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Safety Data Sheet EN

NAPPAR™ 6

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01

Identification

Product identifiers, regulatory numbers, and supplier information

Product Information

Product Name
NAPPAR™ 6
Product Form
Cycloparaffinic Hydrocarbons

Regulatory Identifiers

CAS Number
N/A

Identified Uses

Solvent

Uses advised against

This product is not recommended for any industrial, professional or consumer use other than the Identified Uses above.

Manufacturers & Suppliers

E

ExxonMobil Petroleum & Chemical BV

POLDERDIJKWEG, Antwerpen B-2030 Belgium

+32 2 239 3111

Emergency Contacts

Emergency Contact

+44 20 3885 0382

CHEMTREC

+1-703-527-3887

02

Hazard Identification

GHS classification, signal word, pictograms, and hazard statements

Classified danger

Hazard Classifications

Flam. Liq. Cat. 2 H225
STOT SE Cat. 3 H336
Asp. Tox. Cat. 1 H304
Aquatic Chronic Cat. 2 H411

GHS Pictograms

GHS02 - Flammable

GHS02

GHS07 - Health hazard

GHS07

GHS08 - Serious health hazard

GHS08

GHS09 - Environmental hazard

GHS09

Hazard Statements

H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical, ventilating or lighting equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P261 Avoid breathing vapour.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing, eye protection, face protection, or hearing protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P304 + P312 IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
P310 Immediately call a POISON CENTER or doctor.
P340 Remove person to fresh air and keep comfortable for breathing.
P370 + P378 In case of fire: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 Keep cool.
P405 Store locked up.
P501 Dispose of contents and container in accordance with all local, regional, national and international regulations.
IF SWALLOWED: Do NOT induce vomiting.

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03

Composition / Information on Ingredients

Chemical components, concentration ranges, and hazardous substance identification

Type mixture

solvent naphtha (petroleum), hydrotreated light naphthenic

Chemical Name CAS Number Concentration Hazardous
Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane EC: 926-605-8 --- 100% No
cyclohexane EC: 203-806-2 110-82-7 75% No
heptane and isomers --- 10 - 15% No
hexane (mixtures of isomers) --- 10 - 15% No
n-hexane EC: 203-777-6 110-54-3 5% No

Occupational exposure limits, if available, are listed in Section 8.

Notes

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

04

First Aid Measures

Emergency procedures for chemical exposure incidents

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness. Numbness, muscle cramps, weakness and paralysis that may be delayed.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Symptoms: No known significant effects or critical hazards.

Eye contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

Symptoms: No known significant effects or critical hazards.

Ingestion

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Symptoms: nausea or vomiting.

Immediate Medical Attention

Get medical attention immediately.

Medical Treatment

If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. This material, or a component, may be associated with cardiac sensitization following very high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart-stimulating substances like epinephrine. Administration of such substances should be avoided.

05

Firefighting Measures

Extinguishing media, specific hazards, and firefighter protection

Suitable media

Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable media

Do not use water jet.

Specific hazards

Highly flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapour/gas is heavier than air and will spread along the ground. Vapours may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Instructions

Use standard firefighting procedures and consider the hazards of other involved materials. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Assure an extended cooling down period to prevent re-ignition.

Firefighter Protection

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. No action shall be taken involving any personal risk or without suitable training.

06

Accidental Release Measures

Spill cleanup procedures, containment, and environmental protection

Emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Put on appropriate personal protective equipment. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Small spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill

Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Do not confine in area of spill. Allow liquid to evaporate from the surface. Seek the advice of a specialist before using dispersants. Advise occupants and shipping in downwind areas of fire and explosion hazard and warn them to stay clear.

Environmental

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Cleanup methods

Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Materials: inert dry material, sand, earth, vermiculite or diatomaceous earth

Related Products

Similar products with comparable safety profiles

07

Handling and Storage

Safe handling precautions, storage conditions, and workplace requirements

Handling

Put on appropriate personal protective equipment (see Section 8). Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.

Hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Fire prevention

Store and use away from heat, sparks, open flame or any other ignition source. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material.

08

Exposure Controls / PPE

Occupational exposure limits, engineering controls, and protective equipment

Engineering

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hands

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough time): Nitrile, minimum 0.38 mm thickness or comparable protective barrier material

Eyes

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Respiratory

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Recommended: organic vapour filter (Type A)

Skin/Body

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

09

Physical and Chemical Properties

Appearance, physical state, melting point, boiling point, and material characteristics

Physical State Data
liquid
Vapor Pressure
82.51 mm Hg [20 °C]
Solidification Point
---
Ph
Not applicable.
Lower Explosive Limit
1.2%
Freezing Point
Not available.
Flammability
Flammable liquids - Category 2
Kinematic Viscosity
0.76 cSt [40 °C], 0.93 cSt [20 °C]
Metal Corrosion
---
Partition Coefficient
<4
Upper Explosive Limit
8%
Odor
Slight
Relative Density
0.76
Flash Point
-19°C (-2.2°F)
Dynamic Viscosity
---
Vapor Density
---
Evaporation Rate
9.1 (butyl acetate = 1)
Voc Content
---
Auto Ignition Temperature
274°C (525.2°F)
Decomposition Temperature
Not available.
Relative Evaporation Rate
9.1 (butyl acetate = 1)
Solubility In Fat
---
Colour
Colourless
Properties Status
---
Melting Point
Not available.
Softening Point
---
Boiling Point
78 to 83°C (172.4 to 181.4°F)
Odor Threshold
Not available.
Form
---
Cloud Point
---
Crystallisation Point
---
Explosive Limits
---
Physical State
Liquid. [Clear]
Solubility
---
Appearance
Liquid. [Clear]
Molecular Weight
85
Colour Intensity
---
Bulk Density
---
Density
0.759 g/cm³ [15°C (59°F)]
State Under Standard Conditions
---
Solubility In Water
Negligible
10

Stability and Reactivity

Chemical stability, hazardous reactions, and incompatible materials

Stability

The product is stable.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapour to accumulate in low or confined areas.

Incompatible

Reactive or incompatible with the following materials: oxidising materials, Strong oxidisers

Decomposition

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

12

Ecological Information

Environmental toxicity, biodegradation, and bioaccumulation data

The data for this section has not been processed yet.

13

Disposal Considerations

Waste treatment methods, disposal recommendations, and waste codes

Treatment

Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

Disposal

The generation of waste should be avoided or minimised wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.

14

Transport Information

UN numbers, shipping names, transport classes, and regulatory requirements

UN Number
UN3295
Shipping Name
HYDROCARBONS, LIQUID, N.O.S.
Transport Class
3
Packing Group
II
ADR

The environmentally hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.

IMDG

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

IATA

The environmentally hazardous substance mark may appear if required by other transportation regulations.

15

Regulatory Information

Chemical regulations, safety assessments, and compliance status

?

Frequently Asked Questions

Common questions about safety, handling, and properties

What is the hazard signal word for NAPPAR™ 6?

The signal word is danger.

What is the physical form of NAPPAR™ 6?

NAPPAR™ 6 is a liquid. [clear] appearing as liquid. [clear] with colourless color. It has slight odor.

What is NAPPAR™ 6 used for?

Solvent

What are the hazard statements for NAPPAR™ 6?

This substance has 4 hazard statements:

  • H225: Highly flammable liquid and vapour.
  • H304: May be fatal if swallowed and enters airways.
  • H336: May cause drowsiness or dizziness.
  • H411: Toxic to aquatic life with long lasting effects.

What is the melting point of NAPPAR™ 6?

The melting point is Not available. and the boiling point is 78 to 83°C (172.4 to 181.4°F).