1.22 at 20 C
Physical State
liquid
Relative Evaporation Rate
---
Melting Point
8.5 C (47.3 F)
Explosive Limits
---
Colour
colorless
Metal Corrosion
---
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

The data for this section has not been processed yet.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

The data for this section has not been processed yet.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
1779
Shipping Name
Formic acid
Transport Class
8 (3)
Packing Group
II
15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

The data for this section has not been processed yet.

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Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for Formic acid 98-100% for analysis EMSURE?

The signal word is danger.

What is the physical form of Formic acid 98-100% for analysis EMSURE?

Formic acid 98-100% for analysis EMSURE is a liquid appearing as liquid, colorless with colorless color. It has stinging odor.

What is Formic acid 98-100% for analysis EMSURE used for?

Reagent for analysis, Chemical production

What are the hazard statements for Formic acid 98-100% for analysis EMSURE?

This substance has 4 hazard statements:

  • H226: Flammable liquid and vapor.
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H331: Toxic if inhaled.

What is the melting point of Formic acid 98-100% for analysis EMSURE?

The melting point is 8.5 C (47.3 F) and the boiling point is 100.80 C 213.44 F at 1,013 hPa.

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